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electrons 2.notebook
November 13, 2012
Electron Configuratio
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5.2
The ways in which electrons are arranged in various orbitals around the nuclei of atoms are called electron configurations.
Three rules—the aufbau principle, the Pauli exclusion principle, and Hund’s rule—tell you how to find the electron configurations of atoms.
5.2
Aufbau Principle
According to the aufbau principle, electrons occupy the orbitals of lowest energy first. In the aufbau diagram below, each box represents an atomic orbital.
Oct 11­3:18 PM
5.2
Pauli Exclusion Principle
Electron Configuratio
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According to the Pauli exclusion principle, an atomic orbital may describe at most two electrons. To occupy the same orbital, two electrons must have opposite spins; that is, the electron spins must be paired.
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Electron Configuratio
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Oct 11­3:18 PM
5.2
Hund’s Rule
Electron Configuratio
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Hund’s rule states that electrons occupy orbitals of the same energy in a way that makes the number of electrons with the same spin direction as large as possible.
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5.2
Electron Configuratio
Orbital Filling Diagram
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1
electrons 2.notebook
November 13, 2012
for Conceptual Problem 1.1
Problem Solving 5.9 Solve Problem 9 with the help of an interactive guided tutorial.
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5.2
Exceptional Electron Configurations
Exceptional Electron Configurations
Why do actual electron configurations for some elements differ from those assigned using the aufbau principle?
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5.2
Exceptional Electron Configurations
Some actual electron configurations differ from those assigned using the aufbau principle because half­filled sublevels are not as stable as filled sublevels, but they are more stable than other configurations.
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