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AT350 Introduction to Weather and Climate
Fog and Clouds
Condensation: Dew, Fog and Clouds
Please read Chapter 5 in Ahrens
Condensation
• Condensation is the phase
transformation of water vapor to liquid
water
• Water does not easily condense without
a surface present
– Vegetation, soil, buildings provide surface
for dew and frost formation
– Particles act as sites for cloud and fog drop
formation
Scott Denning
CSU Atmospheric Science
Spring 2008
Dew
• Surfaces cool strongly
at night by radiative
cooling
– Strongest on clear,
calm nights
• The dew point is the
temperature at which
the air is saturated
with water vapor
• If a surface cools
below the dew point,
water condenses on
the surface and dew
drops are formed
• Dew does not “fall”
1
AT350 Introduction to Weather and Climate
Fog and Clouds
Frost
Cloud and fog drop formation
• If the temperature is
below freezing, the
dew point is called the
frost point
• If the surface
temperature falls
below the frost point
water vapor is
deposited directly as
ice crystals
• If the air temperature cools below the dew
point (RH > 100%), water vapor will tend to
condense and form cloud/fog drops
• Drop formation occurs on particles known
as cloud condensation nuclei (CCN)
• The most effective CCN are water soluble.
• Without particles clouds would not form in
the atmosphere
– deposition
– RH of several hundred percent required for
pure water drop formation
• The resulting crystals
are known as frost,
hoarfrost, or white
frost
Typical Sizes
Very Small Drops Tend to Evaporate!
• Surface of
small drops are
strongly curved
• Stronger
curvature
produces a
higher esat
• Very high RH
required for
equilibrium with
small drops
– ~300% RH for
a 0.1 µm pure
water drop
Scott Denning
CSU Atmospheric Science
Spring 2008
If small drops evaporate, how
can we ever get large drops?!
2
AT350 Introduction to Weather and Climate
Fog and Clouds
The Solute Effect
Homogeneous Nucleation
• Condensation of water on
soluble CCN dissolves particle
• Formation of a pure water drop
without a condensation nucleus
is termed “homogeneous
nucleation”
• Random collision of water vapor
molecules can form a small
drop embryo
– Water actually condenses on
many atmospheric salt particles
at RH ~70%
• Some solute particles will be
present at drop surface
– Displace water molecules
– Reduce likelihood of water
molecules escaping to vapor
– Reduce esat from value for pure
water drop
– Collision likelihood limits maximum
embryo size to < 0.01 µm
• esat for embryo is several
hundred percent
Water molecule
– Embryo evaporates since
environmental RH < 100.5%
Solute molecule
Relative Humidity %
Curvature and Solute Effects Compete
Curves are equilibrium
droplet growth curves. Peak
of each curve is critical point
for cloud drop activation.
Can define corresponding
critical RH.
10-15
10-16 g g
Numbers
in red are
the mass
of the salt
condensation
nucleus
10-14 g
Steps in Cloud/Fog Formation
• Air parcel cools causing RH to increase
– Radiative cooling at surface (fog)
– Expansion in rising parcel (cloud)
• CCN (tenths of µm) take up water vapor
as RH increases
– Depends on particle size and composition
• IF RH exceeds critical value, drops are
activated and grow readily into cloud
drops (10’s of µm)
Droplet Radius (micrometers)
Scott Denning
CSU Atmospheric Science
Spring 2008
3
AT350 Introduction to Weather and Climate
Fog and Clouds
Where do CCN come from?
• Not all atmospheric particles are cloud condensation nuclei
(CCN)
• Good CCN are hygroscopic (“like” water, in a chemical sense)
• Many hygroscopic salt and acid particles are found in the
atmosphere
• Natural CCN
– Sea salt particles (NaCl)
– Particles produced from biogenic sulfur emissions
– Products of vegetation burning
More About CCN
Sulfate aerosol (SO42-)
SO2  H2SO4
• CCN from human activity
– Pollutants from fossil fuel combustion react in the atmosphere to
form acids and salts
– Sulfur dioxide reacts to form particulate sulfuric acid and
ammonium sulfate salts
– Nitrogen oxides react to form gaseous nitric acid which can
combine with ammonia to form ammonium nitrate particles
Fogs
Scott Denning
• CCN concentrations vary in
time and space
– Typically 100-1000 per cubic
centimeter
– High in polluted
environments
– Higher CCN concentrations
give rise to greater cloud
drop concentrations
• Climate impacts of these
more reflective clouds?
• Surface radiation and conduction of heat away from
the overlying air cool air temperatures near the
ground
• A layer of air near the ground becomes saturated and
fog forms
• Fog deepens as radiative cooling from the fog top
continues overnight
• Solar heating warms the ground and causes the fog to
“burn off” from the ground up
• What type of meteorological conditions would favor
radiation fog?
Radiation fog
Advection fog
Upslope fog
Evaporation (mixing)
fog
CSU Atmospheric Science
– Clouds ingest sulfur dioxide
(SO2)
– Chemical reactions in the
cloud drops convert
dissolved SO2 to soluble
forms of sulfate (SO4 2-)
– When the cloud drops
evaporate, soluble sulfate
particles are left behind
Radiation Fog
• Fogs are clouds in
contact with the
ground
• Several types of
fogs commonly form
–
–
–
–
SO2
• Clouds even contribute to
CCN production
Spring 2008
4
AT350 Introduction to Weather and Climate
Fog and Clouds
Advection Fog
•
•
•
•
Warm air moves (is advected) over cold surface
Cold surface cools warm air
If saturation is reached, fog forms
Common on west coast of U.S.
• Evaporation (mixing) fog
– Warm moist air from Pacific is advected over upwelling cold coastal waters
– As foggy air moves ashore, solar heating warms the ground and overlying
surface
• Fog evaporates near ground
– Coastal advection fogs are key moisture sources for California Redwoods
Fogs and Visibility
• Light scattering by fog drops (geometric
scatterers) degrades visibility, leading to
– Traffic fatalities
– Airport accidents and closures
• Remedies
– Fog monitoring and warning (optical sensors)
– Fog dispersal (expensive and of limited utility)
Scott Denning
CSU Atmospheric Science
Other Fog Types
Spring 2008
– Mixing of warm, moist air
with colder air produces
saturated air parcel
– Examples
• Exhale on a cold day
• Evaporation of water
from relatively warm, wet
surface and mixing with
colder air above.
• (Smokestack plume,
contrails)
• Upslope fog
– Moist air flows up along
sloped plain, hill or
mountain
– Expansion of rising air
causes cooling and RH
increases
Clouds
• Clouds result when air
becomes saturated
away from the ground
• They can
– be thick or thin, large or
small
– contain water drops
and/or ice crystals
– form high or low in the
troposphere
– even form in the
stratosphere (important
for the ozone hole!)
• Clouds impact the
environment in many
ways
– Radiative balance,
water cycle, pollutant
processing, earthatmosphere charge
balance, etc….
5
AT350 Introduction to Weather and Climate
Fog and Clouds
Cloud Classification
Cloud type summary
• Clouds are categorized by their height,
appearance and vertical development
– High Clouds - generally above 16,000 ft at middle
latitudes
• Main types - Cirrus, Cirrostratus, Cirrocumulus
– Middle Clouds – 7,000-23,000 feet
• Main types – Altostratus, Altocumulus
– Low Clouds - below 7,000 ft
• Main types – Stratus, stratocumulus,
nimbostratus
– Vertically “developed” clouds (via convection)
• Main types – Cumulus, Cumulonimbus
High Clouds
Cirrus
• High clouds
– White in day;
red/orange/yellow at
sunrise and sunset
– Made of ice crystals
– Cirrus
• Thin and wispy
• Move west to east
• Indicate fair weather
– Cirrostratus
– Cirrocumulus
• Less common than cirrus
• Small, rounded white
puffs individually or in
long rows (fish scales;
mackerel sky)
Scott Denning
CSU Atmospheric Science
• Thin and sheetlike
• Sun and moon clearly
visible through them
• Halo common
• Often precede
precipitation
Spring 2008
6
AT350 Introduction to Weather and Climate
Fog and Clouds
Cirrus
Cirrocumulus
Cirrus Display at Dawn
Cirrocumulus
Cirrostratus
Cirrocumulus at Sunset
Cirrostratus with Halo
Scott Denning
CSU Atmospheric Science
Spring 2008
7
AT350 Introduction to Weather and Climate
Fog and Clouds
Contrails
Middle Clouds
• Altocumulus
–
–
–
–
<1 km thick
mostly water drops
Gray, puffy
Differences from
cirrocumulus
• Larger puffs
• More dark/light
contrast
• Altostratus
– Gray, blue-gray
– Often covers entire sky
– Sun or moon may show
through dimly
• Usually no shadows
Altostratus
Alto Stratus Castellanus
Scott Denning
CSU Atmospheric Science
Spring 2008
8
AT350 Introduction to Weather and Climate
Fog and Clouds
Altocumulus
Altocumulus
Alto Cumulus Radiatus
Alto Cumulus
Low Clouds
• Stratus
– Uniform, gray
– Resembles fog that does
not reach the ground
– Usually no precipitation, but
light mist/drizzle possible
• Stratocumulus
– Low lumpy clouds
– Breaks (usually) between
cloud elements
– Lower base and larger
elements than altostratus
• Nimbostratus
Alto Cumulus Undulatus
Scott Denning
CSU Atmospheric Science
Spring 2008
– Dark gray
– Continuous light to
moderate rain or snow
– Evaporating rain below can
form stratus fractus
9
AT350 Introduction to Weather and Climate
Fog and Clouds
Stratus fractus
Looking down on an eastern Atlantic
stratus deck
Scott Denning
CSU Atmospheric Science
Spring 2008
Stratiform cloud layers
10
AT350 Introduction to Weather and Climate
Fog and Clouds
Stratocumulus cloud streets
Stratus
A Layer of Stratocumulus
Cloud viewed from above
Stratus undulatus
Vertically
“developed”
developed”
clouds
• Cumulus
– Puffy “cotton”
– Flat base, rounded top
– More space between cloud
elements than
stratocumulus
• Cumulonimbus
– Thunderstorm cloud
– Very tall, often reaching
tropopause
– Individual or grouped
– Large energy release from
water vapor condensation
Scott Denning
CSU Atmospheric Science
Cumulonimbus with Pileaus caps
Spring 2008
11
AT350 Introduction to Weather and Climate
Fog and Clouds
Cumulonimbus Clouds Spawn Tornadoes
Satellite
Observations
• Satellites can be
– Geostationary
• Monitors fixed spot on
Earth’s surface
– Polar orbiting
• Orbit poles with Earth
revolving below
• Satellites observe
–
–
–
–
Scott Denning
CSU Atmospheric Science
Spring 2008
Clouds
Water vapor
Precipitation
Surface properties
(temperature, snow cover,
vegetation, etc…)
12
AT350 Introduction to Weather and Climate
Fog and Clouds
Visible and Infrared Satellite Photos
Visible
Scott Denning
IR
CSU Atmospheric Science
Spring 2008
13