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Uncertainties and significant figures How big is the beetle? Measure between the head and the tail! Between 1.5 and 1.6 in Measured length: 1.54 in The 1 and 5 are known with certainty The last digit (4) is estimated between the two nearest fine division marks. Copyright © 1997-2005 by Fred Senese Return to TOC Uncertainties and significant figures Uncertainty in measurements • A digit that must be estimated in a measurement is called uncertain. • A measurement always has some degree of uncertainty. It is dependent on the precision of the measuring device. Return to TOC 2 Uncertainties and significant figures Significant Figures • In science, measured values are reported in terms of significant figures. • Significant figures in a measurement consist of all the digits known with certainty plus one final digit, which is uncertain or is estimated. • The term significant does not mean certain. • Insignificant digits are never reported. Return to TOC Uncertainties and significant figures What value should be recorded for the length of this nail? 6.35 Uncertain or estimated number but significant. Return to TOC Uncertainties and significant figures Rules for Counting Significant Figures 1. Nonzero integers always count as significant figures. – 3456 has 4 sig figs (significant figures). 2. There are three classes of zeros. a. Leading zeros are zeros that precede all the nonzero digits. These do not count as significant figures. 0.048 has 2 sig figs. Return to TOC 5 Uncertainties and significant figures Rules for Counting Significant Figures Classes of zeros. b. Captive zeros are zeros between nonzero digits. These always count as significant figures. – 16.07 has 4 sig figs. c. Trailing zeros are zeros at the right end of the number. They are significant only if the number contains a decimal point. – 9.300 has 4 sig figs. – 150 has 2 sig figs. – 120. has 3 sig figs. Return to TOC 6 Uncertainties and significant figures Rules for Counting Significant Figures 3. Exact numbers have an infinite number of significant figures. – 1 inch = 2.54 cm, exactly. – 9 pencils (obtained by counting). Return to TOC 7 Uncertainties and significant figures Sample Problem How many significant figures are in each of the following measurements? a. 28.6 g 3 sig figs, no zeros, all digits are significant b. 3440. cm 4 sig figs, zero significant, followed by a decimal point c. 910 m 2 sig figs, the zero is not significant, no decimal point d. 0.046 04 L 4 sig figs, the first two zeros are not significant; the third zero is significant. e. 0.0067000 kg 5 sig figs, the first three zeros are not significant; the last three zeros are significant. Return to TOC Uncertainties and significant figures Significant Figures in Mathematical Operations 1. For multiplication or division, the number of significant figures in the result is the same as the number in the least precise measurement used in the calculation. 1.342 × 5.5 = 7.381 7.4 2 sig figures 2 sig figures Return to TOC 9 Uncertainties and significant figures Rounding Return to TOC Copyright © Cengage Learning. All rights reserved Uncertainties and significant figures Significant Figures in Mathematical Operations 2. For addition or subtraction, the result has the same number of decimal places as the least precise measurement used in the calculation. 23.445 7.83 31.275 Corrected 31.28 Return to TOC 11 Uncertainties and significant figures CONCEPT CHECK! You have water in each graduated cylinder shown. You then add both samples to a beaker (assume that all of the liquid is transferred). How would you write the number describing the total volume? 2.8 + 0.28 = 3.1 mL What limits the precision of the total volume? Return to TOC 12 Uncertainties and significant figures Exponential Notation • Example – 300. written as 3.00 × 102 – Contains three significant figures. • Two Advantages – Number of significant figures can be easily indicated. – Fewer zeros are needed to write a very large or very small number. Return to TOC 13