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An In-vitro evaluation of frictional resistance of polymer- coated elastomeric modules (super slick) and non-coated conventional elastomeric modules after use in the oral environment at 1 week and 1 month intervals. Dr Raghu H.Ha, Dr. H. L.Umab, Dr. V. Shashikala Kumaric a Dental Surgeon, Mysore Associate Professor, Department of Orthodontics, Government Dental College & Research Institute, Bangalore. c Professor& Head, Department of Orthodontics, Government Dental College & Research Institute, Bangalore. b ABSTRACT: Background and objectives: The aim of this study was in-vitro evaluation of frictional resistance of polymer coated elastomeric super slick modules and non-coated conventional elastomeric modules after their use in true oral environment during sliding mechanics at intervals of 1 week and 1 month . Method: Ten subjects undergoing orthodontic treatment with pre-adjusted edgewise 022”×028” prescription and 019”×025” stainless steel arch-wire in place were chosen. In the upper arch, the arch wire was ligated to the brackets with polymer coated super slick elastomeric modules and in the lower arch with non-coated conventional elastomeric modules and vice-versa for other five individuals. The modules were retrieved after 1week and 1month of use in true oral environment. The as-received and retrieved modules were tested for frictional resistance using an experimental model mounted on the crosshead of an instron machine and the co-efficient of dynamic friction was recorded. Results: There were statistically significant differences in the co-efficient of dynamic friction between the non-coated conventional (0.08 at 1week and 0.05 at 1month) and polymer-coated super slick modules (0.17 at 1week and 0.11 at 1month) retrieved from the oral environment at different time intervals. No statistically significant differences were found between the upper and lower modules of both types. Conclusion: The co-efficient of dynamic friction of polymer coated super slick modules was significantly greater when compared to non-coated conventional modules in the true oral environment. Since low frictional values are desired during leveling and aligning and during sliding mechanics, polymer coated super slick modules are not advised for use as they can add to the burden of anchorage. Key words: Friction, ligature, super slick modules, conventional modules Introduction During orthodontic space closure with sliding mechanics resistance to sliding is produced at the bracket-arch-wire interface which tends to counteract the applied force and in turn the desired tooth movement.1 Resistance to sliding in other words is friction.Friction is a force that retards or resists the relative motion of two objects in contact. During space closure with sliding mechanics some amount of applied force is dissipated as friction and the remaining is transferred to the supporting structures of the tooth to mediate tooth movement.2 Friction is a clinical challenge and must be dealt with efficiently to provide optimum orthodontic results. The variables affecting friction or resistance to sliding is multifactorial. These can be either mechanical or biological. Mechanical variables include bracket material, slot size, bracket width and angulation, wire size, wire shape, wire material, ligature material, force of ligation, etc. Biological factors include saliva, plaque, acquired pellicle, corrosion, biological resistance, etc.2 Various methods have been used to reduce the friction of ligation such as stainless steel ligatures, elastomeric modules and self-ligating brackets. Stainless steel ligatures produce variable ligation forces, are time consuming to place and cause discomfort to the patient.3 Recently introduced selfligating brackets reduce treatment time, are comfortable to the patient and have low frictional resistance but they are more costly.4 Elastomeric modules have replaced stainless steel ligatures since their introduction in the 1960’s.Their advantages are quick application and removal, enhanced patient comfort, fluoride release potential and availability in a variety of colors for better patient acceptance.5 But the dentition and soft tissues may be adversely affected by microbial accumulation around the ligated bracket and arch-wire may not seat completely during torquing and rotation correction. Binding may occur during sliding mechanics, creating friction and thus loss of applied force.5 To overcome these disadvantages, a polymer-coated ligature Super Slick was introduced with claims that it significantly reduced friction compared with non-coated conventional elastomeric modules. These are manufactured with a special polyurethane mix by injection moulding technique and coated with covalently bonded metafasix. These modules have claimed to reduce friction by 60% compared to uncoated modules with similar elastic properties.3 Conflicting reports exist regarding lubrication and its effect on friction. Saliva or a saliva substitute serves as an excellent lubricant in the sliding of the bracket along the wire.6 Comparison of clinical and laboratory measurements has shown that less force was needed to initiate movement when experimental models were used to measure resistance to movement intra-orally than in the laboratory. This was due to the occlusal forces on tooth movement in the mouth.3 Elastomeric materials in general exhibit force decay after stretching, more so in the oral environment because of the moisture from saliva.7 Besides dimensional alterations, the exposure of elastomers to water leads to weakening of the intermolecular forces and subsequently to matrix decomposition and chemical degradation of these materials.8 Any improvement in the frictional properties would be of clinical benefit only if the coating remained functional in the oral environment. Kusy et al9 stated that experiments conducted in artificial saliva were invalid because it is no substitute for human saliva. The in-vivo environment differs markedly from ex-vivo conditions because of variables such as masticatory force and temperature.10 Thus the aim of this study was an in-vitro evaluation of frictional resistance of polymer-coated elastomeric modules Super slick and non-coated conventional elastomeric modules after their use in the oral environment at intervals of 1 week and 1 month respectively. Materials and methods Ten subjects were chosen from patients undergoing orthodontic treatment at the Department Of Orthodontics and Dentofacial Orthopedics, Government Dental College And Research Institute, Bengaluru. All selected cases were under treatment with pre-adjusted edgewise 022”x028”slot prescription (Gemini, 3M, USA) and 019”x025”SS arch wire in place.Two types of elastomeric modules were compared;SuperslickTMelastomeric modules (TP orthodontics,LaPorte, Ind)(Fig1) and Conventional elastomeric modules (3M Unitek USA) (Fig2). In this study, upper arch was ligated with polymer-coated super slick elastomeric modules and lower arch with conventional modules (Fig3) for five individuals and vice versa (Fig4) for other five individuals. The upper and lower arches were randomly selected for placement of elastomeric modules. Patients were instructed to maintain oral hygiene with no special instructions during this period. The first set of modules remained in the patient’s mouth for1 week. On retrieval, these modules were replaced by fresh set of modules of the same type, in the same way by the same operator which were also retrieved from patient’s mouth after one month. This process was repeated in 10 patients. Specimens retrieved were stored in normal saline. Experimental groups were as follows: Group 1 C - 10 non-coated conventional modules at 0 hrs (as received). Group 2 CU- 10 upper non-coated conventional modules after 1 week of intra oral use. Group 3 CU- 10 upper non-coated conventional modules after 1 month of intra oral use. Group 4 CL - 10 lower non-coated conventional modules after 1 week of intra oral use. Group 5 CL - 10 lower non-coated conventional modules after 1 month of intra oral use. Group 1 S - 10 polymer- coated modules at 0 hrs (as received) Group 2 SU - 10 upper polymer- coated modules after 1 week of intra oral use. Group 3 SU -10 upper polymer- coated modules after 1 month of intra oral use. Group 4 SL - 10 lower polymer- coated modules after 1 week of intra oral use. Group 5 SL - 10 lower polymer- coated modules after 1 month of intra oral use. PREPARATION OF TEST ASSEMBLIES: In actual clinical situation when sliding mechanics are employed to retract the anterior teeth, the friction arising from archwire contact, results not from a single bracket but more relevantly due to contact in the buccal segment attachments. Unlike previous frictional studies where the predominant test model was a model or assembly having archwires being pulled through a single bracket slot only, the present study evaluated the frictional forces arising when the archwire slides through an entire buccal segment.Two experimental models reproducing the buccal segments of maxillary (Fig5) and mandibular arch (Fig6) with respective upper and lower 022”x028” preadjusted edgewise canine and 2nd premolar brackets and molar tubes bonded to respective natural teeth were used to assess the frictional forces produced by two types of elastomeric modules on conventional stainless steel brackets. Each experimental model consisted of an acrylic bar which had a line scribed parallel to its long axis. A section of 0215”x028” stainless steel wire was used to align the brackets before embedding them in the acrylic bar along the scribed line. This was to aid in aligning the pull of the wire through thebrackets, so that friction was not induced by adverse tipping or torsion moments and also allow the brackets to move along the wire as an axial tensile force was applied by the instron machine. According to Pizzoni et al11,the experimental setup in this study falls under the second group where the archwires slide through brackets parallel to the bracket slot. Instron 4467 (Instron Corporation, Massachusetts, USA) with 0.005% accuracy for set speed and 0.05% accuracy for applied force was used for checking the force in the as- received and retrieved samples of both types of modules.0.019”x0.025” stainless steel wire was inserted into the bracket assembly and the as- received and retrieved modules from oral cavity after 1 week and 1 month use were applied separately on to the brackets. The experimental models were mounted in the instron machine. For every traction test over a distance of 15 mm at a speed of 5 mm/min the frictional forces were recorded. Coefficient of dynamic friction was studied and the values obtained were non-parametric (Table). All measurements were performed at room temperature of 20 ± 2ºC. The Statistical software namely SPSS 15.0, Stata 8.0, MedCalc 9.0.1 and Systat 11.0 was used for the analysis of the data. Student t-test (two tailed, dependent) was used to find the significance of study parameters on continuous scale within each group. Student t-test for paired comparisons was used to investigate the significance of the difference between single population means. No assumption was made about the population variances. A comparative evaluation study Split Mouth Design was used in this study. RESULTS: Friction can be described by the co-efficient of friction which is a constant and is related to the surface characteristics of the materials. The co-efficient of friction can be described mathematically as the frictional force that resists motion divided by the normal force that acts perpendicular to the two contacting surfaces. There are two co-efficient of friction for a material. One is the co-efficient of static friction and another is the co-efficient of dynamic friction which reflects the force necessary to perpetuate this motion.2 Cacciafestaet al12 found that even though static frictional forces were greater than the dynamic ones, no significant differences were found between static and dynamic frictional forces. Mean values and standard deviation of co-efficient of dynamic friction for the two sets of elastomeric modules of the experimental groups are shown in the Table. It also shows comparison of friction between the experimental groups at different time points,at 1week and 1month of intra-oral use.The co-efficient of dynamic friction of non-coated conventional and polymer coated super slick elastomeric modules in the as-received state was 0.20 and 0.18 respectively. There were statistically significant differences between the retrieved non-coated conventional and polymer coated super slick elastomeric modules with conventional modules showing a mean co-efficient of dynamic friction of 0.08 at 1week and 0.05 at 1 month of intra-oral use and super slick modules showing a mean coefficient of dynamic friction of 0.17 at 1 week and 0.11 at 1 month of intra-oral use during sliding mechanics. The amount of force exerted by non-coated conventional modules was less when compared with super slick modules after 1 week and 1month of intra-oral use. There was no statistically significant difference in the co-efficient of dynamic friction between the upper and the lower elastomeric modules. Discussion The success of tooth movement during sliding mechanics with pre-adjusted appliances depends to a large extent on the ability of orthodontic archwire to slide through brackets and tubes with as much minimum friction as possible.Various studies have shown that friction is produced between brackets, tubes and archwires that tend to counteract the applied force and in turn the desired tooth movement many a time causing loss of anchorage.1,2,13,14 Studies have shown that the portion of applied force lost due to resistance to sliding can range from 12% to 60%.15 Iwasaki et al16 confirmed that during sliding mechanics 30% to 50% of total frictional force generated by a premolar bracket travelling along a 019”x025” stainless steel archwire is lost due to the friction of ligation. Thus when orthodontic tooth movement is being planned, an understanding of forces required to overcome friction is important so that the appropriate magnitude of force can be used to produce optimal biologic tooth movement.12 It has been reported that friction is largely determined by the nature of ligation.12 Various studies have described the significant influence of different modes of ligation and their resulting effects on friction.Traditional methods of ligation include the use of elastomeric modules and stainless steel ties. Stainless steel ties produced less frictional forces compared to elastomeric modules.17 Iwasaki R.Laura et al16 reported that the frictional forces generated by stainless steel ligation was found to vary considerably between loose and tight ligation in the range of 618±578g to 1470±915g respectively and significant inter-operator variability was present. Additionally, it was also observed that there was a wide variation in the amount of force generated by stainless steel ties even when a single operator was employed. Stainless steel ties are time consuming to place and cause discomfort to the patient.3 Researchers have recently focused on elastomeric ligatures and self-ligating brackets as alternatives to reduce or eliminate the shortcomings of stainless steel ligatures. Several studies have reported significantly lower frictional forces produced by self-ligating brackets than conventional ligatures.2,3,12,16,18 Thorstensen and Kusy19 stated that resistance to sliding of self-ligating brackets in the open state tied with ligature wire was comparable to that of conventional brackets. Franchi et al20 found no significant difference in friction between self-ligating brackets and nonconventional elastomeric ligatures (Slide,Leoneorthodontic products) but significant reduction in friction was reported between Slide and conventional elastomeric ligatures. Since their introduction to orthodontics, elastomeric modules have replaced stainless steel ties. A single module produces a ligation force of 50-150g.2 Elastomeric modules may not completely seat the wire during torquing or rotational corrections and binding may occur during sliding mechanics. A polymeric-coated ligature SUPER SLICK (TP Orthodontics, LaPorte Ind) was introduced to the orthodontic market with claims that it significantly reduced friction compared with conventional ties.10 Research on sliding mechanics using super slick on 019x025 inch archwires demonstrated an advantageous reduction in frictional force compared with rectangular cross-sectional modules but not to round cross-sectional non-coated modules and self-ligating brackets.7 However other studies have reported that coated modules did not produce less friction than uncoated modules.3,6,16,18 Whereas in some studies super slick modules showed similar frictional forces compared to non-coated modules. Contrary to the studies7, 10 which showed that Super Slick modules significantly reduce friction with sliding mechanics, our results indicate that they do not confer any advantage over conventional modules, and in fact, their resistance was significantly greater.Similar results were obtained by Helen Sylvia Griffiths, Martyn Sherriff, and Anthony John Ireland6 in their study.The co-efficient of dynamic friction of both types of modules reduced with time of stretch. As observed from the Table, the co-efficient of dynamic friction exerted by conventional modules and super slick modules in the as-received state is almost the same, which is 0.20 and 0.18 respectively with no statistically significant difference.Over a period of 1 week of intra-oral use, the retrieved conventional modules showed a reduction in the co-efficient of dynamic friction of 0.08, both in the upper and lower whereas the super slick modules over the same period remained almost same (0.17) as that in the as-received state. This difference was found to be statistically significant. After one month of intra-oral use, the retrieved conventional modules both upper and lower showed 0.05 and 0.06 respectively, a 75% reduction in the co-efficient of dynamic friction whereas the super slick modules reduced marginally 0.11 and 0.14 respectively by only 39%.This difference in reduction of co-efficient of dynamic friction between the two types of modules was found to be strongly significant. The co-efficient of dynamic friction of conventional modules reduced drastically with time of stretch compared to that of super slick. Tayler N.G. and Icon K21 found that the ligation with loosely placed ligatures or stretched modules reduced frictional forces and showed a steady reduction over a 3 week period. Chimenti C, Franchi L et al22 stated that dimensions of elastomeric ligatures and elastomeric materials lubricated with silicon influence the static frictional resistance in sliding mechanics. The lubricated elastomeric ligatures generated significantly smaller frictional forces than non-lubricated elastomeric ligatures. Kuster et al23 in their comparative study between two brands of elastic chains showed that the decline in frictional force during intra-oral use was much greater than in the laboratory tests. Similarly in our study, it was expected that in the oral environment with saliva as a medium, the dynamic friction of super slick and conventional modules would reduce. But only the dynamic friction of conventional modules reduced drastically by 61% whereas that of super slick reduced by 43% after one month of intra-oral use. Hain M, Dhopatkar A and Rock P4 stated that under simulated effects of human saliva the coated modules produced 50% less friction than all other conventional ligation methods. However Datana et al5 investigated the degradation of force and surface characteristics of conventional and super slick modules in true oral environment and stated that super slick modules introduced increased frictional forces than conventional modules similar to our study. The super slick modules seem to be highly stable in the oral environment which may be because of the special surface coating. Clinically the reduction in friction of conventional modules might be considered an advantage in orthodontic procedures such as space closure and overjet reduction with sliding mechanics, especially in critical posterior anchorage. But other functions of the ligatures are put at risk, such as adequate torque expression and complete seating of the archwire in the bracket slots. So when aligning and levelling are priorities, the conventional modules are preferable because of their reduced friction instead of the highly stable super slick elastomeric modules. It is clear from the present study that coated Super Slick elastomeric modules produce higher levels of co-efficient of dynamic friction than the non-coated conventional elastomeric modules. Most likely the higher frictional values were the result of the stable polymer coating which may have caused archwire binding in the brackets in true oral environment. Further investigation needs to be done to study the surface characteristics of super slick modules and its effect on friction when used in the oral environment. CONCLUSION: The co-efficient of dynamic friction of polymer coated Super Slick modules was significantly greater when compared to non-coated conventional modules in the true oral environment. Low frictional forces are desired during leveling and aligning and during space closure. Higher frictional forces are desired for expressing the torque in the bracket and during finishing and detailing. Their use during sliding mechanics is not advised as the higher frictional forces of super slick may add to the burden of anchorage. Instead they can be used as active tie- backs for space closure and for full torque expression. References: 1. Drescher D, Bourauel C, Schumacher HA. Frictional forces between bracket and arch wire. Am J Orthod Dentofacial Orthop 1989; 96:397-404. 2. Nanda R. Biomechanics in clinical orthodontics. Philadelphia, WB Saunders Company; 1997: 50 – 51. 3. Hain M, Dhopatkar A, RockP. A comparison of different ligation methods on friction. Am J OrthodDentofacialOrthop 2006;130:666-7 4. Gandini P, Orsi L, Bertoncini C, Massironi S, Franchi L. In vitro frictional forces generated by three different ligation methods. AngleOrthodontist 2008; 78:917-921. 5. Datana S, SenguptaJ, Sharma V. Structural and mechanical characterization of newer elastomeric modules. J IndOrthodSoc 2006; 39:23-29. 6. Griffiths H S, Sherriff M, Ireland A.J. Resistance to sliding with 3 types of elastomeric modules. Am J OrthodDentofacialOrthop 2005;127:670-5. 7. Angolker PV, Kapila S, Duncanson MG, Nanda RS. Evaluation of friction between ceramic brackets and wires. Am J OrthodDentofacial Orthop 1990; 98: 499-506. 8. Taloumis GA, Smith TM, Houndrum SO, Lorton L. Force decay and deformation of orthodontic elastomeric ligatures. Am J OrthodDentofacialOrthop 1997; 111:1-11. 9. Kusy RP, Whitley JQ, Prewitt MJ:Comparison of the frictional co-efficients for selected archwire bracket slot combinations in the dry and wet states. Angle Orthod 1991; 61: 293302. 10. Hain M, Dhopatkar A, RockP. The effect of ligation method on friction in sliding mechanics.Am J OrthodDentofacialOrthop2003; 123: 416-22. 11. Pizzoni L, Ravnholt G, Melsen B. Frictional forces related to self-ligating brackets. Eur JOrthod. 1998; 20:283-291. 12. Cacciafesta V, Sfondrini MF, Ricciardi A, Scribante A, Kiersy C, Aurcchino F. Evaluation of friction of stainless steel and esthetic self-ligating brackets in various bracket arch wire combinations. Am J OrthodDentofacialOrthop 2003;124:395-402. 13. Vaughan JL, Duncanson MG, Nanda RA, Currier GF. Relative kinetic frictional forces between red stainless steel brackets and Orthodontic wires.Am J OrthodDentofacOrthop 1995;107: 20-27. 14. Tidy DC. Frictional forces in fixed appliances. Am J Orthod Dentofacial Orthop.1989; 96: 249 – 54. 15. Kusy RP, Whitley JQ. Friction between different wire-bracket configurations and materials. Semi Orthod 1997; 3:166-77 16. Iwasaki LR, Beatty MW, Randall CJ, Nickel JC. Clinical ligation forces and intraoral friction during sliding on a stainless steel arch wire. Am J OrthodDentofacialOrthop 2003; 123:40815 17. Khambay B, Millet D, McHugh S. Evaluation of method of archwire ligation on frictional resistance. Eur J Orthod2004; 26:327-332. 18. Tecco S, Festa F, Caputi S, Traini T, Di lorio D, D’ Attilio M. Friction of conventional and self -ligating brackets using a 10 bracket model. Angle Orthod 2005; 75:1041-1045. 19. Thomas S, Sherriff M, Birnie D. A comparative in vitro study of the frictional characteristicsof two types of self-ligating brackets and two types of pre-adjusted edgewise brackets tied with elastomeric ligatures. Eur J Orthod. 1998; 20:589-596. 20. Franchi L, Baccetti T, Camporesi M, Barbato E. Forces released during sliding mechanics with passive self-ligating brackets or nonconventional elastomeric ligatures. Am J Orthod Dentofacia lOrthop 2008; 133:87-90. 21. Taylor NG, Icon K. Frictional resistance between orthodontic brackets and archwires in the buccal segments. Angle Orthod 1996;663(3):215-222. 22. Chementi C, Franchi L, Di Guseppe M.G, LucciM : Friction of orthodontic elastomeric ligatures with differentdimensions. Angle Orthod 2005; 75(3) 377-381 23. Kuster R, Ingervell B, Burigin W. Laboratory and intra-oral tests of the degradation of elastic chains. 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