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Electrons
Chemistry
Dr. May
Atomic Inventory
• Protons (Atomic Number)
• Neutrons (Atomic Mass minus Protons)
• Electrons (Same number as protons)
Atomic Particles
Particle
Proton
Neutron
Electron
Location
Mass in
amu
Charge
nucleus
1
+1
nucleus
1
0
cloud
0
1
Electron Function
• Only the electrons of an atom are involved
in chemical reactions
• Only the electrons in the outermost orbital
are involved in chemical reactions
Outermost Electrons
• Atoms have between 1 and 8 electrons in
the outermost orbital
• These electrons are called valence electrons
• Only valence electrons are involved in
chemical reactions
Electron Distribution and
Configuration
Atom
1s
Ca - 40 
EC
1s2
2s
2p
3s
3p
4s
        
2s2
2p6
3s2
3p6
4s2
Electron Configuration
• Krypton
– 1s22s22p63s23p64s23d104p6
• Sodium
– 1s22s22p63s1
• Chlorine
– 1s22s22p63s23p5
Reading Electron Configurations
• Krypton - 1s22s22p63s23p64s23d104p6
• The large numbers are the orbitals
and in the known elements can go
from 1 to 7
Reading Electron Configurations
• Krypton - 1s22s22p63s23p64s23d104p6
• The letters s,p,and d represent the
suborbitals
• The fourth letter f is not used in Kr
Suborbitals
• The suborbitals (s,p,d and f) are named after
lines in the electromagnetic spectrum:
s = sharp
p = principle
d = diffuse
f = fundamental
Metal Salts Burning
Reading Electron Configurations
• Krypton - 1s22s22p63s23p64s23d104p6
• The superscript or exponent (2p6)
represents the number of electrons
in each suborbital
• Kr has 6 electrons in the 2p
Valence Electrons
• Krypton - 1s22s22p63s23p64s23d104p6
has 8 valence electrons
• Sodium - 1s22s22p63s1
has 1 valence electron
• Chlorine - 1s22s22p63s23p5
has 7 valence electrons
Element 118
• 1s22s22p63s23p64s23d104p65s24d105p66s24f14
5d106p67s25f146d107p6
• Element 118 (ununoctium) (Uuo)
•
•
•
•
Has 118 electrons
Has 8 valence electrons
Is an inert gas
Was discovered at Berkley in 1999
Valence Electrons
Sum of the outermost s an p electrons
• Na = 1
• N=5
• Ca = 2
• O=6
• Al = 3
• Cl = 7
• C=4
• Ne = 8
Oxidation Number
Number of valence electrons lost (+) or gained (–)
during a chemical reaction
• Na = (1) +1
• N = (5) +5 or –3
• Ca = (2) +2
• O = (6) –2
• Al = (3) +3
• Cl = (7) –1
• C = (4) +4 or –4
• Ne = (8) 0
Distribution Of Sodium
atom
Na - 11
1s
2s
2p
3s
     
3p
4s
Distribution Of Sodium Ion
ion
Na+1
1s
2s
2p
3s
     X
3p
4s
Distribution Of Chlorine
atom
Cl - 17
1s
2s
2p
3s
3p
        
4s
Distribution Of Chloride Ion
ion
Cl  1
1s
2s
2p
3s
3p
        
4s
Opposite Charges Attract
The End
• This presentation was created for the benefit
of our students by the Science Department
at Howard High School of Technology
• Please send suggestions and comments to
[email protected]
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