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Material reprocessing PLASTICS PETE: Polyethylene terephthalate Recycle code 1 HDPE: High density polyethylene Recycle code 2 UPVC: Unplasticised polyvinyl chloride Recycle code 3 PP: Polypropylene Mechanised separation & reprocessing After, material separation at a Material Recovery Facility mixed plastics PETE, HDPE & UPVC are bulk hauled in a compacter to a plastics reprocessing factory Separation Infra – red Sort 1 A fully computerised machine using Infra-red light identifies the different plastics by their chemical structure and separates into individual plastic type Wash A whole bottle wash removes dirt, glue and labels. Grinders Chop the separated plastics into flakes. Each plastic type has it’s own special grinder. Washing 2 PETE and UPVC plastic flake is washed in heated water treated with detergents and additives. HDPE is washed in cold water. The separated flake is dried, weighed and bagged, before it is fed to the extruder. Extruder The extruder melts the plastic flake. The extruder has a die and cutter at the end of it. The plastic emerges as strands and is cut into pellets. Infra–red Sort 2 Identifies and separates clear and coloured HDPE and PETE. UPVC is identified and separated by X Ray sensor. PETE flake is separated from PP cap and ring seal pieces in a flotation tank. The two plastics have different densities. The PETE sinks to the bottom while the PP floats to the surface and is skimmed off. The pellets are then bagged ready to be sold to manufacturers as secondary raw material for the manufacture of new plastic product. Reprocessing After, material separation at the Material Recovery Facility glass is bulked hauled to a secondary sorting plant where it is dumped into a hopper ready for colour separation and crushing into cullet (small pieces). Metal contamination in the form of caps and lids is removed by magnets and eddy - current separators Further contamination is removed by computerised optical sorting machines and separation into the 3 main colour types for glass containers: Green, Clear & Brown The colour of glass is determined in the original manufacture process by the addition of various colouring agents, such as, chrome (green) and coal (brown). Once the colour is added it cannot be removed. Therefore brown bottles can only make other brown bottles Recycled glass cullet is sold to packaging manufacturers such as ACI for the production of new glass bottles and jars. The $ value of recycled glass cullet is largely dependent on how clean it is ie free of other material contamination and the consistency of colour segregation. Why Recycle Glass Environmental benefits: — Reduces manufacturing related air pollution by 20% and water pollution by 50% — Saves energy because recycled glass can be processed at a lower temperature than new glass made from raw materials — Reduces Greenhouse gas emissions associated with the burning of fossil fuels in transportation of raw materials to glass manufacturing plants. Sources of recycled glass are usually located closer to glass packaging plants. — Save resources. 14 billion bottles and jars are thrown away in the USA every week > GLASS Raw materials: Sand, Soda Ash and Limestone Not all glass is the same Glass is 100% recyclable but because the formulation of glass varies according to application, only glass bottles and jars can be recycled into glass bottles and jars. The glass used for light bulbs, cookware and windows is made with the addition of ceramics. Heat resistant glass also melts at a different temperature than the glass used to make bottles and jars. Is it Recycled The recycled glass content of glass packaging produced in Australia is on average 44% and sometimes more than 60%. Material reprocessing 2 ALUMINIUM CAN Raw materials: Bauxite After material separation the aluminium can bales are transported to an aluminium smelting plant. On arrival the bales are unloaded and tested for quality and moisture content. The bales are then broken up and the cans shredded into small pieces. De- lacquering Paint and residual moisture is burnt off the shredded cans in a De-lacquering oven The hot shredded aluminium is then screened to remove dirt and contaminants before being fed into a furnace. Heated to 650o Centigrade the cans melt and blend with the molten metal already in the furnace. The molten aluminium is checked for correct chemical composition and then poured into moulds. The resulting ingots are allowed to cool and harden. New Aluminium Can To make aluminium sheet suitable for can manufacture the ingots are “Scalped”. Scalping is where the top and bottom layers of the ingot are milled to a smooth surface. The ingot is then passed through a large rolling mill many times and heated, and then rolled again until it reaches the necessary hardness and thickness for can manufacture A roll of aluminium sheet suitable for making cans may measure 2-3 kilometres and be made from over 1.2 million recycled cans After material separation the steel can bales are transported to steel mills. A bale of used steel cans weighs 1 tonne and contains around 14,000 cans At the steel mill the bales are broken up before de-tinning De-tinning The tin plate that protects the steel can from corrosion and the contents from spoilage is removed. The de-tinned steel can material is shredded and used in the making of new steel Around half of the 700 million tonnes of crude steel produced globally each year will be recycled as scrap. Every tonne of scrap steel used in steel making saves 3 tonnes of natural resources Raw materials — Iron ore — Coal converted to coke — Limestone — Steel scrap At a paper reprocessing plant the paper is sorted by hand to remove obvious contamination and separated into various grades of paper such as newsprint, office paper, cardboard etc. Newsprint is the lowest grade of paper. The better the quality of paper collected the higher the quality of recycled paper produced. Unsorted paper can be used for packaging. Much of the packaging found on supermarket shelves is recycled. Compacted into bales the paper is then transported by truck to a paper mill. At the mill, the waste paper is mixed with water in a machine similar to a washing machine. The resulting pulp is a mixture of water and cellulose fibre, the long thick walled cells of plants that gives stems and trunks rigidity and strength. During pulping contaminants such as plastic covers and metal in the form of paperclips and staples are removed. The pulp is then filtered through wire mesh screens to remove the water. Passed through presses and a dryer to remove any remaining water the paper is then spun into huge reels ready to be made into new paper product. > TIN-PLATED STEEL CAN Steel making — Blast furnace - Iron making — Electric Arc furnace– Steel making — Basic Oxygen furnace – Steel making PAPER Material reprocessing 3 PAPER continued De-inking Paper that has been printed such as newspapers and magazines must have the ink removed before it can be recycled into new paper product. To do this the pulp is de-inked by washing it in a mixture of detergent and aerated water to form a bubbly froth. The resulting inky froth is skimmed off leaving an ink free pulp ready to be made into paper How many times can paper be recycled? Waste paper can be recycled about 5-10 times before the cellulose fibres become so short and weak they can no longer mesh together to form a sheet of paper. ORGANIC WASTE Categories: — Green Waste - Plant debris such as leaves and grass clippings — Food Waste – Surplus food and fruit and vegetable peelings COMPOSTING Who’s Eating Who COMPOST VIALS BY CHACO KATO A complex food web is at work in your home compost heap. The conversion of green and food waste into nutrient rich compost is the sum of the actions of invertebrates such as millipedes, snails, slugs and earthworms along with bacteria and fungi as they live, eat, excrete and die. As each decomposer dies or excretes, more food is added to the web for other decomposers Invertebrates The invertebrates shred the organic material creating a greater surface area for bacteria and fungi to do the bulk of the decomposition work and heat generation. Many kinds of worms including earthworms and nematodes eat the decaying vegetation and microbes and excrete organic compounds that enrich the compost. The tunnelling of worms also aerates the compost Bacteria Bacteria are the smallest living organisms making up to 90% of the billions of micro-organisms found in a gram of compost. Bacteria are responsible for > Statistics — America has a population of approximately 288 million people. Every day Americans buy 62 million newspapers and throw away 44 million, the equivalent of dumping 500,000 trees to land fill each day. — In Australia about 26% of newsprint is recycled paper. — Australia imports more than 50% of the printing and writing paper used here. — Laser printed paper cannot be recycled back into printer paper because the ink is melted onto the paper and is too difficult and costly to remove. Material reprocessing 4 COMPOSTING Who’s Eating Who continued most of the decomposition and heat generation in a compost heap. Bacteria use a broad range of enzymes to chemically break down organic material into compost. Bacteria and fungi are also eaten in turn by organisms such as mites. Heat Various species of bacteria are present at each of the various heat stages in the decomposition. There are 3 stages of heat generation in decomposition: A moderate temperature phase 0-40oC lasting a couple of days A high temperature phase 40-60>oC which can last anything from a few days to a couple of months A cooling and maturation phase which can last serval months Decomposition, in the moderate heat phase, is carried out by bacteria commonly found in topsoil, as the temperature increases above 40oC the dominant species is Bacillus. At high temperature the genus Thermus is present. These micro-organisms can withstand extremely high temperatures. Compost Chemistry: Getting the Recipe Right Carbon and nitrogen are the most important elements in the decomposition process. Carbon is both the energy source and the basic building material of microbial cells and of course all forms of life on Earth. Nitrogen is the crucial component for cell growth and function. Carbon–to–nitrogen ratio: Brown–to-Green To achieve efficient decomposition the carbon–to–nitrogen ration should be 30:1 or 30 parts carbon, by weight, for each one part that is nitrogen. Why 30:1? At lower ratios, nitrogen will be supplied in excess and will be lost as ammonia gas, causing odour. Higher ratios mean that there is not enough nitrogen for microbial population growth, so the compost will remain relatively cool and degradation will be slow. Green & Brown Materials that are green and moist are high in nitrogen, and those that are brown and dry are high in carbon. High nitrogen materials include grass clippings, plant cuttings, and fruit and vegetable scraps. Brown or woody materials such as autumn leaves, woodchips, sawdust, and shredded paper are high in carbon. Most of the nitrogen in compostable material is readily available. Some of the carbon, however, may be bound in compounds that are highly > Material reprocessing 5 COMPOSTING Who’s Eating Who continued resistant to biological degradation. Newspaper, for example, is slower than other types of paper to break down because it is made up of cellulose fibres covered in lignin, a highly resistant compound found in wood. Oxygen Oxygen is another essential element for composting. As micro-organisms oxidise carbon for energy, oxygen is used up and carbon dioxide is produced. Without enough oxygen, the process will become anaerobic and smell. How much oxygen do aerobic microbes need? Aerobic microbes can survive on oxygen concentrations as low as 5%. Though concentrations of more than 10% are best for maintaining aerobic composting. This can be easily achieved by turning and mixing compost ingredients. pH A pH between 5.5 and 8.5 is ideal for compost microorganisms. As bacteria and fungi digest organic matter, they release organic acids. In the early stages of composting, these acids often accumulate. The resulting drop in pH encourages the growth of fungi and the breakdown of lignin and cellulose. Usually the organic acids break down further during the composting process. If the system becomes anaerobic, however, acid accumulation can lower the pH to 4.5, severely limiting microbial activity. In such cases, aeration through turning and mixing is usually enough to return the compost pH to acceptable levels. Compost Physics: Size Does Matter The rate at which composting occurs depends on physical as well as chemical factors. Temperature is a key factor as well as the physical characteristics of the compost ingredients such as particle size and moisture content. Particle Size Microbial activity generally occurs on the surface of the organic particles. Decreasing particle size, through its effect of increasing surface area, will encourage microbial activity and increase the rate of decomposition. When particles are too small and compact, air circulation through the pile is inhibited. This decreases the amount of oxygen available to micro -organisms and decreases their activity. Particle size also affects the availability of carbon and nitrogen. For example, large wood chips are a good bulking agent that ensure aeration through a compost pile, but they provide less available carbon per mass than they would in the form of wood shavings or saw dust System Size The size and shape of the compost system (eg wind row or COMPOST VIALS BY CHACO KATO compost bin) affects the type and rate of aeration and the ability of the compost to retain or dissipate the heat generated. Temperature: Just Hot Enough Temperature is a key factor in successful composting. The heat generated is a by-product of the breakdown of organic material and is dependent on moisture, aeration, C/N ratio and ambient temperature. The temperature at any point during composting depends on how much heat is being produced by micro –organisms, balanced by how much is being lost through conduction, convection, and radiation. Sufficient heat needs to be generated to destroy plant diseases, fly larvae and weed seeds but not so much that it affects beneficial composting micro-organisms that cannot survive temperatures above 6065C. Turning to aerate the compost reduces temperature. Aeration: A Breath of Fresh Air Oxygen is essential for the metabolism and respiration of aerobic micro -organisms, and for the oxidisation of the various organic molecules present in the waste material. At the beginning of biological decomposition oxygen levels are similar to that of air. As microbial activity increases oxygen levels drop and carbon dioxide levels increase. If oxygen levels fall below 5%, anaerobic conditions will develop resulting in odour. Regular mixing and turning will aerate the compost pile and maintain aerobic conditions. Moisture: As Damp as a Wrung out Sponge Moisture content of 50 – 60% is considered ideal for composting. Microbe induced decomposition occurs most rapidly in the thin liquid films found on the surfaces of organic particles. Moisture content of less than 30% reduces bacterial activity. Moisture content greater than 65% results in slow decomposition, odour and nutrient leaching Source: Cornell University USACornell Composting – Science & Engineering web sitewww.cfe.cornell.edu Authors: Richards, Trautmann et al