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SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Mercury (II) Chloride PRODUCT NUMBER: 2551 CAS NUMBER: 7487-94-7 SYNONYMS: Bichloride of mercury, Dichloromercury, Mercury dichloride, Mercuric chloride MANUFACTURER: Prochem, Inc. 826 Roosevelt Road Rockford, IL 61109 PHONE: FAX: TOLL FREE: 815-398-1788 815-398-1810 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Danger Signal Word Hazard Statements H300+H310 H314 H318 H341 H361 H372 H410 Fatal if swallowed of in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing genetic defects. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. Precautionary Phrases P201 P202 P260 P270 P280 P301+P330+P331 P303+P361+P353 P304+P340+P310 P305+P351+P338+P310 MERCURY (II) CHLORIDE Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink, or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. PAGE 1 SECTION 2 HAZARDS IDENTIFICATION (Cont.) HMIS CLASSIFICATION: Health: 3 Chronic: * NFPA RATING: Health: 3 Flammability: 0 Fire: 0 Reactivity Hazard: 1 Reactivity Hazard: 1 EYE CONTACT: Causes mild to severe irritation of the eyes. May deposit mercury in the lens of the eyes. SKIN CONTACT: Causes mild to severe irritation of the skin. Toxic in contact with skin. INHALATION: Toxic by inhalation. Dust will cause severe respiratory and gastrointestinal distress, and may damage the central nervous system. INGESTION: Very toxic if swallowed. Lack of appetite, abdominal cramps, vomiting, kidney failure, and paralysis. Mercury binds to thiol groups of protein. CHRONIC HEALTH EFFECTS: The chronic effects of mercury poisoning include stomatitis, tremors, psychic disturbances, excessive salivation, dermatitis, and pain on chewing. May cause heritable genetic damage and impair fertility. ACUTE HEALTH EFFECTS: Irritating to the skin, eyes, and respiratory tract. Poison. May cause stomach upset and pain, vomiting, excessive salivation, and urine production stops. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: HgCl2 Molecular Weight: 271.50 CHEMICAL NAME CAS# % Mercury (II) Chloride 7487-94-7 100 SECTION 4 FIRST AID MEASURES EYE EXPOSURE: Immediately flush the eyes with copious amounts of water for at least 15 minutes. Assure flushing under eyelids. A victim may need assistance in keeping their eyelids open. Get immediate competent medical attention. SKIN EXPOSURE: Wash affected area with plenty of water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove to fresh air and keep at rest. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases, seek immediate medical assistance. INGESTION: Seek medical assistance immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Product is not flammable AUTO IGNITION TEMPERATURE: Not available EXPLOSION LIMITS: Not available EXTINGUISHING MEDIUM: Use fire fighting measures that suit the surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Mercury oxide and hydrogen chloride SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear all appropriate equipment when using this material. Ensure adequate ventilation. Avoid breathing dust. ENVIRONMENTAL PRECAUTIONS: Prevent spillage from entering drains or allowing to be released into the environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Sweep up and place in suitable container for proper disposal. MERCURY (II) CHLORIDE PAGE 2 SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Wear appropriate personal protective equipment. Ensure adequate ventilation. Avoid contact with skin and eyes. CONDITIONS FOR SAFE STORAGE: Store in cool, dry, and well-ventilated area. Light and moisture sensitive. Store away from strong bases and oxidizing agents. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EXPOSURE CONTROLS: Component Mercury (II) Chloride Exposure Limits 3 0.025 mg/m 3 0.05 mg/m TWA: Time Weighted Average over 8 hours of work. Basis TWA TWA Entity ACGIH NIOSH EYE PROTECTION: Wear chemical safety glasses or goggles and face shield. SKIN PROTECTION: Wear nitrile or rubber gloves, and a complete suit protecting against chemicals. VENTILATION: Provide local exhaust, preferably mechanical. RESPIRATOR: Use an approved respirator. ADDITIONAL PROTECTION: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: White solid ODOR: None MOLECULAR WEIGHT: 271.50 BOILING POINT: 302° C MELTING POINT: 280-282° C SPECIFIC GRAVITY: 5.44 gm/ml VAPOR DENSITY: No data available SOLUBILITY: Insoluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Moisture and light INCOMPATIBILITY: Strong oxidizing agents and strong bases DECOMPOSITION PRODUCTS: Mercury oxide and hydrogen chloride SECTION 11 TOXICOLOGICAL DATA ACUTE TOXICITY: LD50 Oral – rat – 1 mg/kg CARCINOGENIC EFFECTS: Not classified as a human carcinogen MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available CHRONIC TOXICITY: Not available RTECS: OV9100000 To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. May cause long lasting harmful effects to aquatic life. Very toxic for aquatic organisms. MERCURY (II) CHLORIDE PAGE 3 SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local, state, and federal regulations. SECTION 14 TRANSPORTATION DATA UN1624 Mercuric chloride CLASS 6.1 PG II Marine Pollutant: No SECTION 15 REGULATORY INFORMATION SARA 302/304: Mercuric chloride SARA 311/312: Acute Health Hazard, Chronic Health Hazard SARA (TITLE 313): Not listed CALIFORNIA PROP. 65: Mercuric chloride MASSACHUSETTS RIGHT TO KNOW COMPONENTS: Mercuric chloride NEW JERSEY RIGHT TO KNOW COMPONENTS: Mercuric chloride PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Mercuric chloride SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 03/15 SDS DEPT. MERCURY (II) CHLORIDE PAGE 4