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High Temperature, Vol. 42, No. 1, 2004, pp. 133–139. Translated from Teplofizika Vysokikh Temperatur, Vol. 42, No. 1, 2004, pp. 143–150. Original Russian Text Copyright © 2004 by Dombrovskii. HEAT AND MASS TRANSFER AND PHYSICAL GASDYNAMICS The Propagation of Infrared Radiation in a Semitransparent Liquid Containing Gas Bubbles L. A. Dombrovskii IVTAN (Institute of High Temperatures) Scientific Association, Russian Academy of Sciences, Moscow, 125412 Russia Received May 13, 2003 Abstract—A theoretical model is suggested for the propagation of infrared radiation in a semitransparent liquid containing gas bubbles, which includes an approximate description of the radiation characteristics and radiation transfer in a disperse system. Calculations are performed for a layer of water containing vapor bubbles illuminated by the thermal radiation of an external source. It is demonstrated that, for real values of the parameters, the scattering of radiation by bubbles may lead to the absorption of thermal radiation in a much thinner layer of water. The possible application of the obtained results to the solution of a conjugate problem is discussed. INTRODUCTION The problem treated in this paper arises in the case of theoretical simulation of water cooling of burning hot surfaces. A practical example is provided by the delivery of water to the surface of the core melt in the case of a serious failure of a nuclear reactor [1]. The thermal radiation of a solid or melt with a temperature of 2000–3000 K is largely associated with the near infrared spectral region where water is semitransparent. Therefore, a significant part of the radiation is not absorbed in the surface layer but penetrates deep into the water and leads to volumetric heat release [2]. The forming vapor bubbles may, in turn, affect the propagation of the radiation. The complete physical formulation of the problem must take into account this feedback and the development of the process in time. At the same time, in the first stage, it is of interest to investigate the variation of infrared radiation characteristics of water in the presence of vapor bubbles and to solve the problem on the propagation of thermal radiation in a two-phase disperse system which both absorbs and scatters the radiation. The problem to be solved is rather general and relates both to any semitransparent liquids and to solids containing numerous bubbles or other spherical inclusions. Such structures are formed in the manufacture of glass and are observed in some heat-insulating materials. The determination of the radiation characteristics and the calculation of radiation transfer in such media represent important elements of the calculation of the thermal process conditions or of the heat-insulating properties [3–5]. The following main assumptions are used in this study to determine the radiation characteristics of a medium containing bubbles: the absorption of radiation occurs in a layer whose thickness significantly exceeds the bubble size; all bubbles are spherical; the bubbles are arranged at random; and the distance between bubbles significantly exceeds their sizes and the radiation wavelength. The first of these assumptions implies that only that spectral range is treated in which the medium weakly absorbs radiation (semitransparent region). The assumptions of the random arrangement of bubbles and of their not-too-high concentration lead one to believe that the scattering of radiation by an individual bubble does not depend on the presence of other bubbles [6, 7]. The restriction of our treatment to bubbles of spherical shape significantly simplifies the determination of their radiation characteristics. The problem was analogously formulated in [8–10] in calculating the radiation characteristics of glass containing gas bubbles. The relations used were valid only in the Rayleigh–Gans approximation or for the region of anomalous diffraction [11, 12]. In this study, the radiation characteristics of a medium containing bubbles are analyzed using the rigorous theory of scattering. RELATIONS FOR RADIATION CHARACTERISTICS OF SPHERICAL PARTICLES IN A SEMITRANSPARENT ABSORBING MEDIUM The classical Mie solution for the absorption and scattering of radiation by a spherical particle relates to the case when the particle is in a vacuum. According to the Mie theory, the characteristics of absorption and scattering depend on the diffraction parameter x = 2πa/λ (a is the particle radius, and λ is the radiation wavelength) and on the complex refractive index of the particle material m' = n' – iκ' (n' is the refractive index, and κ' is the absorption index) [11–13]. The regular formulas for the efficiency factors of scattering Qs and 0018-151X/04/4201-0133 © 2004 MAIK “Nauka /Interperiodica” 134 DOMBROVSKII extinction Qt , as well as for the factor of asymmetry of scattering µ , have the following form [13]: The following formulas are given in [8–10] for gas bubbles in glass: b ∞ 2 2 2 Q s = -----2 ( 2k + 1 ) ( a k + b k ), x k=1 ∑ (1) ∑ ∑ (3) 2k + 1 + -------------------- Re ( a k b k* ) . k(k + 1) Here, ak and bk are Mie coefficients expressed in terms of the Riccati–Bessel functions; the asterisk indicates complex conjugate quantities. The factor of absorption efficiency Qa and the transport factor of extinction efficiency Qtr, which are of interest to us (these quantities are required to perform an approximate calculation of radiation transfer [13, 14]), are determined by the formulas Qa = Qt – Qs , Q tr = Q t – Q s µ. (4) It is also convenient to use the transport factor of scattering efficiency, tr Q s = Q tr – Q a = Q s ( 1 – µ ). 2 (7) Obviously, in the case of particles, cavities, or gas bubbles which do not absorb radiation, the absorption efficiency factor Qa in an absorbing medium is negatr tive, and the transport factor of scattering efficiency Q s is positive. b g the complex refractive index for gas mb, Q a was calculated by the complex refractive index for gas mg, and the diffraction parameter was taken to be the same in both cases, x = 2πa/λ. No validation of formulas (8) and (9) is given in [8]. One can demonstrate both theoretically and using direct calculations that formula (8) is valid only in the limiting case of |mg – 1| 1, κgx 1 (the inequalities |mb – 1| 1, κbx 1 for gas are a priori valid) when the Rayleigh–Gans approximation is valid [11]. As to formula (9), it is erroneous, because the scattering depends on the ratio mb/mg rather than on the value of mb. THE EFFECT OF BUBBLES ON THE RADIATION CHARACTERISTICS OF A SEMITRANSPARENT MEDIUM The coefficient of absorption of elementary volume of a medium containing polydisperse particles or bubbles with the size distribution function F(a) is determined by the formula [13] ∞ f 4πκ 2 Σ a = ---------- + 0.75 ------v- Q a a F ( a ) da, a 30 λ ∫ (10) 0 where fv is the volume particle density, ∞ a ij = ∞ ∫ a F ( a ) da ∫ a F ( a ) da. i j 0 (11) 0 Similarly, the transport coefficient of scattering has the form (6) where r ≥ a is the distance to the particle center. For the semitransparent region treated in this study, κx 1. In this case, the coefficient C is independent of the distance r and is determined by the simple formula 2 -. C = --------2 2 n x (9) where, according to [8], Q a and Q s were calculated by (5) Mundy et al. [15] demonstrated that the formulas of the Mie theory are also valid for particles in a refracting and absorbing medium with an arbitrary complex refractive index m = n – iκ. In so doing, the complex quantities m̃ = m'/m (for cavities or gas bubbles, m̃ = 1/m) and x̃ = mx must be substituted for m' and x as independent variables in calculating the Mie coefficients, and the coefficient 2/x2 in formulas (1)–(3) must be replaced by 4κ exp [ – 2κx ( r/a ) ] -, C = ----------------------------------------------------------------------------------2 2 ( n + κ ) [ 1 + ( 2κx – 1 ) exp ( 2κx ) ] b b (2) ∞ k(k + 2) 4 -------------------- Re ( a k a *k + 1 + b k b *k + 1 ) µQ s = -----2 x k=1 k+1 (8) Qs = Qs , ∞ 2 Q t = -----2 ( 2k + 1 )Re ( a k + b k ), x k=1 g Qa = Qa – Qa , ∞ tr Σs f tr 2 = 0.75 ------v- Q s a F ( a ) da, a 30 ∫ (12) 0 The transport coefficient of extinction is Σtr = Σa = tr Σs . In a monodisperse approximation, formulas (10) and (12) are written as Q 4πκ Σ a = ---------- + 0.75 f v ------a , a λ (13) tr Qs tr Σ s = 0.75 f v ------. a HIGH TEMPERATURE Vol. 42 (14) No. 1 2004 THE PROPAGATION OF INFRARED RADIATION α 1.3 135 Qstr 0.5 1 2 3 1.2 1.1 0.4 4 0.3 3 0.2 2 0.1 1 I II 1.0 0 10 20 30 x 0 5 10 15 20 25 30 x Fig. 1. The relative factor of absorption efficiency for bubbles in media with different optical properties: (1) n = 1.2, (2) 1.3, and (3) 1.5; I – κ = 10–3, II – κ = 10–4. Fig. 2. The transport factor of absorption efficiency for bubbles in nonabsorbing media with different refractive indices: (1) n = 1.2, (2) 1.3, (3) 1.4, and (4) 1.5. We will examine the effect of monodisperse bubbles on the radiation characteristics of a medium. For clarity, we will rewrite formula (13) as For a polydisperse medium, approximate formulas have the form 4πκ Σ a = ---------- ( 1 – f v α ), λ α = – Q a / ( 8κx/3 ). (15) The results of calculation of the α(x) dependence by the algorithm similar to that suggested in [13] for the most interesting range of variation of the optical constants of the medium are given in Fig. 1. One can see that, even with x > 10 and κx < 0.01, the parameter α approaches the asymptotic value for large bubbles in a weakly absorbing medium, α = 1. In the near-infrared spectrum, the condition x > 10 is valid for all bubbles with a radius a > 4 µm. Because fv 1, we have αfv 1; therefore, according to Eqs. (15), the effect of the bubbles on the absorption of radiation in the semitransparent region is negligibly low and may be ignored on the assumption that Σa = 4πκ/λ. A series of calculations using the Mie theory have demonstrated that, in a medium that weakly absorbs radiation, the absorption has almost no effect on the scattering of radiation by bubbles, and it is sufficient to tr treat the Q s (x) dependences for κ = 0 given in Fig. 2. The results of approximate calculations demonstrate that, even for x > 10, the transport factor of scattering efficiency may be regarded as a constant quantity, which corresponds to the transition to the region of geotr metrical optics. The respective values of Q s may be estimated by the formula tr Q s = 0.9 ( n – 1 ), (16) whence 4πκ Σ a = ---------- , λ (18) n–1 tr Σ s = 0.675 f v -----------. a 32 (19) We will compare the transport scattering coefficient with the absorption coefficient using the ratio between them, n–1 tr Σ s /Σ a ≈ 0.34 f v -----------, κx 32 2πa 32 -. x 32 = ------------λ (20) It follows from (20) that, with a bubble concentration fv > 10κx32, radiation scattering may dominate over absorption. With an invariable spectral absorption index for liquid, the importance of scattering is defined by the ratio of the volume density of the bubbles to their average radius fv /a32. THE METHOD OF CALCULATION OF RADIATION TRANSFER IN AN ABSORBING AND REFRACTING MEDIUM CONTAINING SCATTERING PARTICLES We will treat the problem on radiation transfer in a semi-infinite layer of an absorbing and refracting medium containing radiation-scattering particles. We will assume that the surface of the medium is uniformly illuminated by diffuse randomly polarized outer radiation. The equation of radiation transfer in the transport approximation has the form [13] tr 1 n–1 tr Σ s = 0.675 f v -----------. a HIGH TEMPERATURE Vol. 42 (17) Σ ∂I µ -------λ + Σ tr I λ = -----s- I λ dµ, ∂z 2 ∫ –1 No. 1 2004 (21) 136 DOMBROVSKII and boundary condition for the spectral radiation intensity Iλ(z, µ), 2 e I λ(0, µ) = RI λ(0, – µ) + ( 1 – R )2n q λ , 0 ≤ µ ≤ 1. (22) Here, µ = cosθ, the angle θ is reckoned from a nore mal directed into the medium, q λ is the spectral flow of outer radiation, and R(µ) is the reflection coefficient, 1 µ – nµ' 2 nµ – µ' 2 R ( µ ) = --- ------------------ + ------------------ , nµ + µ' 2 µ + nµ' 2 µ' = 2 1 – n (1 – µ ), R ( µ ) = 1, µ ≤ µc = µ > µc , The differential approximation is provided by the DP0-approximation of the method of dual spherical harmonics, or two-flow approximation [13]. We assume that – + – I λ ( z, µ ) = ϕ 0 ( z ) + [ ϕ 0 ( z ) – ϕ 0 ( z ) ]Θ ( µ ) (27) and integrate Eq. (21) separately over the intervals −1 < µ < 0 and 0 < µ < 1 to derive, after simple transformations, the following boundary-value problem for – + the function g0 = ϕ 0 + ϕ 0 : (23) dg d – ----- D λ --------0 + Σ a g 0 = 0 , dz dz 2 1 – 1/n . In a particular case of a nonscattering medium, the problem given by Eqs. (21)–(23) has an obvious analytical solution, z = 0, (28) dg n 2 e - ( g 0 – 4n q λ ) , D λ --------0 = ------------2 dz n +1 (29) dg 0 -------- = 0. dz (30) 2 e I λ ( z, µ ) = ( 1 – R )2n q λ exp ( – Σ a z/µ )Θ ( µ – µ c ), (24) where Θ is the Heaviside function. According to Eq. (24), the outer radiation, after entering a refracting medium, propagates within a cone with an apex angle of 2 arccos ( µ c ) . The power of absorbed radiation P(z) was determined as ∞ P(z) = ∫ Σ W ( z ) dλ, λ a (25) 0 where the spectral density of radiation energy is 1 W λ(z) = ∫ I ( z, µ ) dµ 1 2 e Here, Dλ = 1/(4Σtr) is the spectral coefficient of radiation diffusion. Because, in the case of a numerical solution of the problem, boundary condition (30) is preassigned for some finite z = ∞ rather than for z = z0, a less rigid condition imposed on the derivative (instead of the possible condition g0 = 0) is preferred. The coefficient in the boundary condition on the liquid surface is determined, as in [16, 17], by the value of the reflection coefficient at µ = 1, 2 λ –1 z = ∞, 2 R(1) = (n – 1) /(n + 1) . (26) ∫ = 2n q λ ( 1 – R ) exp ( – Σ a z/µ ) dµ. µc In the presence of scattering, the radiation field in the medium becomes significantly more complex. If scattering prevails over absorption, the angular dependence of the radiation intensity does not exhibit the feature mentioned above and characteristic of the solution in a nonscattering medium. In this case, an approximate calculation of radiation transfer may be performed using some differential approximation, as has been done, for example, by Fedorov and Viskanta [8]. However, in the general case of an arbitrary ratio between absorption and scattering, this may lead to a significant underestimation of the depth of radiation penetration. Therefore, I follow [13, 14] and suggest a combined solution in which the differential approximation is used only to determine the integral term in the right-hand part of transfer equation (21) and, in the second step of the solution, the equation of radiation transfer with the known right-hand part is integrated. (31) The solution of the boundary-value problem (28)– (30) gives an approximate profile of the spectral density of radiation energy entering the right-hand part of transfer equation (21), 1 W λ(z) = ∫ I ( z, µ ) dµ = g ( z ). λ 0 (32) –1 Note that, with constant coefficients Σa and Dλ, the problem given by Eqs. (28)–(30) has a simple analytical solution, 2 e 2n q λ - exp ( – 2 Σ a Σ tr z ). g 0 ( z ) = ----------------------------------------2 n +1 1 + -------------- Σ a /Σ tr 2n (33) Comparison of formulas (26) and (33) at Σtr = Σa gives an idea of the error of the DP0-approximation in a weakly scattering medium. HIGH TEMPERATURE Vol. 42 No. 1 2004 THE PROPAGATION OF INFRARED RADIATION Solutions to the equation of radiation transfer (21) with the right-hand part calculated in the DP0-approximation may be obtained using an integrating factor [18], I λ ( z, µ ) = I λ ( 0, µ ) exp ( – Σ tr z/µ ) z tr 1 Σ z–t + --- -----s- g 0 ( t ) exp – Σ tr --------- dt, 2 µ µ ∫ (34) 0 ∞ Formula (40) corresponds to the regular definition [18, 19], and Eq. (41) is distinguished by a nonzero lower integration limit. After determining Wλ(z), the power of the absorbed radiation (P(z) is found by integration over the spectrum (by formula (25)). Note that the function P(z) satisfies the relation for energy balance, which is written for a semi-infinite layer of a medium as ∞ tr Σs 1 t–z I λ ( z, – µ ) = --- ------ g 0 ( t ) exp – Σ tr --------- dt, 2 µ µ ∫ 137 µ > 0. (35) ∞ ∫ P ( z ) dz = q, 0 q = ∫ q dλ, λ (42) 0 z Relations (34) and (35) in combination with boundary condition (22) make it possible to calculate the spectral radiation intensity in all directions at any point of the calculation region. First, Iλ(z, –µ) is determined by formula (35), and then the known quantity Iλ(0, –µ) from boundary condition (22) is used to calculate Iλ(0, µ). After that, Iλ(z, µ) is calculated by formula (34). However, it is not our objective to determine the angular dependence of the spectral radiation intensity. It is sufficient to calculate the profile of the spectral density of radiation energy, – + W λ ( z ) = W λ ( z ) + W λ ( z ), ∫ 1 – (36) + where W λ (z) = 0 I λ (z, –µ)dµ and W λ (z) = µ)dµ. We use Eq. (35) to find ∫ 1 I (z, 0 λ ∞ – W λ(z) ∫ (37) Relation (34) and boundary condition (22) yield the approximate integral relation z 1 tr + + W λ ( z ) = W λ ( 0 ) + --- Σ s g 0 ( t )E 1 [ Σ tr ( z – t ) ] dt, (38) 2 ∫ 0 + – W λ ( 0 ) = R ( 1 )W λ ( 0 )E 2 ( Σ tr z ) (39) 2 e + [ 1 – R ( 1 ) ]2n q λ Ẽ 2 ( Σ tr z ). Formulas (36)–(39) enable one to calculate the spectral density of radiation energy. The integroexponential functions appearing in Eqs. (37)–(39) are defined as 1 ∫µ k–2 ∞ z Q(z) = ∫ P ( z ) dz ∫ 0 0 exp ( – y/µ ) dµ, k = 1, 2; (40) 0 1 Ẽ 2 ( y ) = ∫ exp ( – y/µ ) dµ. (41) µc HIGH TEMPERATURE Vol. 42 No. 1 2004 z 1 P ( z ) dz = --- P ( z ) dz. q ∫ (43) 0 CALCULATIONS FOR WATER CONTAINING VAPOR BUBBLES We will treat the model problem on the propagation of thermal radiation in a thick layer of water containing vapor bubbles. The spectrum of radiation incident on the water layer is taken to be similar to the spectrum of blackbody radiation for some temperature Te, i.e., it is e 1 tr = --- Σ s g 0 ( t )E 1 [ Σ tr ( t – z ) ] dt. 2 z Ek ( y ) = where q is the integral flux of thermal radiation on the z = 0 surface. We will follow [2] and, along with the differential characteristic of absorption P(z), use the function corresponding to the fraction of total integral flux of thermal radiation absorbed in a layer of liquid (0, z), assumed that q λ = Bλ(Te). The concentration of vapor bubbles and their size are assumed to be constant over tr the entire layer of water. The coefficients Σa, Σ s , and Σtr are independent of coordinate z. It is obvious that the real problem is conjugate, because the profiles of volume concentration fv(z) and of the average bubble radius a32(z) affect the thermal radiation transfer, and the volumetric heat release causes a variation of the fv(z) and a32(z) profiles as a result of absorption of radiation. However, in order to solve the problem, one needs some kinetic model describing the nucleation and growth of vapor bubbles with due regard for the absorption of thermal radiation. Such a general problem is beyond the scope of this study; therefore, in the model calculations performed, the constant values of fv and a32 are treated as preassigned parameters. In the calculations of the spectral radiation characteristics of water containing vapor bubbles, the absorption index for water in the infrared spectrum was determined by way of interpolation of the tabular data of [20], and the refractive index was taken to be n = 1.33 (in the semitransparent region, it varies from n = 1.335 at λ = 0.5 µm to n = 1.324 at λ = 1.2 µm). The vapor in the bubbles was assumed to be fully transparent to thermal radiation. The spectral coefficient of absorption 138 DOMBROVSKII Q 1.00 z0, m 100 10 (a) 0.95 4 1 3 1 0.90 0.1 0.85 0.01 0.001 0.5 1.0 1.5 2.0 2.5 λ, µm Fig. 3. The thickness of the water layer in which the outer radiation is almost fully absorbed. Estimation was made by formula (44). and the spectral transport coefficient of scattering were determined by formulas (18) and (19). For better illustration of the transparent region of water, Fig. 3 gives the values of water layer thickness z0 at which the radiation on a given wavelength is almost fully absorbed. The value of z0 was determined by the formula 10 z 0 = ------ , Σa (44) i.e., from the condition of the equality of the spectral optical thickness of the water layer to ten. Curve z0(λ) in Fig. 3 defines the region in which the problem of radiation transfer does not degenerate. The Q(z) dependences were calculated as follows. First, the analytical solution of (32) was used to determine the function g0(z) which was a first approximation for the spectral density of radiation energy Wλ(z). Then, formulas (36)–(39) were used to find the next approximation for Wλ(z). The resultant function was substituted into Eq. (25) for the power of absorbed radiation P(z) and, finally, the function Q(z) was determined by formula (43). Figure 4 gives the calculated dependence Q(z) for different values of fv /a32, because this particular ratio is the only parameter allowing for the effect of vapor bubbles on radiation transfer. Also given for comparison is the Q(z) curve for fv = 0. The calculations were performed for two temperatures of the thermal radiation source, namely, Te = 2000 K and Te = 3000 K. One series of calculations was performed in the DP0approximation (without the second step of solution), and the other series was performed using a combined computational model. It follows from the data in Fig. 4 that the DP0-approximation gives qualitatively correct results but underestimates the thickness of the water layer in which the thermal radiation is absorbed by a factor of almost two. The error of the DP0-approxima- I II 0.80 1.0 (b) 4 0.9 3 2 0.8 1 0.7 I II 0.6 0.5 1 10 100 z, mm Fig. 4. The effect of vapor bubbles on the absorption of radiation in a layer of water: (a) Te = 2000 K, (b) Te = 3000 K; I—DP0-approximation, II—combined computational model; (1) fv /a32 = 0 (2) fv /a32 = 10 m–1, (3) 100 m–1, (4) 1000 m–1. tion somewhat decreases with increasing contribution by scattering. As was to be expected, the scattering of radiation by vapor bubbles leads to the absorption of radiation in a thinner layer of water. This effect becomes significant even at fv /a32 ≥ 10 m–1. Figure 5 illustrates the effect of relatively low values of the parameter fv /a32 on the thickness ∆ of the water layer in which the bulk of the power of thermal radiation is absorbed at Te = 3000 K. The values of ∆ given in Fig. 5 were determined using the equalities Q(∆) = 0.07 and Q(∆) = 0.8. In order to understand how real the preassigned values of fv /a32 are, one can turn to the experimental data of [21, 22], according to which the value of fv /a32 in the majority of cases varies from 5 to 100. In this range, the treated effect shows up quite clearly. Turning back to the discussion of the conjugate problem in view of the effect of the absorption of radiation on the nucleation and growth of vapor bubbles (bearing in mind, for example, film boiling on a surface with a temperature above 2000 K), note the presence of positive feedback: an increase in the concentration and size of bubbles leads to an ever stronger absorption of HIGH TEMPERATURE Vol. 42 No. 1 2004 THE PROPAGATION OF INFRARED RADIATION ∆, mm 35 tering of radiation by bubbles may lead to the absorption of thermal radiation in a much thinner layer of water than in the case of water without bubbles. The suggested theoretical model may be used in solving a conjugate problem in view of the effect made by volume absorption of radiation on the nucleation and growth of vapor bubbles. 1 2 30 139 25 20 15 REFERENCES 10 5 0 5 10 15 20 25 30 ƒv /a32, m–1 Fig. 5. The effect of vapor bubbles on the thickness of the water layer in which (1) 70% and (2) 80% of the power of thermal radiation is absorbed at Te = 3000 K. The calculation was performed by the combined computational model. radiation in a thin layer of water in the vicinity of the surface. As a result, one can expect a periodic explosion-like boiling of liquid in this surface layer with a splashing of fine droplets. CONCLUSIONS A theoretical model is suggested of for propagation of infrared radiation in a semitransparent liquid containing gas bubbles, which includes an approximate description of the spectral radiation characteristics and radiation transfer in view of the scattering of radiation by the bubbles. The Mie theory was employed to calculate the effect of bubbles on the absorption and scattering of radiation. The calculation results have demonstrated that, in the real range of variation of parameters, the bubbles have almost no effect on the absorption coefficient and the main effect is associated with the scattering of radiation. A simple formula is suggested for the scattering coefficient, which approximates the results of exact calculations. A combined computational model is suggested for the calculation of radiation transfer in a liquid containing gas bubbles; in this model, the DP0-approximation is used in the first step of the solution, and then the equation of radiation transfer is integrated. It is demonstrated that the second step of solution significantly refines the calculated profiles of absorption in a layer of water. Calculations were performed for a thick layer of water containing vapor bubbles illuminated by the thermal radiation of an external source. It has been demonstrated that, for real values of the parameters, the scat- HIGH TEMPERATURE Vol. 42 No. 1 2004 1. 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