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http://gallerypick.com/university-of-illinois-at-urbana-champaign-images/ Outline • Introduction and Motivation • Ball Lightning • Ball plasmoid characteristics • Adjusted parameters • Optical Emission Spectroscopy • Spectral Analysis and Fitting • Conclusions • Future Work http://drevol.com/en/blog/Nikola-Tesla-158-years-birthday-009 Tesla, N. Colorado Springs Notes: 1899-1900, Nolit, Beograd, Yugoslavia, 1978 Ball Lightning • Sphere of light • Up to 1m diameter • Lasts many seconds • Difficult to observe in the field • One documented observation to date • Formation / Lifetime • Laboratory analogue: Ball plasmoid Image courtesy of the Wikimedia Commons Cen, J.; Yuan, P.; Xue, S. Phys. Rev. Lett. 2014, 112, 035001 McNally, J. R. Preliminary Report on Ball Lightning, No. 3938; Oak Ridge National Laboratory: Oak Ridge, TN, 1966 Ter Haar, D. Phys. Scr. 1989, 39, 735 Endean, V.G. Nat. 1976, 273, 753-755 Wu, H. C. Sci. Rep. 2016, 6, 28263 Hardware Discharge Characterization: 105 ms 99 ms 150 ms 200 ms 300 ms 10 cm Detachment 1. Pre-initiation a. b. Buildup 2. Buildup a. b. Switch Closes Switch closes Current begins to flow (< cathode spot threshold) More current begins to flow Plasma forms at electrode 3. Detachment a. Preinitiation Plasma detaches from electrode and becomes plasmoid i. Buoyancy OES Experiment: Whole Plasmoid • Ocean Optics S2000: 200-500 nm, 0.5 nm resolution - better efficiency in the blue/violet/UV • Ocean Optics Jaz: 250-800 nm, 0.7 nm resolution - better efficiency in the red - measurements made with optical fiber • Wavelength and intensity calibration with external sources • Internal trigger: continuously fire when signal across chip is > 2% dark spectrum Spectrometer OES Experiment: Height Resolved • Series of equal-sized holes oriented vertically • Spectrometer 0-40 cm • “Field of view” of spectrometer (fiber) is larger than hole Spectral Assignment http://www.bristoldynamics.com/activity/laser-spectroscopy-and-pgopher/ • Use NIST Atomic Spectral Database to assign atomic transitions • Use SPECAIR to “Auto-find” transitions • Extract appropriate molecular info from Exomol and HITRAN databases • Use literature values to get other spectroscopic constants not included in these databases • Generate molecular spectra with PGOPHER https://www.nist.gov/ Tennyson et al., J. Mol. Spec., 2016, 327, 73-94. Rothman et al. Journal of Quantitative Spectroscopy & Radiative Transfer, 2013, 130, 4 http://www.spectralfit.com/ PGOPHER, a Program for Simulating Rotational Structure, C. M. Western, University of Bristol, http://pgopher.chm.bris.ac.uk Example Spectra: Whole Plasmoid Tungsten electrode, 7 kV Example Spectra: Height Resolved Hβ O I (5P→5S) 0 cm (cathode level) +10 cm OH Example Spectra: Height Resolved O I (5P→5S) Hβ +20 cm OH O I (5P→5S) Hβ +40 cm Electrode Composition Molecular Fitting # Trot OH [K] 0 No emission 1 4540 ± 490 2 3680 ± 360 3 3700 ± 350 4 3670 ± 350 5 3790 ± 370 Temperature Fitting # Trot [K] 0407-18 Trot [K] 0407-19 Trot [K] 0407-20 0 No emission No emission No emission 1 No emission 7680 ± 900 5910 ±740 2 5820 ± 730 5730 ± 720 5570 ± 700 3 5130 ± 650 5270 ± 670 4870 ± 620 4 4630 ± 590 4110 ± 520 4070 ± 500 5 4040 ± 510 No emission No emission Blackbody Fitting This is not exactly a blackbody curve, however, a Planck function can be fit to the spectra Possible mechanisms of continuum emission: • Triatomics • Thermal radiation • Bremsstrahlung radiation Summary • First time-resolved measurements of OH rotational temperature in ball plasmoids • High temperature early in discharge, decreases over time • First continuum fits of ball plasmoid emission spectra • Possible radiation processes: • Triatomic emission • Bremsstrahlung radiation • Thermal radiation Future Directions X-Band horn antennas Plasmoid Amplifier Function Generator Frequency Multipliers Amplifiers Splitter (difference) “Magic” Tee (sum) Coax cable Phase Shifter • • • • Attenuator Amplifier X-band interferometer operating at ~9.2 GHz Measure phase shift and attenuation of beam induced by plasmoid Calculate electron “column density” as a function of time Deduce primary electron recombination mechanism? Acknowledgements • McCall Research Group • Amber N. Rose • Prof. Nick Glumac – instrumentation and emission spectroscopy • Prof. J. Gary Eden – microwave interferometry