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Unit 4 – Nutrient Cycles in marine ecosystems Magnesium, Calcium, and Phosphorus Cycle Magnesium: • Used to make chlorophyll Ca Cycle: • Ca present in ocean as Ca2+ (calcium ions) • From weathering/erosion of rocks; brought to ocean from runoff of rivers • Used by marine organisms to: – Make corals – Make shells (mussels, clams, scallops, etc)—CaCO3 – Make bone—CaCO3 • Fall to seabed when organisms die • Forms limestone (AKA Calcium Carbonate CaCO3)/chalk Calcium Cycle: = CaCO3 **“Quick lime” = calcium oxide **Slaking: mix w/ H2O The Phosphorous Cycle • Biological uses: used to make DNA and bone • Very slow process • Found only in sedimentary rocks and water (not in atmosphere) • Released as rocks erode • Travels through food chain • Released by decomposition The Phosphorus Cycle Phosphorus occurs only in very minute amounts in the atmosphere. The main reservoirs of phosphorus are rock (especially the mineral apatite) and natural phosphate deposits, from which the element is released by weathering, leaching, erosion, and mining for agricultural use. Some of the phosphorus passes through terrestrial and aquatic ecosystems as organic phosphorus from plants to grazers, predators, and parasites. It is returned to the ecosystem by excretion, death and decay. In terrestrial ecosystems, organic phosphates are reduced by bacteria to inorganic phosphates. The Phosphorus Cycle The global phosphorus cycle is unique among the major biogeochemical cycles in having no significant atmospheric component Human impacts on the global phosphorus cycle • Phosphorus fertilizers used in agriculture are derived from phosphate rock. Most of the phosphate fertilizer combines with calcium, iron, and ammonium in soil to form insoluble salts and little escapes in runoff. • Part of the phosphorus used as fertilizer is removed in crops, transported far from the point of application and eventually released as waste in the processing and consumption of food. • Phosphorus is concentrated in wastes from food processing plants, feedlots, and sewage plants. • Most of the phosphorus enrichment of aquatic ecosystems comes from sewage disposal plants. • Overenrichment or eutrophication of freshwater ecosystems (where phosphorus is usually limiting) even more of a problem with phosphorus than with nitrogen. • The Phosphorus Cycle The phosphorus cycle in terrestrial and aquatic ecosystems. Crash Course: Nitrogen & Phosphorus http://youtu.be/leHy-Y_8nRs