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Chapter 12: Thermal Energy Honors Physics Teacher Notes - Grothaus Main Idea: “Thermal Energy is related to the motion of an object’s particles and can be transferred and transformed” Only doing section one. Section two is covered in chemistry – don’t need to do it this year Thermal Energy: Look at a balloon. Is anything moving inside? What is the energy of something moving called? What happens when the movement increases (velocity)? 1 2 Kinetic energy – energy of movement. Formula: KE mv 2 What happens as v increases? What happens if v=0? Kinetic energy of moving molecules increases as the velocity of the particles increases. When we are talking about particles within an object or in a gas, we can feel the kinetic energy as thermal energy (not “heat”). More movement, more kinetic energy = more thermal energy. However, when we are talking temperature of a substance, it is affected by the average kinetic energy of the particles! Why average?? Temperature is directly proportional to the average kinetic energy of a substance. Two substances that have the same temperature have the same average kinetic energy. Bucket of hot water has more KE than a glass of water at a higher temperature, but the average KE of the water in the glass is higher. Look at our balloons. If we blow up two the same size, what would happen if we stuck one in the freezer for 15 minutes while someone holds the other in their hands, or even puts it over the heat lamp for 15 minutes? Gases vs. Solids – how are they different? Atoms aren’t free to move around in a solid, but higher kinetic energy still means more thermal energy. It gets hotter! Can a solid also get bigger? Train tracks, concrete slabs, etc. Demo – soda can on hot plate “When matter gets warmer, the atoms or molecules in the matter move faster” (take up more room or less room?) Honors Physics: 2014-2014 Page 1 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Question: What happens when you leave an open soda on the counter? Soda can demo, balloon on flask demo Temperature: “Temperature is the quantity that tells how hot or cold something is compared with a standard”. Not one of your vocabulary words, but should be. Temperature depends only on the average KE of the particles in an object. Not – number of particles Thermal energy, however depends on both. Same temperature, but the bigger muffin has 10 times the number of particles, so it has 10 times the thermal energy. Small glass of hot water vs. large bucket of cold water? Another example – total points vs. average grade in different classes How do you normally measure temperature? What are the three scales we normally use? Three different scales: 1. Fahrenheit – United States only 32 degrees - water freezes and 212 degrees - water boils 2. Celsius – makes sense 0 - water freezes and 100 - water boils Most used in the world 20º is room temperature, body temp is 37º (1741 – by Anders Celsius - based on the properties of water) 3. Kelvin – scientific temperature scale -- SI unit for temperature Its degrees are the same size as the Celsius degrees and called Kelvins 0 is the lowest possible temperature – called absolute zero N At absolute zero – no movement of atoms and molecules – zero KE -273 degrees C Explanation of absolute zero: Honors Physics: 2014-2014 Page 2 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy https://www.youtube.com/watch?v=TNUDBdv3jWI Which of the above scales has the smallest degree size? Equilibrium and Thermometers: (begin water boiling) How do you measure your body heat? How do you measure the temperature in a room? We spent a lot of time last semester talking about equilibrium. Most things want to be in equilibrium. Same with thermal energy. – Thermal Equilibrium In a gas, the molecules spread out – see p. 322, figure 4 In a liquid, same thing – remember that ‘fluids” in physics means both gases and liquids. In a solid? - how quick depends….. A thermometer works because the fluid inside (mercury, colored alcohol) reaches thermal equilibrium with it’s surroundings. Technically, a thermometer does not measure the temperature of the air or your body, it measures it’s own temperature as it reaches thermal equilibrium with its surroundings. Demos Are they really at different temperatures? Take a cake out of the oven – pan vs. cake – which is hotter? Heat When you touch a hot stove, energy transfers into your hand because the stove is hotter than your hand. Energy always goes from the warmer substance to the cooler substance. That energy that transfers from one thing to another because of a difference in temperature is called heat. Things do not technically contain heat. Matter contains energy in several forms, but it does not contain heat. Heat is energy in transit, moving from something with a higher temperature to something with a lower temperature. When two objects are in contact and heat flows from one to another, they are in thermal contact. Always: When two substances of different temperatures are in thermal contact, heat flows from the higher-temperature substance to the lower temperature substance. Missed things from last time? : Explanation of absolute zero: https://www.youtube.com/watch?v=TNUDBdv3jWI Honors Physics: 2014-2014 Page 3 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Veritasium – misconceptions about heat: https://www.youtube.com/watch?v=vqDbMEdLiCs Minute physics: https://www.youtube.com/watch?v=yXT012us9ng If time – How hot can things get - https://www.youtube.com/watch?v=4fuHzC9aTik Why does touching a hot object cause damage in your skin? It's a matter of energy transfer. Temperature can be thought of as a measure of the average kinetic energy of the molecules in a substance. When a hot object (like a stove eye) comes into contact with a cooler object (like a human hand), the faster moving molecules in the stove eye bump into (and tranfer some of their kinetic energy into) the molecules in your hand. This causes the molecules in your hand to move faster, creating a rise in the temperature of your hand. This is called thermal conduction. If molecules in your hand received enough energy, they can be altered. In the case of proteins and enzymes, certain temperature ranges are required for them to retain their functional shape. Heat them up too much and they get "bent out of shape" and lose their function. That's obviously not a good thing for your body. This occurs at relatively lower temperatures than the following effects. At higher temperatures, the water in your skin may boil. As water boils, it expands greatly in volume. Cells are mostly water, so if the water within them boils, they will burst. Even higher up, certain substances within your body (such as sugars, fats, and proteins) will begin to burn. Burning a substance greatly alters its chemical structure. When you burn an organic substance, you typically get water vapor and carbon dioxide (among other gases) as a by-product. A human being obviously cannot survive in the form of gas. So in conclusion, high temperatures cause injury by altering the chemicals in your body, either by changing their shape (like enzymes) changing their phase (like water), or changing their composition (like carbohydrates and lipids). It's also possible that certain connective substances in your tissues like collagen might be melted by high temperatures, but I'm less sure of this. Worksheet on temperature scales? Three different types of heat transfer: Heat can be transferred by conduction, by convection, and by radiation. Conduction Demo with hot water The heat transfers material by conduction. Conduction of heat is the transfer of energy within materials and between materials that are in direct contact (thermal contact). Materials that conduct heat well are known as heat conductors. Metals are the best conductors. Silver is the best, then copper, aluminum and iron. (ice melting in video) How does it work? Remember that the higher the temperature, the faster the atoms or molecules move. As they move faster, they start to collide with the atoms or molecules that are next to them. Faster moving molecules mean higher temperature, which then causes them to collide with the next molecules, etc. In conduction, collisions between particles transfer thermal energy, without any overall transfer of matter. Honors Physics: 2014-2014 Page 4 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Conductors Metals are good conductors because they have atoms with “loose” outer electrons. They are good conductors of heat AND electricity. The looser the outer electrons, the better the conductor. Wood on the other hand, doesn’t conduct heat very well. Poor conductors are called insulators. Other examples are wool, straw, paper and cork. (Balloon?) Question: If you hold one end of a metal bar against a piece of ice, the end in your hand will soon become cold. Does cold flow from the ice to your hand? Insulators: Liquids and gases are generally good insulators. An insulator is any material that is a poor conductor of heat and delays the transfer of heat. Air is a very good insulator. Porous materials with small air spaces are good insulators: wool, fur and feathers Birds stay warm in the cold because they fluff their feathers and cause air pockets between the feathers and the bird’s skin. Snowflakes have a lot of air caught in their crystals and act as good insulators. Like a blanket, warm clothes, insulation in a house, etc., snow does not a source of heat, it just keeps the heat from escaping too fast. Question: What adaptations do polar bears have to be able to live up in the arctic? Blubber, thick hide, black skin, fur is hollow and transparent They actually tend to over heat – slow movement, swimming Question: If you are driving around in the north during winter and you see some houses with lots of icicles hanging from the eaves, and others with very few icicles. Explain what is going on with respect to insulation. Heat is energy. Cold is not – merely the absence of heat! No insulation is perfect. Eventually the heat will get out, but just a lot slower! https://www.youtube.com/watch?v=eDAQPxR9-YM sleek geeks – physics of firewalking https://www.youtube.com/watch?v=7dgpsI1MdQI mythbusters – Adam walks on hot coals What is fire?: Honors Physics: 2014-2014 Page 5 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy https://www.youtube.com/watch?v=1pfqIcSydgE Fire in space: https://www.youtube.com/watch?v=9zdD7lfB0Fs Convection Conduction involves the transfer of energy from molecule to molecule. Energy moves, but the molecules do not Convection is a means of heat transfer by movement of the heated substance itself, such as by currents in a fluid. (molecules do move) Only happens in fluids – not solids You’ve heard that warm air rises. Air above a stove will rise and heat the air above. In convection, heat is transferred by movement of the hotter substance from one place to another. When you heat a pot of water, the water expands, becomes less dense and rises. It rises in the same way that wood floats on water. The less dense material gets pushed up by the denser surrounding fluid. Cooler water then moves to the bottom, heats up and floats up, etc. Air does the same thing. Picture on page 434 – Different parts of the surface of the Earth heat at different rates. Water can absorb a lot of heat. Land gets warm faster during the day, but then cools down faster after the sun goes down. This difference causes air currents. (Camp fires on shore – which way will the fire lean?) Warm air expands and then rises. As it rises, it cools down This temperature difference on different surfaces of the Earth is the major cause of wind patterns. Convection in action! Honors Physics: 2014-2014 Page 6 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Atmospheric turbulence is caused by convection of gases in the atmosphere. Thunderstorms and hurricanes are excellent examples of large-scale atmospheric convection. Ocean currents that move water and materials over large distances also result from convection! Natural Convection in a fish tank: https://www.youtube.com/watch?v=eAHxhYBaEFo Demo: Candle flame: hand above vs. fingers to the side (like about to pinch it) Why does this work? Convection causes the hot air to rise – not go to the side Conduction would bring the heat to your fingers, but air is a good insulator! Important – why do shore breezes patterns change from day to night? See graphic below. Radiation How does the sun warm Earth’s surface? Conduction? Honors Physics: 2014-2014 Page 7 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Why not? Convection? Why not? The sun’s heat is transmitted by radiation. Radiation is energy transmitted by electromagnetic waves. In radiation, heat is transmitted in the form of radiant energy or electromagnetic waves. Radiant energy includes radio waves, microwaves, infrared radiation (such as heat from a fireplace), visible light, ultraviolet radiation, X-rays and gamma rays. See poster on the wall. Will study the wavelength / frequency relationship in the next unit. Question: Why is it hotter at the equator than north or south of it? Flashlight on paper – horizontal vs. at an angle. Which one will get hotter? Candle flame: hand above vs. fingers to the side (like about to pinch it) Emission of Radiant Energy We absorb radiant energy from the sun, right? What would happen if we absorbed the energy without ever getting rid of some of it? All substances continuously emit radiant energy in a mixture of wavelengths. Low temperature objects (cooler) emit long waves. (low energy) Higher temperature objects (warmer) emit waves with shorter wavelengths (high energy) Every day temperatures emit long, lazy wavelengths – in between radio and light waves Shorter-wavelength infrared waves absorbed by our skin produce the sensation of heat. Heat radiation is infrared radiation. When we speak about heat radiation, we are speaking of infrared radiation. Infrared thermometers – like the aural (ear) thermometers! People with a surface temperature of 310 K, emit light in the low-frequency infrared part of the spectrum – can’t see each other in the dark If an object is hot enough, some of the radiant energy it emits is in the range of visible light. At about 500º C, an object begins to emit red light (the longest waves that we can see) Higher temps – yellow light (like sunlight), about 1500ºC, all colors – so “white hot” Stars: Blue-hot stars are hotter than white-hot stars and red-hot is less hot Honors Physics: 2014-2014 Page 8 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy “stellar radiation” - see graphic (our sun - 5500ºC) Below: Star Color Examples in the Fall / Winter http://mail.colonial.net/~hkaiter/life_cycle_of_a_star.htm Remember that the hotter the star – the shorter it’s life cycle Earth – radiant energy emitted by Earth is called terrestrial radiation Below our threshold of sight. Radiant energy is partly reflected and partly absorbed – when absorbed, it raises the thermal energy of the object (heats things up) Specific Heat: Some materials are easier to warm up than others. Beach sand vs. ocean water When an object is heated, its thermal energy increases and its temperature can increase. The amount of the increase in temperature depends on the size of the object and its composition. The specific heat of a material is the amount of energy that must be added to a unit mass of the material to raise its temperature by one temperature unit. In SI units, specific heat (C) is measured in J/(kgK). Can also be measured in J/(kgC), so watch units if you look at different tables. Change in temperature: T (degrees C or K) Heat (amt. of thermal energy transferred to the object): Q (joules) Honors Physics: 2014-2014 Page 9 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Mass: m (kg) Q mCT mC(T f Ti ) Units here are in grams, not kg. Always look at units given any table. Why is the specific heat of water so high compared to other materials? “Water has a high specific heat index—it absorbs a lot of heat before it begins to get hot. This is why water is valuable to industries and in your car's radiator as a coolant. The high specific heat index of water also helps regulate the rate at which air changes temperature, which is why the temperature change between seasons is gradual rather than sudden, especially near the oceans.” Concept check: 1. Water has an unusually high specific heat capacity. Which one of the following statements logically follows from this fact? a. Compared to other substances, hot water causes severe burns because it is a good conductor of heat. b. Compared to other substances, water will quickly warm up to high temperatures when heated. c. Compared to other substances, it takes a considerable amount of heat for a sample of water to change its temperature by a small amount. 2. Explain why large bodies of water such as Lake Michigan can be quite chilly in early July despite the outdoor air temperatures being near or above 90°F (32°C). Textbook problems: p. 326: 1 – 3; p. 342: 42, 43, 44 Bellwork: In your lab notebook: p. 329: 9, 11, 13, 16, 17, 18 Honors Physics: 2014-2014 Page 10 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Newton’s Law of Cooling Yes, another law attributed to Newton! Common sense! This one states that the rate of cooling of an object – whether by conduction, convection or radiation – is approximately proportional to the temperature difference ΔT between the object and its surroundings. Take a cup of warm water and a cup of boiling water. Which one is going to cool faster? If you take cookies out of the oven and you want it to cool as fast as possible where would you put it? Same holds true for heating. Ice will melt a lot faster in a warm room than a cool room. Greenhouse Effect The Greenhouse effect is named after the way people use greenhouses to raise the temperature to be able to grow plants even in winter – florists, farmers, etc. Today, the greenhouse effect is mostly referred to when talking about the warming of a planet’s surface due to the trapping of radiation by the planet’s atmosphere. Causes of the Greenhouse Effect - 2 things to look at to understand 1. Remember that higher temperature objects radiate shorter (higher energy) wavelengths and that cooler objects radiate longer (lower energy) wavelengths. 2. Glass and air is transparent (lets light through) – but only to certain wavelengths of light. Air – transparent to both infrared (longer) waves and visible (shorter) waves. However, if there is an excess of carbon dioxide and water vapor, it then absorbs the infrared waves (doesn’t let it through). Glass – transparent to visible light waves but always absorbs infrared waves. Why does your car get so hot when it’s sunny out, even on a sunny winter day? The windshield (glass) absorbs the infrared rays, but lets in the shorter visible light rays (otherwise you couldn’t see out!) Honors Physics: 2014-2014 Page 11 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Some light will be reflected back out, but a lot of the light gets absorbed by the seats, dashboard, etc. in the car. The inside of the car heats up. These things then emit radiation back out, but because the heat in the car isn’t as hot as the sun, this radiation has much shorter wavelengths and can’t get back out of the glass. Most of the re-radiated energy stays in the car making the inside even warmer. As hot as the interior gets, it won’t radiate waves that will be able to get through the glass. https://www.youtube.com/watch?v=ZzCA60WnoMk NASA video simply explaining greenhouse effect Same thing happens in the atmosphere It is transparent to solar radiation – about 30% gets immediately reflected back out to space, but 70% gets into our atmosphere What gets in radiates the Earth and everything on it. These things then reradiate (terrestrial radiation) in longer wavelengths. Atmospheric gases (water vapor, carbon dioxide and methane – and clouds!) will then absorb and re-emit much of this terrestrial radiation back down to Earth. If not, Earth would be about 30ºC cooler! Best slideshow to review: http://slideplayer.com/slide/4617567/ Honors Physics: 2014-2014 Page 12 of 13 Honors Physics Teacher Notes - Grothaus Chapter 12: Thermal Energy Measuring Specific Heat: Calorimeter – will be doing experiment with this in Chemistry Closed system – want temperature changes to only be because of the reaction inside. Known: mass and temperature of the water (cold); mass and temperature of a hot substance Measured – after thermal equilibrium occurs, then measure the temperature of the water If the system is closed, then no loss of energy occurs That means that the amount of thermal energy that is lost from the hot substance has to equal the amount of thermal energy that the water gains. E A EB Note: a gain of thermal energy means an increase in temp. (positive) a loss of thermal energy means a decrease in temp. (negative) Since it is a closed system and there is no other energy changing (no work being done), then Q E mCT mC(Tf Ti ) Combining the two equations: mAC A (Tf TA ) mBC B (Tf TB ) or: CA mBC B (Tf TB ) mA (Tf TA ) How to solve for the final temperature? Practice problems: on a separate piece of paper: p. 328: 1, 3; p. 342: 45, 46 Answers to concept checks: Answer: C A substance with a high specific heat capacity is a substance that requires a relative large quantity of heat to cause a small temperature change. Because of this, water does not change its temperature as rapidly as other substances that are heated in the same manner; choice B does not logically follow. Specific heat capacity should not be confused with thermal conductivity. Thermal conductivity is the measure of the ability of a substance to conduct heat; choice A has to do with thermal conductivity. Lake Michigan is a body of water with a large m value and a large C value. It would take a lot of solar energy absorption to increase its temperature from the cold wintry temperatures to the higher summertime temperatures. It may take a couple of months of summer before the heating of the large mass of water is "complete." Honors Physics: 2014-2014 Page 13 of 13