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Redox Reactions Objectives: define oxidation, define reduction, assign oxidation numbers to all elements Define Oxidation -Loss of electrons -Increase in oxidation number Define Reduction -Gain of electrons -Decrease in oxidation number Rules for Oxidation Numbers The oxidation number of an uncombined atom is zero Diatoms included! The oxidation number of a Group A monatomic ion in a compound is equal to the charge on the ion The oxidation number of oxygen in most of its compounds is always –2 Each oxygen in peroxide is -1. Name the compound—unless you say ….. peroxide, oxygen will be -2. The oxidation number of hydrogen in most of its compounds is +1 When hydrogen is the anion (hydride) it is -1. The oxidation number of the more electronegative atom in a compound is the same as the charge it would have if it were an ion For us, this is NH3. Nitrogen is more electronegative and therefore its oxidation number is -3. Hydrogen would be +1. The sum of the oxidation numbers of the atoms in a polyatomic ion is equal to the charge on the ion MnO4=-1 x + 4(-2) = -1 x =+7 T. O’Toole The sum of the oxidation numbers in a neutral compound is zero CuSO4 = 0 x + (-2) = 0 x =2 Review What is the oxidation number of chromium in K2Cr2O7 ? Cr2O7 = -2 2x + 7(-2) = -2 2x = +12 x = +6 (1) +12 (2) +2 (3) +3 (4) +6 In which substance does chlorine have an oxidation number of +1? +1 +x +(-2) = 0 x=+1 (1) Cl2 (2) HCl (3) HClO (4) HClO2 What is the oxidation number of chromium in CrPO4? x + (-3) = 0 x = +3 (1) +1 (2) +2 (3) +3 (4) +4 Minute Paper Write the equation and identify the oxidation numbers of all elements for the synthesis of aluminum bromide. 10 Minute Makeover Customize your learning by choosing from the following options each night: Complete this section on the Portfolio Page Review the PPT file on the website QUIA practice (http://www.quia.com/jg/1382948list.html) Read pages 654-656 in the book Extra practice problem: page 656 #9-answer in Appendix C Check out the tutorial sources in the LiveBinder Complete the SYS Assignment Review the skills from today’s Train Your Brain T. O’Toole