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Intro to Weather and Climate – EART 80C Summer 2008 Lecture 1: July 28 Lecture 1: Scientific Quantities and SI Units Mass – kg Distance – m Time – s Temperature – K Force – Newton, N, kg*m/s2 (Mass times acceleration) Velocity – m/s (Distance per unit time) Acceleration – m/s2 (Velocity per time, change in velocity/change in time) Energy – Joules, J = Nm = kg*m/s2 * m (Force times distance) Pressure – N/m2 = Pascale, Pa (Force divided by area) kg*m/s2 *1/m2 Density (ρ) – kg/m3 (Mass per volume) Area – m2 Volume – m3 Power – Watt = J/s (energy per time) Mole – 6.023*1023 Things Scientific Notation Scientific notation is the way that scientists easily handle very large numbers or very small numbers. So, how does this work? W e can think of 5.6 x 10-9 as the product of two numbers: 5.6 (the digit term) and 10-9 (the exponential term). Here are some examples of scientific notation. 10000 = 1 x 104 1000 = 1 x 103 100 = 1 x 102 10 = 1 x 101 1 = 100 1/10 = 0.1 = 1 x 10-1 1/100 = 0.01 = 1 x 10-2 1/1000 = 0.001 = 1 x 10-3 1/10000 = 0.0001 = 1 x 10-4 24327 = 2.4327 x 104 7354 = 7.354 x 103 482 = 4.82 x 102 89 = 8.9 x 101 (not usually done) 0.32 = 3.2 x 10-1 (not usually done) 0.053 = 5.3 x 10-2 0.0078 = 7.8 x 10-3 0.00044 = 4.4 x 10-4 As you can see, the exponent of 10 is the number of places the decimal point must be shifted to give the number in long form. A positive exponent shows that the decimal point is shifted that number of places to the right. A negative exponent shows that the decimal point is shifted that number of places to the left. In scientific notation, the digit term indicates the number of significant figures in the number. The exponential term only places the decimal point. As an example, 46600000 = 4.66 x 107 Intro to Weather and Climate – EART 80C Summer 2008 Lecture 1: July 28 This number only has 3 significant figures. The zeros are not significant; they are only holding a place. As another example, 0.00053 = 5.3 x 10-4 This number has 2 significant figures. The zeros are only place holders. Significant Figures - no more than 3 sig figs usually Scientific notation is the most reliable way of expressing a number to a given number of significant figures. In scientific notation, the power of ten is insignificant. For instance, if one wishes to express the number 2000 to varying degrees of certainty: 2000 2 x 103 is expressed to one significant figure 2000 2.0 x 103 is expressed to two significant figures When handling significant figures in calculations, two rules are applied: Multiplication and division -- round the final result to the least number of significant figures of any one term, for example: The answer, 36.8, is rounded to three significant figures, because least number of significant figures was found in the term, 4.87. Addition and subtraction -- round the final result to the least number of decimal places, regardless of the significant figures of any one term, for example: The answer, 14.4587, was rounded to two decimal places, since the least number of decimal places found in the given terms was 2 (in the term, 13.45). Suppose more than one mathematical operation is involved in the calculation? Such a calculation may be "deceptive" as to how many significant figures are actually involved. For instance: The subtraction in the numerator must be performed first to establish the number of significant figures in the numerator. The subtraction results in: Intro to Weather and Climate – EART 80C Summer 2008 Lecture 1: July 28 Since the subtraction in the numerator resulted in a number to two significant figures the final result must be rounded to two significant figures. The Atmosphere A. Composition 78% Nitrogen (N) – basically inert so it was able to build up in the atmosphere 21% Oxygen (O) 1% Argon (Ar) – also inert Carbon Dioxide (CO2) – from respiration, combustion, GHG Methane (CH4) – cows, wetlands, rice patties, low oxygen environments, GHG Ozone (O3) – in both the stratosphere (good) and troposphere (bad) Water (H2O) – 0-5% variable over the surface of the earth Hydrogen (H2) Helium (He) Carbon Monoxide (CO) Ammonia (NH3) Nitrogen Oxide (NO) Nitrous Oxide (N2O) Sulfur Dioxide (SO2) Nitrogen Dioxide (NO2) Particles – Aerosols, dust, smoke B. Vertical Structure of the Atmosphere 1. Mostly true – Sun warms the earth, the earth warms the air! (Not at fact!) a. suggests that T decreases as height from the surface increases 2. The vertical structure of the atmosphere is defined by temperature Figure 1: The vertical structure of the atmosphere Intro to Weather and Climate – EART 80C Summer 2008 Lecture 1: July 28 c. Troposphere – warmed by earth decreases with height d. Stratosphere – sun warms ozone, ozone warms the air, temperature increases with height e. Mesosphere – returns to normal temperature decrease with height f. Thermosphere – very high temperatures, the sun warms N2 and O2 and heats up the rarefied “air”. The molecules have lots of energy and that energy is not necessarily in ‘heat’ energy. Thus, the temperature is high due to the interactions of the energized molecules bumping into one another. C. Temperature a. Gas – molecules bouncing off each other and “walls” and boundaries b. How fast the molecules are moving c. Kinetic energy of each molecule d. Has nothing to do with the number of the molecules e. Units 1. Kelvin, K, absolute zero is 0 K = -273.15 °C 2. Celsius, °C 3. Fahrenheit, °F (°F=(1.8*°C)+32) 4. Rankine, R (°F = R - 459.67) D. Pressure a. Pressure is Force per Area, the units are Pa = N/m2 b. 1 atm = 101325 Pa, 1.013*105 Pa c. 1kPa = 1000Pa d. 1 atm = 101.3kPa = 1.01 bar e. 1 bar = 100kPa f. 1 bar = 1000mb g. 1 bar = 100kPa = 1000mb = 105 Pa h. Pressure associated with fluid – force the fluid exerts on the walls. i. Pressure is the force/area exerted on a surface caused by the molecules colliding with the surface. h. Pressure does not require gravity EX 1: How much pressure does a standing person exert on the floor a) Find area: 7in *10in 70in 2 * 2.54cm 2.54cm 1m 1m * * * 0.045m 2 1in 1in 100cm 100cm b) Find Force: N = kg * m/s2 F = mass*acceleration (in this case acceleration is gravity) Weight = mass * 9.8 m/s2 Intro to Weather and Climate – EART 80C Summer 2008 mass 155lb * Lecture 1: July 28 1kg 70kg (go over conversion of lb to kg) 2.2lbs m F (70kg) * 9.8 700 N s P 700 N 1.5 * 10 4 Pa 2 0.045m D. Pressure (con’t) a. Pressure is Force per Area, the units are Pa = N/m2 1. Pressure = Force/Area Example: Why aren’t we crushed by the weight of the air above us? 1) We developed under this pressure. 2) Pressure force of air is exerted in all directions Pressure force is exerted in all directions Pressure in only one direction 3) If you lower the pressure drastically the cells of our bodies would burst!! (Hickies) b. Pressure Profile (From text) For every 5km you go up the pressure Decreases by 50% From 0 to 5km = 50% From 5 to 10km = 25% From 10 to 15km = 12.5% Intro to Weather and Climate – EART 80C Summer 2008 Lecture 1: July 28 E. Ideal Gas Laws PV nRT where P = Pressure R = Universal gas constant, 8.314 V = Volume N = Number of moles PV mRT where M J in SI units mol * K T = Temperature in Kelvin m = mass of gas M = Molecular weight of gas (from periodic table) Of air = 29 g/mole in a mole of normal air O2 = 32g/mol, N2 = 14g/mol, H2O = 18g/mol P RT M ρ = density of gas (density is in units of kg/m3 Mass per Volume!) where P cRT where c = concentration of gas (unites are moles/m3) Example: What is the density of air at Room Temperature? P RT M PM J using the values: R = 8.314 RT mol * R M = 29 g/mol = 0.028 kg/mol T = 20C = 20 + 273 K = 293K P = 1atm = 100kPa = 100000Pa = 1.0*105Pa Plug in the values: kg mol 1.2 kg m3 * 293K (1.0 *10 5 Pa) * 29 8.314 J mol * K Unit conversion within the problem! kg * m 2 N Pa 3 s 3 m m J Nm kg * m *m s2 N kg * m s2 F. Buoyancy a) Does it sink or float?? b) Density – big ships float but a little pebble sinks – density determines buoyancy Intro to Weather and Climate – EART 80C Summer 2008 Lecture 1: July 28 1. Less dense rises 2. More dense sinks c) Density of air at the ground at STP is about 1.2 kg/m3 1. Objects with density greater than the surrounding water or air will sink 2. Objects with density less than the surrounding water or air will rise 3. Objects with density equal to the surrounding water or air will stay suspended. People think of hot air rising, and cold air sinking….. Better: Low density rises!! High density sinks!! Temperature isn’t the only factor; pressure has to also be taken into account!