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Round 2 Monday, October 12, 2015 High Four Chemistry Category C: Grades 9 – 10 The use of calculator is required. Answer #1: Solution: 80 1.85g mass of sulfuric acid = 45.05 mL � mass of sulfuric acid = 80 grams mL solution� � 96.0 g acid 100 g solution � Answer#2: Explanation: Evaporation / Vaporization Evaporation / vaporization is the phase change where liquid vaporizes to gas. The NaCl aqueous solution is a mixture of salt (solid) and water (liquid). When heated, water evaporates and salt remains. Answer#3: C Answer#4: Solution: 27.26°C q = mcp ∆t 945 J q = = 3.76℃ ∆t = mcp (60g) �4.184 J ∙ ℃� ∆t = t final − t initial t final = 3.76℃ + 23.5℃ t final = 27.26℃ Answer#5: Solid Answer#6: Bromine trifluoride g Round 2 Monday, October 12, 2015 High Four Chemistry Category C: Grades 9 – 10 The use of calculator is required. Answer#7: Explanation: Sulfur Balance the nuclear reaction. The sum of atomic numbers on the left side is 17. To obtain an equal sum of 17 on the right side, we compute: 17 – 1 = 16. The atomic number of the unknown isotope is 16. Based on the periodic table, the atomic number 16 identifies the element as Sulfur. Answer#8: Solution: 47 MWCaSO4 = 136.15 g/mol Basis: 1 mol of CaSO4 16gO 4molsO �� � 1molCaSO4 1molO = 64 grams of Oxygen grams of O = 1 mol CaSO4 � % by mass of Oxygen = Answer#9: Potassium Answer#10: Solution: 2 grams of CH4 = 3.01x1023 H atoms � 64 grams O x 100 = 47.01% ≈ 47% 136.15 grams CaSO4 1 CH4 mol 16g 1 H mol CH4 � � � �� 4 H mol mol 6.02283 x 1023 atoms grams of CH4 = 2.01 grams ≈ 2 grams Round 2 Monday, October 12, 2015 High Four Chemistry Category C: Grades 9 – 10 The use of calculator is required. Answer#11: Solution: Nitric Acid The balanced chemical equation is as follows: HNO3 + NaOH → NaNO3 + H2O 0.85 mol NaOH � 1 mol HNO3 � = 0.85 mol HNO3 1 mol NaOH The theoretical number of moles of HNO3 required for this reaction is only 0.85 mol. There is an excess of 0.05 moles (the given is 0.90 mol). Therefore, nitric acid is the excess reactant. Answer#12: 17 Answer#13: Solution: 9.19 Manipulate the formula ρ = V= Answer#14: Solution: 0.125 kg x � 101.11 g 1000 g 1 kg �13.6 ml� Atomic weights of K: N: O: � m V to arrive at V = m ρ = 9.19 mL 39.10 14.01 16.00 Molecular weight of KNO3 = 39.10 + 14.01 + 3(16.00) = 101.11 g/mol Answer#15: Explanation: Beta Emission In the given reaction, I-131 gives off a beta particle (the electron) and an isotope. Round 2 Monday, October 12, 2015 High Four Chemistry Category C: Grades 9 – 10 The use of calculator is required. Answer#16: Solution: 4.34 mol 1L � �1.03 � = 0.0743 mol L 1000mL 58.44 g grams of NaCl = 0.0743 mol � � = 4.34 g NaCl mol mol of NaCl = 72.1mL � Answer#17: Solution: 0.90 1000g � = 2,250 grams 1kg 100cm length, l = 2.0 m � � = 200 cm 1m 10cm width, w = 0.5 dm � � = 5 cm 1dm thickness, t = 2.5 cm mass, m = 2.25 kg � Volume, V = l x w x t = (200cm)(5cm)(2.5cm) = 2,500 cm3 = 2,500 mL Answer#18: Explanation: Density, ρ = 202 g 2,250 g = 0.90 mL 2,500 mL chemical symbol mass no. (p+ + n0) 286 84 atomic no. (p+) X n0 = mass no. – atomic no. n0 = 286 – 84 n0 = 202 Round 2 Monday, October 12, 2015 High Four Chemistry Category C: Grades 9 – 10 The use of calculator is required. Answer #19: Explanation: Homogeneous Homogeneous mixtures are mixtures that look the same throughout the sample, even with the use of a microscope. Answer #20: Explanation: 2 The balanced chemical equation for the reaction is: Mg(HCO3)2 + 2HBr MgBr2 + 2H2O + 2CO2 Based on the equation above, two (2) moles of carbon dioxide will be produced.