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Introduction to Semiconductor Lecture #2 נקודות זיקוי3.5- 334011 חשמלי-יסודות תכן ביו Syllabus: 1. General introduction 2. Introduction to semiconductor 3. PN Junction 4. Diode 5. MOS capacitor 6. MOSFET Transistor 7. Circuits - Small signal analysis 8. Circuits – MOSFET amplifier 9. Circuits - MOSFET advanced 10.Differential amplifier 11.Negative feedback 12.Digital circuits Material in electronics Conductors 𝐼 =1 𝑅 𝑉 • Linear Device (ohm's law) (V>0 I>0) • Resistors (R) Semiconductors 𝑑𝐼 =1 𝑅 𝑑𝑉 • Non Linear Device (I>0 only for V>Vth) • Diode, transistors, switches, amplifiers… Insulator 𝑑𝑉 𝐼=𝐶 𝑑𝑡 • I=0 for any voltage • Capacitor – charges accumulation Conductors Material in electronics material that easily conducts electrical current, have low resistance The best conductors are copper, silver, gold, aluminum no energy is needed to get free electrons Insulators material does not conduct electric current, have high resistance no free electrons most commonly use (SiO2 – silicon dioxide) Semiconductors material between conductors and insulators in its ability to conduct electric current most commonly use semiconductor ; silicon(Si), germanium(Ge), and carbon(C). need a small amount of energy to get free electrons (Temperature, voltage) Atom structure of conductors • The atomic structure of good conductors usually includes only one electron in their outer shell: • It is called a valence electron ((אלקטרון ערכיות. • It is easily striped from the atom, producing current flow. • Insulator: The atoms are tightly bound to one another so electrons are difficult to strip away for current flow. Atom structure of semiconductors • The main characteristic of a semiconductor element is that it has four electrons in its outer or valence orbit. • Silicon: +14 Atomic number, electrons per shell (2,8,4) sharing of valence electron produce the covalent bond • Covalent bonding – holding atoms together by sharing valence electrons • The center atom shares an electrons with each of four surrounding atoms, creating a covalent bond with each. Intrinsic Semiconductors Combining the atoms in unique arrangement that is a repeated we get a new structure called “crystal lattice” The result of the bonding: 1. The atoms link together with one another sharing their outer electrons (covalent bands) forming a solid substrate. 2. The atoms are all electrically stable, because their valence shells are complete. Since the outer valence electrons of each atom are tightly bound together with one another, the electrons are difficult to dislodge for current flow 3. The complete valence shells cause the silicon to act as an insulatorintrinsic (pure) silicon is a very poor conductor Conductance in Semiconductors How can we make a pure (intrinsic) semiconductor to be conduct? Conduction level Covalent level Conductance in Semiconductors How can we make a pure (intrinsic) semiconductor to be conduct? Temp (K) Temp (°C) Germanium Silicon 300 26 400 126 500 226 600 326 Thermal energy or light (photon energy) produce free electrons in intrinsic semiconductor Applying electrical field cause a flow of electrons current Extrinsic Semiconductors - Doping How can we make a pure (intrinsic) semiconductor to be conduct? Doping: To make the semiconductor conduct electricity, other atoms called impurities with 5 or 3 valence electrons must be added. • Adding arsenic (doping with 5 valence electrons) will allow four of the arsenic valence electrons to bond with the neighboring silicon atoms. • The one electron left over for each arsenic atom becomes available to conduct current flow, because it is not attached to any atom As doping atom n-type Semiconductors – Doping • If we use lots of arsenic atoms for doping, there will be lots of extra electrons so the resistance of the material will be low and current will flow freely. • Doping atom that gives up an electron -call a donor atom • Current carries in n-type are electrons – majority carries • No. of conduction electrons can be controlled by the no. of impurity atoms. By controlling the doping amount, virtually any resistance can be achieved. p-type Semiconductors – Doping • You can also dope a semiconductor material with an atom such as boron that has only 3 valence electrons. • The 3 electrons in the outer orbit do form covalent bonds with its neighboring semiconductor atoms as before. But one electron is missing from the bond. • This place where a fourth electron should be is referred to as a hole. • The hole assumes a positive charge so it can attract electrons from some other source. • Holes become a type of current carrier with positive charge like the electron to support current flow. B doping atom When a valance electron moves left to fill a hole while leaving another hole behind; the hole has effectively moved from right to left p-type Semiconductors – Doping Holes as charge carriers p-type Semiconductors – Doping • If we use lots of Boron atoms for doping, there will be lots of extra holes (missing electrons) so the resistance of the material will be low and current will flow freely. • Doping atom that take an electron -call a acceptor atom • Current carries in p-type are hole – majority carries • No. of holes can be controlled by the no. of impurity atoms. By controlling the doping amount, virtually any resistance can be achieved. Current Flow in Extrinsic Semiconductors • The voltage source has a positive terminal that attracts the free electrons in the semiconductor and pulls them away from their atoms leaving the atoms charged positively. • Current (electrons) flows from the negative terminal to the positive terminal. • Electrons from the negative supply terminal are attracted to the positive holes and fill them. • Current (electrons) flows from the negative terminal to the positive terminal. • Inside the semiconductor current flow is actually by the movement of the holes from positive to negative Summary • In its pure state, semiconductor material is an excellent insulator. • The commonly used semiconductor material is silicon. • Semiconductor material has a crystal lattice structure. • Semiconductor materials can be doped with other atoms (doping) to add or subtract electrons. • An N-type semiconductor material has extra free electrons with negative charges (doping atoms are donor atoms with positive charge, they lose their electron) . • A P-type semiconductor material has a shortage of electrons with vacancies called holes positive charges (doping atoms are acceptor atoms with negative charge, they accept electrons). • By controlling the doping of silicon the semiconductor material can be made as conductive as desired. Energy Band of Semiconductors The electrons in free atoms can be found only in certain discrete energy states (quantum mechanic). These sharp energy states are associated with the orbits or shells of electrons in an atom Energy Band of Semiconductors When atoms come together to form a compound, their atom orbital energies mix to form molecular orbital energies. As more atoms begin to mix and more molecular orbitals are formed, it is expected that many of these energy levels will start to be very close to, or even completely degenerate, in energy. These energy levels are then said to form bands of energy. Energy Band of Semiconductors e: free electrons h: holes e: tightly bound electrons Valence Band: The band of energy where all of the valence electrons reside and are involved in the highest energy molecular orbital. Electrons are tightly bound and holes are free to move throughout the crystal lattice. Conduction Band: where electrons freely move throughout the crystal lattice and are directly involved in the conductivity of semiconductors Energy gap: Is the minimum energy required to break a covalent bond and generate free electron-hole pairs Energy Band of Semiconductors −∆𝐸𝐶𝐹 𝑛 ∝ 𝑒𝑥𝑝 𝐾𝑇 −∆𝐸𝐹𝑉 𝑝 ∝ 𝑒𝑥𝑝 𝐾𝑇 ∆𝐸𝑔𝐶𝐹 = 𝐸𝐶 − 𝐸𝐹 ∆𝐸𝑔𝐹𝑉 = 𝐸𝐹 − 𝐸𝑉 K is Boltzmann constant, T is temperature KT=26meV is the thermal energy in room temperature Fermi level: the chemical potential of electrons in steady state, and its value represents the concentration of free electrons (n) and holes (p) in the semiconductor Energy Band of intrinsic Semiconductors At room temperature, sufficient thermal energy exists to break some of the covalent bonds, resulting in a production of electron-hole pairs (thermal generation). These electrons are free and can conduct when electrical field is applied. In this process , the number of electrons and holes are equal: 𝒏 = 𝒑 ≡ 𝒏𝒊 The Fermi level is equal to the intrinsic level 𝑬𝑭 = 𝑬𝒊 = 𝑬𝒈 𝟐 ni is called the intrinsic carrier density (1/cm^3) Energy Band of intrinsic Semiconductors Some numbers @ Room Temperature (RT): T=300K Energy gap Eg Density of intrinsic carrier ni Density of atoms units eV Germanium Silicon 0.72 1.1 Maybe the number of ni seem large, however, to put it into context, we should compare it to the density of atoms and we will find that only 1 atom from 5xE12 atoms contribute to the conductivity in room temperature. Mass action law: 𝒏 ∙ 𝒑 = 𝒏𝒊 𝟐 −∆𝐸𝐶𝐹 𝑛 ∝ 𝑒𝑥𝑝 𝐾𝑇 −∆𝐸𝐹𝑉 𝑝 ∝ 𝑒𝑥𝑝 𝐾𝑇 −∆𝐸𝐶𝐹 − ∆𝐸𝐹𝑉 𝑛 ∙ 𝑝 ∝ 𝑒𝑥𝑝 𝐾𝑇 −∆𝐸𝑔 𝑛 ∙ 𝑝 ∝ 𝑒𝑥𝑝 𝐾𝑇 Energy Band of extrinsic Semiconductors n-type: Doping the semiconductor with atoms having 5 valence electrons. e: free electrons by doping e: free electrons by thermal h: holes by thermal Donors (dopant atoms) Donors change the Fermi level toward the conduction level ∆𝑬𝒈𝑪𝑭 < 𝑬𝒈 𝟐 • Donors level: is the energy level of dopant atoms and it is approximated to be equal to the conductance level ED≈EC. Every dopant atom donates one free electron to the semiconductor and therefor their charge is positive. • Doping process generates only free electrons without any holes. All the holes in the n-type are those generated by thermal process. • Free electrons has two sources: (1) Donors and (2) thermal process. Generally the contribution of doping process is much larger than thermal process. Energy Band of extrinsic Semiconductors How to calculate the concentration of free electrons and holes in n-type? 1. We assume that the concentration of free electrons produced by doping is much larger than electrons produced by thermal energy 𝒏𝒏 ≈ 𝑵𝑫 ND is the concentration of donors nn is the concentration of total free electrons in n-type 2. Holes in n-type (pn) generates only by thermal process 3. Mass action law is also correct in extrinsic semiconductor 𝒏𝒊 𝟐 𝒑𝒏 = 𝑵 𝑫 𝒏𝒏 ∙ 𝒑𝒏 = 𝒏𝒊 𝟐 Given an n-type silicon semiconductor @ T=300K, Dopant concentration (ND) is 1E+17/cm^3, Find the concentration of holes (pn) and electrons (nn)? nn=ND=1E+17/cm^3, ni (@T=300K)=1.5E+10/cm^3 pn=(1.5E+10)^2/(1E+17)=2.25+E3/cm^3 n-type: electrons are majority and holes are minority Energy Band of extrinsic Semiconductors p-type: Doping the semiconductor with atoms having 3 valence electrons. h: holes by doping h: holes by thermal e: free electrons by thermal Acceptors (dopant atoms) Acceptors change the Fermi level toward the valence level ∆𝑬𝒈𝑭𝑽 < 𝑬𝒈 𝟐 • Acceptor level: is the energy level of dopant atoms and it is approximated to be equal to the valence level EA≈EV. Every dopant atom accept one electron and produce one hole and therefor their charge is negative. • Doping process generates only holes. All the free electrons in the p-type are those generated by thermal process. • Hole has two sources: (1) Acceptors and (2) thermal process. Generally the contribution of doping process is much larger than thermal process. Energy Band of extrinsic Semiconductors How to calculate the concentration of free electrons and holes in p-type? 1. We assume that the concentration of holes produced by doping is much larger than holes produced by thermal energy 𝒑 𝒑 ≈ 𝑵𝑨 NA is the concentration of acceptors pp is the concentration of total holes in p-type 2. Free electrons in p-type (np) generates only by thermal process 3. Mass action law is also correct in extrinsic semiconductor 𝒏𝒊 𝟐 𝒏𝒑 = 𝑵 𝑨 p-type: holes are majority and electrons are minority 𝒏𝒑 ∙ 𝒑𝒑 = 𝒏𝒊 𝟐 Energy Band of electronic material Eg~9eV Eg~1.1eV Eg<26meV Conduction band is empty Conduction band Conduction band is fully filled is partially filled Carrier Transport in semiconductors How can current flow in semiconductors? First condition: having free electrons or holes in the semiconductor Can the thermal energy give a force to electrons/holes to move? Yes, Kinetic energy = Thermal energy 𝟏 𝒎 𝟐 𝒆𝒇𝒇 ∙ 𝒗𝒕𝒉 𝟐 = 𝑲𝑻 𝟐 meff: effective mass of electrons/holes vth : average thermal velocity In silicon, for electrons: 𝑚𝑒𝑓𝑓 = 2.37 × 10−31 𝑘𝑔 𝐾 = 1.38 × 2 𝑚 ∙𝑘𝑔 10−23 𝑠𝑒𝑐 2∙𝑘 , 𝑇 = 300𝑘 𝑣𝑡ℎ = 1 × 107 𝑐𝑚/𝑠𝑒𝑐 Electrons/holes are moving rapidly in all directions. Their thermal motion is random because electrons/holes impact with atoms of the semiconductor (scattering. As a results the net current is zero. Carrier Transport in semiconductors Having free electrons or holes in semiconductors with thermal energy is not enough to get a flow of electrons. We need an external force to give a direction to the motion of electrons/holes 1. Drift 2. Diffusion Carrier Transport: Drift When a small electric field (E) is applied to the semiconductor sample, each electron will experience a force –qE from the field and will be accelerated along the field (in the opposite direction to the field) during the time between collisions. Therefore, an additional velocity component will be superimposed upon the thermal motion of electrons. This additional component is called the drift velocity. The combined displacement of an electron due to the random thermal motion and the drift component is illustrated in Fig. Note that there is a net displacement of the electron in the direction opposite to the applied field. E=0 Random thermal motion: net flow is zero E Combined motion due to random thermal motion and an applied electric field. Carrier Transport: Drift lc : mean free path- average distance between collisions τc: mean free time- average time between collisions lc The force (F) that is applied on electron with effective mass (mneff) when electrical field (E) is applied: 𝑭 = −𝒒 ∙ 𝑬 = 𝒎𝒏𝒆𝒇𝒇 ∙ 𝒗𝒏 𝝉𝒄 q is the charge of electron (1.6 × 10-19 coulombs) vn is the electron drift velocity of electron 𝒗𝒏 = − 𝒒∙𝝉𝒄 𝒎𝒏𝒆𝒇𝒇 ∙𝑬 The electron drift velocity is proportional to the applied electric field. That depends on the mean free time and the effective mass Carrier Transport: Drift We define new parameter “ electron mobility” with units cm2/(V⋅sec) that describes how strongly the motion of an electron is influenced by an applied electric field 𝝁𝒏 ≡ 𝒒∙𝝉𝒄 𝒎𝒏𝒆𝒇𝒇 𝒗𝒏 = −𝝁𝒏 ∙ 𝑬 𝝁𝒑 ≡ 𝒒∙𝝉𝒄 𝒎𝒑𝒆𝒇𝒇 𝒗𝒑 = 𝝁𝒑 ∙ 𝑬 Similar expression can be written for holes in the valence band. vp is the hole drift velocity and μp is the hole mobility. The negative sign is removed because holes drift in the same direction as the electric field. The mobility of electrons for intrinsic silicon is [1350 cm2/(V⋅sec)] larger than the mobility of holes [480 cm2/(V⋅sec)] (why?) The mobility depends on concentration of dopant atoms, why? The mobility depends on temperature, why? Carrier Transport: Drift The mobility is related directly to the mean free time between collisions, which in turn is determined by two dominant scattering mechanisms: 1. Lattice scattering results from thermal vibrations of the lattice atoms. Since lattice vibration increases with increasing temperature, lattice scattering becomes dominant at high temperatures; mobility decreases with increasing temperature 2. Impurity scattering results when a charge carrier travels past a positive/negative dopant (donor or acceptor). The charge of dopants affect the charge of electrons/holes. At higher temperatures, the carriers move faster (they gain energy); they remain near the dopant for a shorter time mobility decreases with increasing temperature Therefore, there is a tradeoff between mobility and temperature. Drift Current Calculate the drift current in semiconductor: The total drift current is equal: 𝑰 = 𝑰𝒏 + 𝑰𝒑 Electron drift current with charge (-q): V : voltage applied on the sample [V] A: surface area [cm2 ] L: length [cm] n: electrons concentration [cm-3] p: holes concentration [cm-3] q: electron charge [coulomb] vn : electron drift velocity [cm/sec] vp: hole electron velocity [cm/sec] E: electrical field [V/cm] μn: electron mobility [cm2/(V⋅sec)] μp: hole mobility [cm2/(V⋅sec)] Hole drift current with charge (+q): 𝑰𝒏 = −𝑨 ∙ 𝒒 ∙ 𝒏 ∙ 𝒗𝒏 𝑰𝒑 = 𝑨 ∙ 𝒒 ∙ 𝒑 ∙ 𝒗𝒑 𝒗𝒏 = −𝝁𝒏 ∙ 𝑬 𝒗𝒑 = 𝝁𝒑 ∙ 𝑬 𝑰𝒏 = 𝑨 ∙ 𝒒 ∙ 𝒏 ∙ 𝝁𝒏 ∙ 𝑬 𝑰 𝒑 = 𝑨 ∙ 𝒒 ∙ 𝒑 ∙ 𝝁𝒑 ∙ 𝑬 Drift Current The total drift current is equal: 𝑰 = 𝑨 ∙ 𝒒 ∙ (𝒏 ∙ 𝝁𝒏 + 𝒑 ∙ 𝝁𝒑 ) ∙ 𝑬 We define the current density as : 𝑰 𝑱 = = 𝒒 ∙ (𝒏 ∙ 𝝁𝒏 + 𝒑 ∙ 𝝁𝒑 ) ∙ 𝑬 𝑨 By ohm’s law, we have defined resistivity ρ [Ω∙cm]: 𝝆= 𝑬 𝑱 ⇒ 𝝆= 𝟏 𝒒∙(𝒏∙𝝁𝒏 +𝒑∙𝝁𝒑 ) And conductivity σ [1/ Ω∙cm]: 𝝈≡ 𝟏 𝝆 The electrical field E=V/L 𝑰= 𝑨 𝑳∙𝝆 ∙𝑽 𝑰=𝑽 𝑹 Resistor 𝑳 𝑹=𝑨∙𝝆 = 𝒒 ∙ (𝒏 ∙ 𝝁𝒏 + 𝒑 ∙ 𝝁𝒑 ) Diffusion Current Calculate the diffusion current in semiconductor: Diffusion current results from the random thermal motion of carriers in from a region of high concentration to a region of low concentration. Diffusion is a result of thermal motion: ⇒ 𝒗 = 𝒗𝒕𝒉 = 𝑳𝒄 𝝉𝒄 The current density at x = 0 due to carriers that originate at x = -Lc and move from left to right equals: 𝑱𝟏(𝒍𝒆𝒇𝒕→𝒓𝒊𝒈𝒉𝒕) = 𝒒 ∙ 𝒗𝒕𝒉 ∙ 𝒏(𝒙 = −𝑳𝒄 ) 𝟐 where the factor 1/2 is due to the fact that electrons have equal probability to move left or right Lc is the free mean path due to thermal motion vth average thermal velocity Diffusion Current The flux at x = 0 due to carriers that originate at x = Lc and move from right to left, equals: 𝑱𝟐(𝒓𝒊𝒈𝒉𝒕→𝒍𝒆𝒇𝒕) = 𝒒 ∙ 𝒗𝒕𝒉 ∙ 𝒏(𝒙 = +𝑳𝒄 ) 𝟐 The total flux of carriers moving from left to right at x = 0 equals to carriers moving from right to left is subtracted from the flux due to carriers moving from left to right 𝑱= 𝒒∙𝒗𝒕𝒉 𝟐 ∙ 𝒏 𝒙 = +𝑳𝒄 − 𝒏(𝒙 = −𝑳𝒄 ) ⇒ 𝑱 = 𝒒 ∙ 𝒗𝒕𝒉 ∙ 𝑳𝒄 ∙ 𝒏 𝒙=+𝑳𝒄 −𝒏(𝒙=−𝑳𝒄 ) 𝟐∙𝑳𝒄 Diffusion Current For Lc 0: 𝒏 𝒙 −𝒏 𝒙+𝑳𝒄 𝑳𝒄 ≈ 𝒅𝒏 𝒅𝒙 Diffusion current density is equal to: 𝑱 = 𝒒 ∙ 𝑫𝒏 ∙ 𝒅𝒏 𝒅𝒙 𝟐 Dn is the diffusion coefficient for electrons [cm2/sec]: 𝑫𝒏 = 𝒗𝒕𝒉 ∙ 𝑳𝒄 = 𝑳𝒄 𝝉𝒄 Einstein Relation between mobility and diffusion: 𝑫𝒏 = 𝒗𝒕𝒉 ∙ 𝑳𝒄 = 𝒗𝒕𝒉 ∙ 𝒗𝒕𝒉 ∙ 𝝉𝒄 = 𝒗𝒕𝒉 𝟐 ∙ 𝝉𝒄 𝟏 𝒎𝒆𝒇𝒇 𝟐 𝝁𝒏 ≡ ∙ 𝒗𝒕𝒉 𝟐 = 𝒒∙𝝉𝒄 𝒎𝒏𝒆𝒇𝒇 𝑲𝑻 𝟐 𝑲𝑻 𝒗𝒕𝒉 𝟐 = 𝒎 𝒏𝒆𝒇𝒇 𝝉𝒄 = 𝝁𝒏 ∙𝒎𝒏𝒆𝒇𝒇 𝒒 𝑫𝒏 = 𝝁𝒏 ∙ 𝑲𝑻 𝒒 Current Density Equations When an electric field is present in addition to a concentration gradient, both drift current and diffusion current will flow. The total current density at any point is the sum of the drift and diffusion components: 𝒅𝒏 Current density for electrons: 𝑱𝒏 = 𝒒 ∙ 𝝁𝒏 ∙ 𝒏 ∙ 𝑬 + 𝒒 ∙ 𝑫𝒏 ∙ 𝒅𝒙 Current density for holes: 𝑱𝒑 = 𝒒 ∙ 𝝁𝒑 ∙ 𝒑 ∙ 𝑬 − 𝒒 ∙ 𝑫𝒑 ∙ Total Current density for electrons and holes: 𝒅𝒑 𝒅𝒙 𝑱 = 𝑱𝒏 + 𝑱𝒑