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Introduction to the modern model.notebook March 10, 2015 Oct 259:18 PM The Atom Lets kick it oldschool... John Dalton All matter is composed of very small things which he called atoms. Electrons and the nucleus were unknown. Sep 27:50 PM 1 Introduction to the modern model.notebook J.J. Thomson March 10, 2015 uPlum Pudding Sep 27:58 PM Neils Bohr But I was wrong! They‛re more like bees around a hive. Neils Bohr Oct 259:17 PM 2 Introduction to the modern model.notebook March 10, 2015 Now that we got a little bit smarter ;) Quantum Mechanical Model of the Atom Erwin Schrödinger developed a mathematical treatment into which both the wave and particle nature of matter could be incorporated. Mathematical laws can identify the regions outside of the nucleus where electrons are most likely to be found. These are principle energy levels which are assigned numbers. Oct 259:18 PM Characteristics of the model: • the atom has no definite shape and there is no precise orbit • electrons are now thought to be located on PRINCIPAL ENERGY LEVELS which are assigned numbers • Each energy level is divided into ENERGY SUBLEVELS • Each energy sublevel corresponds to an ATOMIC ORBITAL (often referred to as a cloud) Jan 2910:12 AM 3 Introduction to the modern model.notebook March 10, 2015 Quantum Mechanical Model First Quantum Number n represents the principle energy level 1 2 3 4 Oct 2510:01 PM Generally symbolized by n, it denotes the probable distance of the electron from the nucleus. “n” is also known as the Principle Quantum number or principle energy level number. Oct 259:21 PM 4 Introduction to the modern model.notebook March 10, 2015 An ATOMIC ORBITAL is a region in space where there is a high probability of finding an electron. s orbitals are sphere shaped always have 1 p orbitals are dumbbell shaped always have 3 d complex shapes always have 5 f complex shapes always have 7 Jan 2910:23 AM Sep 28:17 PM 5 Introduction to the modern model.notebook March 10, 2015 The ways in which electrons are arranged around the nuclei of atoms are called ELECTRON CONFIGURATIONS. The rules that govern the way the electrons fill the atomic orbitals are: 1. AUFBAU PRINCIPLE electrons enter orbitals of the lowest energy levels first 2. PAULI EXCLUSION PRINCIPLE an atomic orbital may hold at most two electrons. Each must have an opposite spin. 3. HUND’S RULE when electrons occupy orbitals of equal energy one electron enters each orbital until all the orbitals contain one electron with parallel spins before filling the orbitals with opposite spins. Jan 2910:23 AM Sep 28:23 PM 6 Introduction to the modern model.notebook March 10, 2015 Examples : Jan 2910:10 AM Noble Gas Configuration: Find the noble gas that's closest to the your element but NOT larger! Replace and complete. Jan 2910:10 AM 7 Introduction to the modern model.notebook March 10, 2015 Aufbau Ex : Ar (18) Sep 28:18 PM Electron configuration: Ar : 1s2 2s2 2p6 3s2 3p6 Noble Gas Notation : [Ar] Sep 28:26 PM 8 Introduction to the modern model.notebook March 10, 2015 Sep 32:28 PM Ion Charges Sep 810:57 AM 9 Attachments plum.webloc