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AT350 Introduction to Weather and Climate Fog and Clouds Condensation: Dew, Fog and Clouds Please read Chapter 5 in Ahrens Condensation • Condensation is the phase transformation of water vapor to liquid water • Water does not easily condense without a surface present – Vegetation, soil, buildings provide surface for dew and frost formation – Particles act as sites for cloud and fog drop formation Scott Denning CSU Atmospheric Science Spring 2008 Dew • Surfaces cool strongly at night by radiative cooling – Strongest on clear, calm nights • The dew point is the temperature at which the air is saturated with water vapor • If a surface cools below the dew point, water condenses on the surface and dew drops are formed • Dew does not “fall” 1 AT350 Introduction to Weather and Climate Fog and Clouds Frost Cloud and fog drop formation • If the temperature is below freezing, the dew point is called the frost point • If the surface temperature falls below the frost point water vapor is deposited directly as ice crystals • If the air temperature cools below the dew point (RH > 100%), water vapor will tend to condense and form cloud/fog drops • Drop formation occurs on particles known as cloud condensation nuclei (CCN) • The most effective CCN are water soluble. • Without particles clouds would not form in the atmosphere – deposition – RH of several hundred percent required for pure water drop formation • The resulting crystals are known as frost, hoarfrost, or white frost Typical Sizes Very Small Drops Tend to Evaporate! • Surface of small drops are strongly curved • Stronger curvature produces a higher esat • Very high RH required for equilibrium with small drops – ~300% RH for a 0.1 µm pure water drop Scott Denning CSU Atmospheric Science Spring 2008 If small drops evaporate, how can we ever get large drops?! 2 AT350 Introduction to Weather and Climate Fog and Clouds The Solute Effect Homogeneous Nucleation • Condensation of water on soluble CCN dissolves particle • Formation of a pure water drop without a condensation nucleus is termed “homogeneous nucleation” • Random collision of water vapor molecules can form a small drop embryo – Water actually condenses on many atmospheric salt particles at RH ~70% • Some solute particles will be present at drop surface – Displace water molecules – Reduce likelihood of water molecules escaping to vapor – Reduce esat from value for pure water drop – Collision likelihood limits maximum embryo size to < 0.01 µm • esat for embryo is several hundred percent Water molecule – Embryo evaporates since environmental RH < 100.5% Solute molecule Relative Humidity % Curvature and Solute Effects Compete Curves are equilibrium droplet growth curves. Peak of each curve is critical point for cloud drop activation. Can define corresponding critical RH. 10-15 10-16 g g Numbers in red are the mass of the salt condensation nucleus 10-14 g Steps in Cloud/Fog Formation • Air parcel cools causing RH to increase – Radiative cooling at surface (fog) – Expansion in rising parcel (cloud) • CCN (tenths of µm) take up water vapor as RH increases – Depends on particle size and composition • IF RH exceeds critical value, drops are activated and grow readily into cloud drops (10’s of µm) Droplet Radius (micrometers) Scott Denning CSU Atmospheric Science Spring 2008 3 AT350 Introduction to Weather and Climate Fog and Clouds Where do CCN come from? • Not all atmospheric particles are cloud condensation nuclei (CCN) • Good CCN are hygroscopic (“like” water, in a chemical sense) • Many hygroscopic salt and acid particles are found in the atmosphere • Natural CCN – Sea salt particles (NaCl) – Particles produced from biogenic sulfur emissions – Products of vegetation burning More About CCN Sulfate aerosol (SO42-) SO2 H2SO4 • CCN from human activity – Pollutants from fossil fuel combustion react in the atmosphere to form acids and salts – Sulfur dioxide reacts to form particulate sulfuric acid and ammonium sulfate salts – Nitrogen oxides react to form gaseous nitric acid which can combine with ammonia to form ammonium nitrate particles Fogs Scott Denning • CCN concentrations vary in time and space – Typically 100-1000 per cubic centimeter – High in polluted environments – Higher CCN concentrations give rise to greater cloud drop concentrations • Climate impacts of these more reflective clouds? • Surface radiation and conduction of heat away from the overlying air cool air temperatures near the ground • A layer of air near the ground becomes saturated and fog forms • Fog deepens as radiative cooling from the fog top continues overnight • Solar heating warms the ground and causes the fog to “burn off” from the ground up • What type of meteorological conditions would favor radiation fog? Radiation fog Advection fog Upslope fog Evaporation (mixing) fog CSU Atmospheric Science – Clouds ingest sulfur dioxide (SO2) – Chemical reactions in the cloud drops convert dissolved SO2 to soluble forms of sulfate (SO4 2-) – When the cloud drops evaporate, soluble sulfate particles are left behind Radiation Fog • Fogs are clouds in contact with the ground • Several types of fogs commonly form – – – – SO2 • Clouds even contribute to CCN production Spring 2008 4 AT350 Introduction to Weather and Climate Fog and Clouds Advection Fog • • • • Warm air moves (is advected) over cold surface Cold surface cools warm air If saturation is reached, fog forms Common on west coast of U.S. • Evaporation (mixing) fog – Warm moist air from Pacific is advected over upwelling cold coastal waters – As foggy air moves ashore, solar heating warms the ground and overlying surface • Fog evaporates near ground – Coastal advection fogs are key moisture sources for California Redwoods Fogs and Visibility • Light scattering by fog drops (geometric scatterers) degrades visibility, leading to – Traffic fatalities – Airport accidents and closures • Remedies – Fog monitoring and warning (optical sensors) – Fog dispersal (expensive and of limited utility) Scott Denning CSU Atmospheric Science Other Fog Types Spring 2008 – Mixing of warm, moist air with colder air produces saturated air parcel – Examples • Exhale on a cold day • Evaporation of water from relatively warm, wet surface and mixing with colder air above. • (Smokestack plume, contrails) • Upslope fog – Moist air flows up along sloped plain, hill or mountain – Expansion of rising air causes cooling and RH increases Clouds • Clouds result when air becomes saturated away from the ground • They can – be thick or thin, large or small – contain water drops and/or ice crystals – form high or low in the troposphere – even form in the stratosphere (important for the ozone hole!) • Clouds impact the environment in many ways – Radiative balance, water cycle, pollutant processing, earthatmosphere charge balance, etc…. 5 AT350 Introduction to Weather and Climate Fog and Clouds Cloud Classification Cloud type summary • Clouds are categorized by their height, appearance and vertical development – High Clouds - generally above 16,000 ft at middle latitudes • Main types - Cirrus, Cirrostratus, Cirrocumulus – Middle Clouds – 7,000-23,000 feet • Main types – Altostratus, Altocumulus – Low Clouds - below 7,000 ft • Main types – Stratus, stratocumulus, nimbostratus – Vertically “developed” clouds (via convection) • Main types – Cumulus, Cumulonimbus High Clouds Cirrus • High clouds – White in day; red/orange/yellow at sunrise and sunset – Made of ice crystals – Cirrus • Thin and wispy • Move west to east • Indicate fair weather – Cirrostratus – Cirrocumulus • Less common than cirrus • Small, rounded white puffs individually or in long rows (fish scales; mackerel sky) Scott Denning CSU Atmospheric Science • Thin and sheetlike • Sun and moon clearly visible through them • Halo common • Often precede precipitation Spring 2008 6 AT350 Introduction to Weather and Climate Fog and Clouds Cirrus Cirrocumulus Cirrus Display at Dawn Cirrocumulus Cirrostratus Cirrocumulus at Sunset Cirrostratus with Halo Scott Denning CSU Atmospheric Science Spring 2008 7 AT350 Introduction to Weather and Climate Fog and Clouds Contrails Middle Clouds • Altocumulus – – – – <1 km thick mostly water drops Gray, puffy Differences from cirrocumulus • Larger puffs • More dark/light contrast • Altostratus – Gray, blue-gray – Often covers entire sky – Sun or moon may show through dimly • Usually no shadows Altostratus Alto Stratus Castellanus Scott Denning CSU Atmospheric Science Spring 2008 8 AT350 Introduction to Weather and Climate Fog and Clouds Altocumulus Altocumulus Alto Cumulus Radiatus Alto Cumulus Low Clouds • Stratus – Uniform, gray – Resembles fog that does not reach the ground – Usually no precipitation, but light mist/drizzle possible • Stratocumulus – Low lumpy clouds – Breaks (usually) between cloud elements – Lower base and larger elements than altostratus • Nimbostratus Alto Cumulus Undulatus Scott Denning CSU Atmospheric Science Spring 2008 – Dark gray – Continuous light to moderate rain or snow – Evaporating rain below can form stratus fractus 9 AT350 Introduction to Weather and Climate Fog and Clouds Stratus fractus Looking down on an eastern Atlantic stratus deck Scott Denning CSU Atmospheric Science Spring 2008 Stratiform cloud layers 10 AT350 Introduction to Weather and Climate Fog and Clouds Stratocumulus cloud streets Stratus A Layer of Stratocumulus Cloud viewed from above Stratus undulatus Vertically “developed” developed” clouds • Cumulus – Puffy “cotton” – Flat base, rounded top – More space between cloud elements than stratocumulus • Cumulonimbus – Thunderstorm cloud – Very tall, often reaching tropopause – Individual or grouped – Large energy release from water vapor condensation Scott Denning CSU Atmospheric Science Cumulonimbus with Pileaus caps Spring 2008 11 AT350 Introduction to Weather and Climate Fog and Clouds Cumulonimbus Clouds Spawn Tornadoes Satellite Observations • Satellites can be – Geostationary • Monitors fixed spot on Earth’s surface – Polar orbiting • Orbit poles with Earth revolving below • Satellites observe – – – – Scott Denning CSU Atmospheric Science Spring 2008 Clouds Water vapor Precipitation Surface properties (temperature, snow cover, vegetation, etc…) 12 AT350 Introduction to Weather and Climate Fog and Clouds Visible and Infrared Satellite Photos Visible Scott Denning IR CSU Atmospheric Science Spring 2008 13