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Available online at www.sciencedirect.com Lithos 101 (2008) 480 – 500 www.elsevier.com/locate/lithos 40 Ar– 39 Ar ages of intrusions in East Greenland: Rift-to-drift transition over the Iceland hotspot C. Tegner a,⁎, C.K. Brooks b , R.A. Duncan c , L.E. Heister d , S. Bernstein e a d Department of Earth Sciences, University of Aarhus, Høegh-Guldbergs Gade 2, 8000 Århus C, Denmark b Institute of Petrology, University of Copenhagen, Øster Voldgade 10, 1350 København K, Denmark c College of Oceanic and Atmospheric Sciences, Oregon State University, Corvallis, OR 97331, USA Department of Earth Sciences, University of Arkansas at Little Rock, 2081 S. University Avenue, Little Rock, Arkansas 72204-1009, USA e Avannaa Resources Ltd., Geological Museum, Øster Voldgade 5-7, 1350 København K, Denmark Received 16 October 2006; accepted 18 September 2007 Available online 24 September 2007 Abstract Sixteen 40Ar–39Ar ages are presented for alkaline intrusions to appraise prolonged post-breakup magmatism of the central East Greenland rifted margin, the chronology of rift-to-drift transition, and the asymmetry of magmatic activity in the Northeast Atlantic Igneous Province. The alkaline intrusions mainly crop out in tectonic and magmatic lineaments orthogonal to the rifted margin and occur up to 100 km inland. The area south of the Kangerlussuaq Fjord includes at least four tectonic lineaments and the intrusions are confined to three time windows at 56–54 Ma, 50–47 Ma and 37–35 Ma. In the Kangerlussuaq Fjord, which coincides with a major tectonic lineament possibly the failed arm of a triple junction, the alkaline plutons span from 56 to 40 Ma. To the north and within the continental flood basalt succession, alkaline intrusions of the north–south trending Wiedemann Fjord–Kronborg Gletscher lineament range from 52 to 36 Ma. We show that post-breakup magmatism of the East Greenland rifted margin can be linked to reconfiguration of spreading ridges in the Northeast Atlantic. Northwards propagation of the proto-Kolbeinsey ridge rifted the Jan Mayen micro-continent away from central East Greenland and resulted in protracted rift-to-drift transition. The intrusions of the Wiedemann Fjord–Kronborg Gletscher lineament are interpreted as a failed continental rift system and the intrusions of the Kangerlussuaq Fjord as off-axis magmatism. The post-breakup intrusions south of Kangerlussuaq Fjord occur landward of the Greenland–Iceland Rise and are explained by mantle melting caused first by the crossing of the central East Greenland rifted margin over the axis of the Iceland mantle plume (50–47 Ma) and later by uplift associated with regional plate-tectonic reorganization (37–35 Ma). The Iceland mantle plume was instrumental in causing protracted rift-to-drift transition and post-breakup tholeiitic and alkaline magmatism on the East Greenland rifted margin, and asymmetry in the magmatic history of the conjugate margins of the central Northeast Atlantic. © 2007 Elsevier B.V. All rights reserved. Keywords: Chronology; Volcanic rifted margin; Intrusions; Iceland mantle plume; Northeast Atlantic; East Greenland 1. Introduction ⁎ Corresponding author. E-mail address: [email protected] (C. Tegner). 0024-4937/$ - see front matter © 2007 Elsevier B.V. All rights reserved. doi:10.1016/j.lithos.2007.09.001 The Northeast Atlantic igneous province provides a complete history of rift-to-drift magmatism over 62 m.y. from volcanic rifted margin formation to present-day mid- C. Tegner et al. / Lithos 101 (2008) 480–500 ocean ridge spreading (Fig. 1a). Anomalously thick and compositionally enriched basaltic oceanic crust at Iceland and the Greenland–Iceland–Faroes rise witness a sustained mantle melting anomaly relative to normal midocean ridge processes and is referred to as the Iceland mantle plume (White and McKenzie, 1989; Saunders et al., 1997; Holbrook et al., 2001; Allan et al., 2002). The geological map suggests symmetry in the distribution of 481 the continental flood volcanics, the volcanics making up seaward-dipping reflectors at the continent boundaries, and the Greenland–Iceland–Faroes rise (Fig. 1a). Notwithstanding, the history of magmatism at the conjugate volcanic rifted margins is highly asymmetrical. In the British and Faroe Islands, extrusive and intrusive magmatism is confined to a time window from ∼62 to 55 Ma leading up to continental breakup (e.g. Chambers et al., Fig. 1. (a) Geological map of the Northeast Atlantic region showing the distribution of continental flood basalt, volcanics mapped seismically as seaward-dipping reflectors, and thick oceanic crust of the Greenland–Iceland–Faroes Rise. JMMC = Jan Mayen micro-continent: JMFZ = Jan Mayen fracture zone. Modified after Larsen and Saunders (1998). (b) Geological map of central East Greenland showing the major rock types and onland tectonic lineaments (Karson and Brooks, 1999); the location of the anomalously thick oceanic crust of the Greenland–Iceland Rise; location of the coast-parallel dyke complex (Myers,1980; Klausen and Larsen, 2002); magnetic seafloor anomalies (Larsen, 1990); and location of maps in Figs. 4–6. 482 C. Tegner et al. / Lithos 101 (2008) 480–500 Fig. 1 (continued). 2005; Storey et al., 2007a). In contrast, extrusive and intrusive magmatism in central East Greenland was prolonged from ∼62 to 13 Ma (e.g. Sinton and Duncan, 1998; Tegner et al., 1998a; Hansen et al., 2002; Brooks et al., 2004; Storey et al., 2004, 2007a). Likewise, the location of the present-day spreading ridges is asymmetric. While the Reykjanes and Mohns ridges lie close to the axis of symmetry, the Kolbeinsey ridge is displaced towards East Greenland (Fig. 1a). This is linked to a westward relocation of spreading from the Aegir ridge (now extinct) and the formation of the Jan Mayen microcontinent (Nunns, 1983; Scott et al., 2005). The magnetic seafloor spreading anomalies offshore the Blosseville Kyst demonstrate that the proto-Kolbeinsey ridge propagated northwards between East Greenland and the Jan Mayen micro-continent from magnetochron 21 (∼47 Ma) to magnetochron 6 (∼23 Ma) (Fig. 1b). Hence, the rift-todrift transition of the central East Greenland volcanic rifted margin is expected to be prolonged and combined from two rifting events. Here we report 40Ar–39Ar age determinations for sixteen major alkaline plutons, smaller alkaline intru- sions, and gabbroic plutons in central East Greenland. These intrusions were emplaced during and after tholeiitic flood basalt volcanism in major tectonic and magmatic lineaments perpendicular to the rifted margin and extending up to 100 km inland, or in the coastal zone (Fig. 1b). We combine new and published ages to revise the magmatic history of the central East Greenland margin and discuss the link to asymmetry of rift-todrift transition in the Northeast Atlantic and reconfiguration of oceanic spreading ridges over the Iceland mantle plume. 2. Geology and chronology background 2.1. Rifted margin structure South of Kangerlussuaq Fjord at ∼ 68°N (Fig. 1b), the East Greenland rifted margin is characterised by a 20–40 km wide transition zone between largely undisturbed Archean basement with few Paleogene intrusions and the continent–ocean boundary (Klausen and Larsen, 2002). In this narrow transition zone, magmatic C. Tegner et al. / Lithos 101 (2008) 480–500 extension by coast-parallel dyke complexes, layered gabbro and syenite complexes may occupy 30 to 100% of outcrops (Myers, 1980; Klausen and Larsen, 2002). Tectonic extension described as a coast-parallel flexure is manifested in seawards rotation of crustal blocks by antithetic, landward-dipping faults (Nielsen, 1978; Myers, 1980; Klausen and Larsen, 2002). The margin is segmented by tectonic lineaments trending approximately orthogonal to the continent–ocean boundary that are explained as major accommodation zones (Karson and Brooks, 1999; Klausen and Larsen, 2002). Of these lineaments, the Kangerlussuaq Fjord is the most prominent and it has been suggested to represent the failed arm of a triple junction in which extension and riftrelated magmatism took place mainly in two arms forming the present coast line, resulting in a ∼120° angle between the coast-parallel dyke complexes at the mouth of the Fjord (Fig. 1b) (Brooks, 1973; Myers, 1980; Karson and Brooks, 1999). A similar first-order triple junction exists south of Greenland (Karson and Brooks, 1999). Other major, coast-orthogonal lineaments bound segments that are ∼ 100 km wide (Fig. 1). One of these is located at Agtertia Fjord immediately north of the Kruuse Fjord gabbro complex and coincides with an offset in the coastal dyke complex (Myers, 1980; Karson and Brooks, 1999; Klausen and Larsen, 2002). Between the coast-orthogonal lineaments at Kangerlussuaq and Agtertia Fjords, the coastal transition zone is composed mainly of Archean basement that is intruded by a coast-parallel dyke complex (Klausen and Larsen, 2002; Myers, 1980) and layered gabbro plutons (Bernstein et al., 1998b; Tegner et al., 1998a). South of the Agtertia lineament, a ∼ 45 km long stretch of the coast called Kialineq is made up mainly by intrusive layered gabbro complexes (Imilik and NoeNygaard intrusions) and large, younger syenite and granite plutons (Brown et al., 1977; Nielsen, 1987; Tegner et al., 1998a; Bernstein and Bird, 2000). North of the Kangerlussuaq Fjord, north–south trending basins with infill of Cretaceous and Paleogene sediments, the earliest Tertiary volcanics (the Lower Volcanics) and the Sorgenfrei Gletscher Sill Complex are exposed (Fig. 1) (Nielsen et al., 1981; Larsen et al., 1999b; Ukstins Peate et al., 2003). These basins are overlain by the regional Plateau Lavas in which lithostratigraphic formations can be correlated from the Kangerlussuaq area in the south to Scoresby Sund Fjord in the north, and from the Prinsen af Wales Bjerge in the west to the Blosseville Kyst in the east (Larsen et al., 1989; Pedersen et al., 1997; Tegner et al., 1998b; Hansen et al., 2002). Correlation of certain basalt formations has further been established across the 483 Atlantic to the Faroe Islands (Larsen et al., 1999a). Despite the difference in geological setting and the more easterly trend of the coastal dyke complexes, the northern rifted margin is consistently rotated seawards in a fashion similar to the southern segment (Karson and Brooks, 1999; Klausen and Larsen, 2002). A major coast-orthogonal tectonic and magmatic north–south lineament along Wiedemann Fjord–Kronborg Gletscher separates two structural blocks of the flood basalt succession (Fig. 1) (Pedersen et al., 1997). This lineament includes alkaline mafic and ultramafic plutons, nepheline-syenite plutons and north–south trending dyke swarms (Nielsen et al., 2001). 2.2. Chronology of intrusions and lavas K–Ar, Rb–Sr and fission-track (FT) chronology established a chronological frame for magmatism (Beckinsale et al., 1970; Pankhurst et al., 1976; Brooks and Gleadow, 1977; Gleadow and Brooks, 1979; Noble et al., 1988; Holm, 1991). More recent 40Ar–39Ar age determinations have refined the magmatic history (Fig. 2). Supplementary dataset 1 contains a compilation of available age data for the alkaline intrusions. The age of the earliest magmatic event, the Lower Volcanics remains poorly constrained in the Kangerlussuaq area. In the inland Prinsen af Wales Bjerge, the lowermost lavas are 61–60 Ma (Hansen et al., 2002). The main phase of tholeiitic flood volcanism (the Plateau Lavas) erupted between 56.1 ± 0.5 Ma, the age Fig. 2. Age summary for intrusions and lavas exposed on land and for lavas drilled within the Seaward Dipping Reflector Sequences (SDRS) offshore East Greenland. A compilation of published age data for the intrusions is given in Supplementary dataset 1. Age data for the lavas from (Hansen et al., 2002; Heister et al., 2001; Peate et al., 2003; Storey et al., 2007a) and for the SDRS from (Sinton and Duncan, 1998; Tegner and Duncan, 1999). Also shown are magnetic chrons from Gradstein et al. (2004). 484 C. Tegner et al. / Lithos 101 (2008) 480–500 of a basal lava flow (Storey et al., 2007a), and 55.1 ± 0.1 Ma, the age of an alkaline tephra intercalated in the top portion of the lava succession (Heister et al., 2001; Storey et al., 2007b). The Plateau Lavas may have been emplaced in less than 300,000 years (Larsen and Tegner, 2006) and coincides with continental rupture (Fig. 2) (Larsen and Saunders, 1998). The alkaline lavas in the Prinsen af Wales Bjerge (55.1 ± 1.1 to 52.5 ± 1.1 Ma) are intercalated with the Plateau Lavas, but eruptions continued about one million years later (Peate et al., 2003). In the northern part of the Blosseville Kyst (Fig. 1), mildly alkaline basalts erupted into a graben structure within the Plateau Lavas at 50–49 Ma (Larsen et al., 1989; Tegner et al., 1998a). Surprisingly, there is also a report of mildly alkaline lavas of Miocene age (14–13 Ma) overlying the Plateau Lavas close to the inland ice at the northern end of the Wiedemann Fjord–Kronborg Gletscher lineament (Storey et al., 2004). Recent 40Ar–39Ar chronology of the intrusions has focused on the major tholeiitic centres. A precise but unsurprising age of 55.4 ± 0.1 Ma was obtained for the Skaergaard intrusion (Hirschmann et al., 1997) and confirmed by a zircon U–Pb age of 55.59 ± 0.13 Ma (Hamilton and Brooks, 2004). Slightly older ages of 56.7 ± 0.9 Ma and 56.4 ± 0.4 Ma were reported for the Sorgenfrei Gletscher Sill Complex (Fig. 1) (Tegner et al., 1998a). These intrusions thus coincide with the main flood basalt event. More unexpectedly, the tholeiitic gabbro complexes at Kap Edvard Holm, Kruuse Fjord, and Imilik south of Kangerlussuaq Fjord (Fig. 1b) were emplaced at 50–47 Ma, long after continental breakup (Fig. 2) (Nevle et al., 1994; Tegner et al., 1998a). Emplacement of alkaline plutons of the East Greenland margin span a long period beginning before continental breakup with 58.3 ± 0.9 Ma silico-carbonatite dykes of the Sulugsut Complex (Storey et al., 2007a) and continuing to 36 Ma (Fig. 2). The alkaline intrusions mainly crop out either in the coast-orthogonal lineaments (Karson and Brooks, 1999) or closely associated with the coastal gabbro complexes (Myers, 1980; Brooks and Nielsen, 1982; Nielsen, 1987; Nevle et al., 1994). Their geology and age are described in more detail below. 3. New 40 parent’ step ages reported in 40Ar–39Ar geochronology (McDougall and Harrison, 1988). The advantage of 40 Ar–39Ar incremental heating experiments over the K– Ar method is that regression analysis of colinear multiple step Ar-isotopic compositions may be used to verify this assumption. Thus, if the initial 40Ar/36Ar of a sample is within error of atmosphere (295.5), then the ‘apparent’ age is the time since crystallization. If the sample is contaminated with un-degassed, mantle- or crustal-derived 40Ar (excess argon), the initial 40Ar/36Ar is greater than 295.5, and the ‘apparent’ age is calculated using a false assumption and is thus erroneously high. In a single two-component system of radiogenic Ar mixed with excess Ar there are two solutions to calculating reliable crystallization ages. One is to use the isochron regression that yields a true crystallization age regardless of the initial 40Ar/36Ar composition. The second is to recalculate each step age using the initial 40Ar/36Ar value obtained from the regression analysis (McDougall and Harrison, 1988). Such step and plateau ages are denoted “recalculated”. Mixing with a third component (atmospheric Ar) will displace isotopic compositions from the binary mixing line, most notably at low temperature steps, and these compositions are not used in the regression. Excess argon is more likely to be encountered in intrusive rocks than in lavas due to obvious difficulties of equilibration with atmosphere at depth and possible contamination from older host rocks. Another concern with radiometric dating of intrusive rocks is whether the age reflects igneous crystallization or tectonic cooling. For the East Greenland intrusions there is little doubt that 40Ar–39Ar ages represent Ar–39Ar geochronology 3.1. Background and justification The conventional K–Ar method assumes that measured 40Ar derives from that accumulated from decay of 40 K (radiogenic) and from initial composition set by atmospheric Ar. This same assumption applies to ‘ap- Fig. 3. Age vs. closure temperature for dating methods applied to the Kangerlussuaq Syenite Intrusion. Abbreviations: MIN Rb–Sr = Rb–Sr mineral isochron age; WR Rb–Sr = Rb–Sr whole rock isochron age; FT = fission-track age; BIO = biotite. Data from (Beckinsale et al., 1970; Gleadow and Brooks, 1979; Pankhurst et al., 1976) and this study. C. Tegner et al. / Lithos 101 (2008) 480–500 igneous crystallization. The closure temperature of biotite (∼ 350–300 °C) and amphibole (∼ 550– 500 °C) (McDougall and Harrison, 1988) is higher than the ambient crustal temperature at the depth of emplacement. Firstly, all the intrusions were emplaced into Paleogene volcanics (Brooks and Nielsen, 1982; Nielsen, 1987) that were no more than 7–8 km thick and in most cases thinner (Pedersen et al., 1997). This constrains the country rock temperature to less than ∼ 210 °C for a reasonable geothermal gradient. Low 485 regional temperatures for the flood basalts prior to emplacement of plutons, sills and dykes are also implied by the occurrences of zeolite zones in the Plateau Lavas, which record a thermal gradient of about 40 °C/km (Neuhoff et al., 1997). Secondly, apatite fission-track (FT) ages of the basement inland from the thermal influence of intrusions are consistently over 80 Ma (Hansen and Brooks, 2002). This suggests that regional uplift was modest and the present erosion level cooled below 100 °C before emplacement of the intrusions. Fig. 4. Geological map of the Kialineq, Søndre Aputitêq and Patulajivit area showing location of major mafic and felsic plutons, and the location of the dated samples. 486 C. Tegner et al. / Lithos 101 (2008) 480–500 Thirdly, age determinations of the Kangerlussuaq Syenite Intrusion yield concordant ages independent of methods with a closure temperature above ∼200 °C (Fig. 3). The discordant age of 36.1 ± 2.0 Ma (Gleadow and Brooks, 1979) obtained by apatite FT is interpreted as a later cooling event due to exhumation or thermal resetting. 3.2. Samples and methods Sixteen samples were selected from alkaline intrusions between 67°N and 69°N. The results for the two samples from the Gardiner Complex are presented in a companion paper (Heister et al., in preparation), but are also discussed Fig. 5. Geological map of the Kangerlussuaq Fjord region, showing major rock types, the location of the major plutons, and the location of the dated samples. Abbreviations: SSG = Søndre Syenite Gletscher; SS = Snout Series syenite intrusion; AF = Amdrup Fjord. Modified from Gleadow and Brooks (1979). C. Tegner et al. / Lithos 101 (2008) 480–500 here. The location of samples is shown in Figs. 4–6 and Supplementary dataset 2 provides field data and petrographic descriptions. Biotite and hornblende were separated and analysed by incremental heating experiments in a double-vacuum resistance furnace at Oregon State University (n = 14), using a MAP 215-50 mass spectrometer (Sinton and Duncan, 1998; Tegner et al., 1998a; Storey et al., 2007a) and at Stanford University (n = 2) using low-blank CO2 laser heating (Heister et al., 2001). The analytical data calculated using the ArArCalc 487 software (Koppers, 2002) can be found in Supplementary dataset 3. The Ar release patterns and isotope correlations are shown in Figs. 7–9 and summarised in Table 1. We report the isochron age for samples (n = 13) with an acceptable goodness of fit (MSWD b 2.5). The plateau age (n = 2) or total fusion age (n = 1) is preferred as the best age estimate for the remaining samples. All ages are reported relative to 28.02 Ma for the FCT-3 biotite monitor (Renne et al., 1998), allowing for direct comparison with the timescale of Gradstein et al. (2004); previously published Fig. 6. Geological map of the Wiedemann Fjord–Kronborg Gletscher tectonic lineament showing the location of the major plutons, dykes (schematic), diatremes (general area labelled), and the dated samples. 488 C. Tegner et al. / Lithos 101 (2008) 480–500 40 Ar–39Ar ages are recalculated to this monitor age. The errors reported are 2 standard deviations, and include error in the J value. 3.3. Excess argon Excess argon was detected in five samples. In these cases the “recalculated” plateaus are flatter and better defined than the apparent release patterns and concordant with the isochron age (Figs. 8 and 9; Table 1). An example of significant excess Ar is provided by sample 85659 of the Kærven gabbro, for which the apparent release pattern is U-shaped and lacks a plateau while the “recalculated” release pattern displays a 5-step plateau at 55.1 ± 0.4 Ma for 76% of the gas, within error of the isochron age at 55.1 ± 1.4 Ma (Fig. 8). To be consistent and conservative, we use the isochron correlation as the estimate of age and of uncertainty for samples with excess argon. 3.4. Syenite and diorite of the Kialinêq area More than ten plutons are exposed over an area of ∼ 45 × 15 km at the coastal end of a tectonic lineament orthogonal to the coast at ∼67°N (Figs. 1 and 4) (Karson and Brooks, 1999). The Imilik Gabbro Complex (Tegner et al., 1998a; Bernstein et al., 1998a) and the Noe-Nygaard gabbro intrusion (Bernstein and Bird, 2000) crop out in the southern part whereas younger syenite and granite intrusions occur in the northern part (Brown et al., 1977; Nielsen, 1987). Field relations and published ages suggest the Imilik Gabbro Complex consists of 3 units with mutually cross-cutting relations and varying degrees of deformation, hydrothermal alteration and intrusive intensity of the coastal dyke swarm. The oldest unit could not be dated due to lack of suitable material. The unit of intermediate age is constrained to be older than 56.6 ± 0.6 Ma by dating a Fig. 7. Results of 40Ar–39Ar experiments for syenite and diorite intrusions of the Kialineq area and gabbroic complexes at the islands of Søndre Aputitêq and Patulajivit (Fig. 4). Left column shows apparent step ages as open boxes (height gives ±2σ) plotted against accumulated amount of gas released (% 39Ar). Plateau ages are indicated by horizontal lines that bracket concordant step ages. The right column shows 36Ar/40Ar vs. 39Ar/40Ar for the same temperature steps, with isochron age and intercept indicated. C. Tegner et al. / Lithos 101 (2008) 480–500 489 Fig. 8. Results of 40Ar–39Ar experiments for syenite, granite and gabbroic plutons of the Kangerlussuaq Fjord area. Recalculated step ages with initial Ar/36Ar equal to the isochron intercept are shown as black boxes. 40 490 C. Tegner et al. / Lithos 101 (2008) 480–500 cross-cutting dyke, and the youngest unit was dated to 49.5 ± 0.2 and 50.1 ±1.2 Ma (Tegner et al., 1998a). Existing zircon FT, Rb–Sr, and K–Ar ages for the syenite, granite and diorite intrusions of the kialinêq range from 49 to 29 Ma (Beckinsale et al., 1970; Brown et al., 1977; Gleadow and Brooks, 1979; Noble et al., 1988) but most cluster in the range 39–34 Ma (see Supplementary dataset 1). For biotite of the Nuuk diorite we obtained an age of 36.2 ± 0.6 Ma (Fig. 7; Table 1) and for biotite of the Ikerasangmiit Syenite Intrusion an age of 37.2 ± 2.9 Ma, confirming previous results. 3.5. Søndre Aputitêq gabbro–granite complex Sample SA-1 is from a granite vein cutting across gabbro and basalt xenoliths (Dennis K. Bird, pers. comm., 2005) from an island located at the mouth of Agtertia Fjord which coincides with a major coastorthogonal lineament (Fig. 4) (Karson and Brooks, 1999). Amphibole yielded an age of 49.4 ± 1.0 Ma (Fig. 7; Table 1). This age is within error of a titanite FT age of 52.5 ± 2.6 Ma from the island (Gleadow and Brooks, 1979) and an 40Ar–39Ar age of 48.3 ± 1.2 Ma Fig. 9. Results of 40Ar–39Ar experiments for syenite, gabbro, basanite, nephelinite and lamprophyre intrusions of the Wiedemann Fjord–Kronborg Gletscher lineament. Recalculated step ages with initial 40Ar/36Ar equal to the isochron intercept are shown as black boxes. C. Tegner et al. / Lithos 101 (2008) 480–500 491 Table 1 Ar–39Ar incremental heating ages for alkaline intrusions, central East Greenland 40 Location name and rock type Ar MSWD 40Ar/36Ar Type (%) (initial) Material Kialineq district Nuuk Diorite Ikerasangmiit Syenite Intrusion 67.00 67.04 312001 429360 Biotite 36.2 Amphibole 37.2 0.6 2.9 11 6 98 97 1.7 1.7 301 ± 18 392 ± 91 Isochron Isochron Agtertia Fjord lineament and islands Søndre Aputitêq gabbro–granite Patulajivit Gabbro Complex 67.30 67.50 SA-1 P-175 Amphibole 49.4 Biotite 47.2 1.0 0.8 3 98 – 100 1.0 – – – Plateau Total fusion# Kangerlussuaq Fjord lineament Kangerlussuaq Biotite Granite Kræmer Ø Syenite Kangerlussuaq Syenite Intrusion Snout Series Syenite Snout Series Syenite Kærven Complex Gabbro Kærven Complex Alkali Granite 68.15 68.22 68.25 68.25 68.30 68.40 68.40 333132 NM27025 EG4583 312139 81-48 85659 40160 Biotite Biotite Biotite Biotite Biotite Biotite Amphibole 46.6 50.4 50.8 45.6 47.0 55.1 52.8 0.9 1.0 1.1 0.3 0.5 1.4 1.3 5 4 7 12 6 5 4 98 95 96 98 55 76 99 2.4 1.4 0.5 1.0 0.1 0.8 2.3 279 ± 34 417 ± 34 313 ± 69 673 ± 269 283 ± 11 673 ± 93 690 ± 48 Isochron Isochron Isochron Isochron Isochron Isochron Isochron 429285 457127 NM5133 457163 436094 Amphibole Biotite Amphibole Biotite Biotite 41.5 51.8 46.7 36.6 50.2 0.9 1.1 1.0 0.5 1.2 2 7 2 11 9 92 90 64 99 98 4.9 0.4 6.1 0.7 1.2 – 310 ± 8 – 301 ± 7 371 ± 57 Plateau Isochron Plateau Isochron Isochron Wiedemann Fjord–Kronborg Gletscher lineament Wiedemann Fjord Lamprophyre Dyke 68.55 Ejnar Mikkelsen Fjeld Intrusion Gabbro 68.80 Borgtinderne Intrusion Syenite 68.85 Borgtinderne Basanite Dyke 68.85 Kronborg Gletscher Nephelinite Diatreme 68.90 Age 2σ N (Ma) (Ma) 39 Location Sample (approximate no. decimal N) Ages are reported relative to biotite monitor FCT-3 of 28.02 Ma and 2σ includes error in the J value; #recombined total fusion age. for the Kruuse Fjord gabbro complex located inland along the Agtertia lineament (Tegner et al., 1998a). 3.6. Patulajivit gabbro complex The small islands of Patulajivit and Igtutarajik (Fig. 4) are composed mainly of layered gabbro with frequent slump structures similar to coastal gabbros south of Kangerlussuaq Fjord (Tegner et al., 1998a). Sample P-175 from Patulajivit is taken from a pocket of coarse-grained leucogabbro formed by partial melting of a metabasalt xenolith (Dennis K. Bird, pers. comm., 2005). A similar phenomenon is described in the Kap Edvard Holm complex (Brandriss et al., 1996). Biotite from P-175 did not produce an age plateau nor an isochron correlation (Fig. 7). A recombined total fusion age gives 47.2 ± 0.8 Ma. This is identical to the age of 47.3 ± 0.3 Ma obtained for a gabbro-pegmatite pod in gabbros of the nearby island of Igtutarajik (Tegner et al., 1998a). 3.7. Kangerlussuaq Alkaline Complex This huge complex (N 800 km2) crops out west of Kangerlussuaq Fjord (Fig. 5). Its main constituent is the Kangerlussuaq Syenite Intrusion, which is known for concentric zoning from strongly undersaturated foyaite at the centre, oversaturated pulaskite to an outer zone composed of oversaturated quartz-syenite (nordmarkite) (Kempe et al., 1970; Riishuus et al., 2006). Biotite from sample EG4583 from the pulaskite zone yields an age of 50.8 ± 1.1 Ma (Fig. 8; Table 1) and is within error of previous age estimates (Fig. 3). If the three syenite zones are cogenetic, as the lack of intrusive contacts indicate (Kempe et al., 1970), and are related to one another by concurrent assimilation and fractional crystallization in one magma chamber (Brooks and Gill, 1982; Nielsen, 1987; Riishuus et al., 2006), the reported age can be considered representative of the entire intrusion. The Kangerlussuaq Alkaline Complex includes several satellite intrusions that either cut or are cut by the Kangerlussuaq Syenite Intrusion. In the northeast, the Kangerlussuaq Syenite Intrusion cuts across the Kærven Complex (Fig. 5). This older complex is composed of an outer gabbro body along its eastern and northeastern contact and is, in turn, cut by several ring-shaped syenite and alkali granite bodies with decreasing ages to the west (Holm, 1991). A gabbro sample (85659) of the structurally oldest unit, and an alkali granite sample (40160) that represents the structurally youngest unit of the Kærven Complex (Holm, 1991) are dated. Biotite 492 C. Tegner et al. / Lithos 101 (2008) 480–500 from the gabbro yielded an age of 55.1 ± 1.4 Ma (see Section 3.3) and amphibole of the alkali granite gave 52.8 ±1.3 Ma (Fig. 8, Table 1). A U–Pb zircon age of 53.0 ±0.3 Ma for a gabbro-pegmatite at the northern contact of the complex (Holm et al., 2006) suggests that gabbroic activity was prolonged over 1–2 m.y. and overlapping with syenite and granite intrusions. A previous investigation of the same alkali granite sample by 40Ar–39Ar incremental heating experiments yielded ages of 58.1 ±1.1 Ma for amphibole and 58.5 ± 0.4 Ma for K-feldspar (Holm, 1991). However, the amphibole age is the average of only 2 discordant steps that make up nearly all the gas released while the feldspar age is the average of 3 concordant steps (c. 45% gas) in a Ushaped release pattern with minimum ages of c. 45 Ma. Neither of these release patterns qualifies as plateau ages, and both lack assessment of excess argon. We therefore conclude that the Kærven Complex was emplaced between 55.1 ± 1.4 and 52.7 ± 0.8 Ma and thus predates the Kangerlussuaq Syenite Intrusion by at least 1 m.y. We report the first radiometric ages for satellite intrusions that cut across the southeastern periphery of the Kangerlussuaq Syenite Intrusion (Fig. 5). The Snout Series nordmarkite cuts the eastern margin and basement gneisses north and south of Søndre Syenite Gletscher (Nielsen, 1987). The northern sample 81-48 yielded an age of 47.0 ± 0.5 Ma and sample 312139 from south of the glacier gave an age of 45.6 ± 0.3 Ma. This is close to the low end of zircon FT ages of 50–47 Ma for the Snout Series (Gleadow and Brooks, 1979) and a Rb–Sr age of 47.1 ± 0.7 Ma for the nearby Astrophyllite Bay diorite–syenite complex (Riishuus et al., 2005). To the south of Amdrup Fjord (Fig. 5), the ∼ 25 km2 Kangerlussuaq Biotite Granite cuts the Kangerlussuaq Syenite Intrusion and basement (Deer and Kempe, 1976). Judging from the scarcity of cross-cutting dykes (our observation), this biotite granite appears to represent some of the youngest plutonic activity in the area. Biotite from granite sample 333132 yielded an age of 46.6 ± 0.9 Ma, reinforcing this impression. In the periphery of the Kap Edvard Holm complex (Fig. 5), syenite intrusions Hutchinson 1 and 2 formed down to ∼ 42 Ma (Nevle et al., 1994). There are even younger lamprophyre dykes with inclusions of gabbro and syenite in Amdrup Fjord for which FT and K–Ar ages range from 37 to 34 Ma (Gleadow and Brooks, 1979), and minor volcanic and hydrothermal activity of the Flammefjeld ore deposit dated at 39.7 ±0.1 Ma by Re– Os of molybdenite (Brooks et al., 2004). Hence, igneous activity in the Kangerlussuaq Alkaline Complex spans at least 15 m.y. from ∼ 55 to ∼ 40 Ma. 3.8. Gardiner Complex The Gardiner Complex forms a circular, strongly undersaturated alkaline complex between the head of Kangerlussuaq Fjord and the ice cap (Fig. 5) (Nielsen, 1987). Two 40Ar–39Ar ages are presented in a different context in a parallel contribution (Heister et al., in preparation) but are also briefly discussed here in the present context. One sample of the second oldest magmatic phase of ijolite dykes (Nielsen, 1994) yielded an age of 56.5 ±0.3 Ma (biotite from sample 29904). A sample from a melilitolite ring dyke that cuts all other rocks of the complex gave an age of 54.7 ± 1.2 Ma (biotite from sample 303825). This age is within error of an isotope dilution Rb–Sr age of 56.2 ± 2.4 Ma (Waight et al., 2002). 3.9. Kræmer Ø Syenite The Kræmer Ø Syenite at the mouth of Kangerlussuaq Fjord (Fig. 5) is composed of massive nordmarkite surrounded by a marginal breccia with large basalt xenoliths (Brooks, 1991). The possible relation to the Kangerlussuaq Alkaline Complex is obscured by the Fjord. Biotite separated from massive nordmarkite in sample NM27025 yielded an age of 50.4 ± 1.0 Ma (Fig. 8, Table 1). This intrusion is a chronological marker in that various dyke swarms mapped by Nielsen (1978) either cut or are truncated by it. 3.10. Alkaline intrusions in the Wiedemann Fjord– Kronborg Gletscher lineament Five new ages are reported for alkaline intrusions of this relatively unknown tectonic and magmatic lineament (Pedersen et al., 1997; Bernstein et al., 1998a; Nielsen et al., 2001) (Figs. 1 and 6). The alkaline and ultramafic– mafic Ejnar Mikkelsen intrusion was discovered in 2000, and is emplaced into Plateau Lavas in the lower eastfacing slopes of Ejnar Mikkelsen Fjeld, a prominent mountain located at the Y-fork in the Kronborg Glacier (Nielsen et al., 2001). Biotite separated from alkali gabbro sample 457127 yielded an age of 51.8 ± 1.1 Ma. To the north of Ejnar Mikkelsen Fjeld, several nephelinite diatremes were discovered in 1995 (A. K. Pedersen, pers. comm., 2000) cutting the Plateau Lavas (Fig. 6). Biotite separated from nephelinite sample 436094 yielded an age of 50.2± 1.2 Ma (Fig. 9; Table 1). The Borgtinderne Syenite Intrusion is emplaced into the Plateau Lavas east of Kronborg Gletscher and is dominated by leucocratic nepheline syenite that intrudes alkali gabbro and pyroxenite (Brown et al., 1978; Nielsen et al., 2001). Amphibole from sample NM5133 of leucocratic C. Tegner et al. / Lithos 101 (2008) 480–500 nepheline syenite yielded an age of 46.7 ± 1.0 Ma. This is within the range of earlier titanite FT (49–46 Ma; Gleadow and Brooks, 1979) and K–Ar ages (49–40 Ma; Beckinsale et al., 1970; Noble et al., 1988). Swarms of lamprophyre and basanite dykes trending approximately N–S cut the Plateau Lavas, the above-mentioned plutons, and the Lilloise Complex (50.3 ± 0.4 Ma; Tegner et al., 1998a) (Fig. 6) (Pedersen et al., 1997; Bernstein et al., 1998a; Nielsen et al., 2001). An age of 41.5 ± 0.9 Ma is obtained for amphibole of sample 429285 from one of many N–S trending lamprophyre dykes with mantle xenoliths at Wiedemann Fjord (Bernstein et al., 1998a). Biotite from a basanite dyke (also carrying mantle xenoliths; sample 457163) cutting leucocratic syenite of the Borgtinderne Syenite Intrusion, yielded an age of 36.5 ± 0.5 Ma. There is no apparent systematic relation between age and location of the intrusions in this lineament. 4. A revised chronology for magmatism in central East Greenland 4.1. Chronology of plutons Fig. 10 summarises precise 40Ar–39Ar, U–Pb, Rb–Sr and Re–Os ages for intrusions of central East Greenland. A striking feature is the dominance of post-break- 493 up plutons of both alkaline and tholeiitic compositions. In the coastal zone south of the Kangerlussuaq Fjord lineament, the plutons are emplaced in three time windows at 56–54 Ma, 50–47 Ma and 37–35 Ma. In contrast, within the Kangerlussuaq Fjord lineament, the age of intrusions spreads from 56 to 40 Ma. North of the Kangerlussuaq Fjord lineament, the tholeiitic Sorgenfrei Gletscher Sill Complex was emplaced at ∼ 56–55 Ma. In the Wiedemann Fjord–Kronborg Gletscher lineament, the plutons are alkaline and span the period from 52 to 46 Ma. 4.2. Chronology of dyke swarms Several generations of dyke complexes have been described in central East Greenland. Here we use crosscutting relations and available radiometric ages (Nielsen, 1978; Klausen and Larsen, 2002; Hanghøj et al., 2003) to reevaluate their chronology. In the coastal zone, the dominant coast-parallel dykes termed either THOL-1 (Nielsen, 1978), Tholeiitic Series (Hanghøj et al., 2003) or Late Type 1 (Klausen and Larsen, 2002) are dark dolerites that were rotated seawards during breakup. They are interpreted as feeders to the overlying Plateau Lavas and the Sorgenfrei Gletscher Sill Complex (Nielsen, 1978; Hanghøj et al., 2003). One of these dykes was dated at 56.6 ± 0.6 Ma (Tegner et al., Fig. 10. Summary of precise 40Ar–39Ar, U–Pb, Rb–Sr and Re–Os ages for intrusions in central East Greenland plotted vs. distance from Ammassalik (sample locations projected to a line between Ammassalik and Scoresby Sund, Fig. 1). The rift-to-drift transition corresponds to the approximate age consistent with magnetic anomalies at the continent–ocean boundary (Larsen, 1990). 40Ar–39Ar intrusion data from: (Holm, 1991) (n = 1); (Nevle et al., 1994) (n = 3); (Hirschmann et al., 1997) (n = 1); (Tegner et al., 1998a) (n = 10); Heister et al. (in preparation) (n = 2), and this study (n = 16). U–Pb intrusion data from Holm et al. (2006) (n = 2). Rb–Sr intrusion data from Waight et al. (2002) (n = 1) and Riishuus et al. (2005) (n = 1). Re–Os intrusion data from Brooks et al. (2004) (n = 1). Also shown are 40Ar–39Ar age ranges of tholeiitic and alkaline lavas (Heister et al., 2001; Hansen et al., 2002; Peate et al., 2003; Storey et al., 2007a). Magnetic chrons from Gradstein et al. (2004). 494 C. Tegner et al. / Lithos 101 (2008) 480–500 1998a). At Kap Gustav Holm located south of the present study area (Fig. 4), a seawardly-rotated dyke has been dated by 40Ar–39Ar to 54.7 ± 1.5 Ma (Lenoir et al., 2003). Hence, the dominant, seawardly-rotated part of the dolerite dyke complex is coeval with the Sorgenfrei Gletscher Sill Complex and the Plateau Lavas (Tegner et al., 1998a; Hansen et al., 2002; Storey et al., 2007a). In the coastal zone, the coast-parallel, post-breakup dykes are light-grey to grey or chocolate-brown and termed TRANS (Hanghøj et al., 2003; Nielsen, 1978) or Type 2 (Klausen and Larsen, 2002). Their compositions are transitional between tholeiitic and alkali basalt and comparable flood basalts are not known in East Greenland (Hanghøj et al., 2003). These dykes are often close to vertical and therefore post-date coastal rotation (Lenoir et al., 2003). They are typically cut by the coastal layered gabbros and syenites (Nielsen, 1978) and form a pattern that appears to emanate from the large post-breakup gabbro complexes (Bernstein et al., 1992; Klausen and Larsen, 2002; Callot and Geoffrey, 2004). One of these vertical dykes at Kap Gustav Holm was dated to 48.0 ± 2.8 Ma (Lenoir et al., 2003), corroborating to the close spatial and petrogenetic relationship with the gabbro complexes dated at 50–47 Ma (Tegner et al., 1998a) (Fig. 10). Coast-parallel, alkaline basaltic dykes (ALK-1, Nielsen, 1978) cut across the 47.6 ± 0.3 Ma middle series of the Kap Edvard Holm gabbro complex (Tegner et al., 1998a) and therefore extend to younger ages than the transitional dykes. A highly variable group of alkaline to strongly alkaline dykes including lamprophyre and basanite (ALK2) have been described in the Kangerlussuaq Fjord (Nielsen, 1978) and the Wiedemann Fjord–Kronborg Gletscher lineaments (Bernstein et al., 1998a). Two ALK-2 dykes in the Wiedemann Fjord–Kronborg Gletscher lineament are dated at 41.5 ± 0.9 Ma and 36.6 ± 0.5 Ma (Table 1), which indicates the likely time span of these dykes. In the Kangerlussuaq Fjord, most dykes are older than 46.6 ± 0.4 Ma, the age of the crosscutting Biotite Granite. The quartz porphyry dykes of Flammefjeld and the late lamprophyre dykes north of Amdrup Fjord, however, extend down to ages of 39.7 ± 0.1 Ma (Brooks et al., 2004) and 37–34 Ma (Gleadow and Brooks, 1979), respectively. 5. Petrogenesis of post-breakup alkaline magmatism Nielsen (1987) reviewed the petrology of alkaline plutons, dyke complexes and lavas between 66° and 75°N. The large plutons range from alkaline ultramafic and mafic cumulates over foyaite and silica-undersaturated syenite to quartz-syenite (Brooks and Nielsen, 1982; Deer, 1976). Despite this rich compositional variety, Nielsen (1987) demonstrated that there were essentially two kindreds of alkaline magmas; one was strongly undersaturated nephelinite and includes trachybasalt and phonolite derived by fractional crystallization. The other kindred is mildly alkaline and appears to represent the waning stages of tholeiitic magmatism. Isotope compositions (Sr, Nd, Hf, Pb, H and O) of the ultramafic and foyaitic plutonic rocks of the Gardiner Complex, the Kangerlussuaq intrusion, and the Lilloise intrusion are similar to those estimated for Iceland plume mantle (Pankhurst et al., 1976; Nielsen and Holm, 1993; Chambers and Brown, 1995; Bernstein et al., 1998b; Riishuus et al., 2006). The quartz-syenites and granites also relate to a nephelinite parent but often with significant crustal assimilation (Brooks and Gill, 1982; Nielsen, 1987; Riishuus et al., 2005, 2006). The mildly alkaline, post-breakup magmas, likewise, have Sr–Nd–Hf–Pb–Os isotopic and trace element compositions consistent with mixing between enriched Iceland plume mantle and local Archean crust (Brown et al., 1996; Peate et al., 2003; Storey et al., 2004). The formation of alkaline magmas with Icelandic isotopic compositions has been explained by preferential melting of enriched mantle components beneath thick, cold lithosphere that suppresses melting of ambient upper mantle peridotite (Bernstein et al., 2001; Peate et al., 2003). This enriched plume signature carries evidence of either recycled oceanic lithosphere (Bernstein et al., 2001; Peate et al., 2003) or mantle metasomatised during the crossing of the rifted margin over the axis of the ancestral Iceland mantle plume (Storey et al., 2004; Riishuus, 2005). In the following section, we discuss the possible mechanisms that triggered melting of enriched mantle components in the coast-orthogonal lineaments up to 100 km inland from the continent–ocean boundary and up to 20 m.y. after continental breakup. 6. Linking intrusions and rift-to-drift 6.1. Review of rift-to-drift models A prolonged history of overlapping spreading ridges and rift jumps in the central Northeast Atlantic adjacent to the study area demonstrates that the rift-to-drift transition was complicated. Lundin (2002) argued that the Atlantic spreading system propagated northwards in the proto-Reykjanes and proto-Kolbeinsey ridges, close to present-day East Greenland coast. At the same time the Arctic spreading system propagated southwards by way of the proto-Mohns and proto-Aegir ridges, creating overlapping spreading ridges on the Greenland–Iceland C. Tegner et al. / Lithos 101 (2008) 480–500 Rise that persisted to chron 6 (∼23 Ma) (Fig. 11c). In this model, the Jan Mayen micro-continent was rifted away from East Greenland by anti-clock rotation in response to 495 northwards propagation of the proto-Kolbeinsey ridge (Nunns, 1983). According to others (Nunns, 1983; Scott et al., 2005), the proto-Aegir ridge was displaced to the east at the time of breakup and connected to the protoReykjanes and proto-Mohns ridges via two transform faults (Fig. 11a). In the model of Larsen (1988), a strongly curved “initial line of opening” (not shown in Fig. 11) included the proto-ridges shown in Fig. 11a but did not involve major transform faults. In these scenarios, the proto-Kolbeinsey ridge was subsequently initiated on the Greenland–Iceland Rise close to the present-day Blosseville Kyst and propagated northwards (Nunns, 1983; Larsen, 1988; Scott et al., 2005). In contrast to Nunns (1983) and Lundin (2002), Scott et al. (2005) argued that the propagation of the protoKolbeinsey ridge and the retreat of the Aegir ridge were linked by left-lateral, east–west trending transform zones resulting in differential displacement of blocks of the micro-continent (Fig. 11b). This was caused by a counter-clockwise shift in the direction of plate movement (plate vectors in Fig. 11a and b). We note that the proposed models unanimously involve northward propagation of the proto-Kolbeinsey ridge close to the East Greenland margin long after continental breakup and flood basalt volcanism. The leading tip of this system must have been a continental rift that developed into oceanic spreading as it propagated northwards (Fig. 11b). The northwards younging of magnetic seafloor anomalies along the Blosseville Kyst (Fig. 1b) constrain the history of ridge propagation. Identification of magnetochron 21 offshore the southern Blosseville Kyst shows that the inception of the protoKolbeinsey ridge took place at ∼ 47 Ma or slightly older. The presence of magnetochron 6 offshore from the Scoresby Sund area (Fig. 1b) pinpoints the connection Fig. 11. Schematic maps showing the physiography of proposed early rift systems of the Northeast Atlantic. a) The initial spreading configuration (∼ 50 Ma) of the proto versions of the Reykjanes ridge (RR), the Aegir ridge (AR) and Mohns ridge (MR) linked via major transform zones (Scott et al., 2005). Also shown are the tentative locations of the Kangerlussuaq Fjord tectonic lineament (KF) (Karson and Brooks, 1999) and post-breakup alkaline plutons at the inland extension of the southern transform zone. b) Illustration at ∼40 Ma of the separation of the Jan Mayen micro-continent (JM) and the Blosseville Kyst (BK) by northwards propagation of the protoKolbeinsey ridge (KR) linked to retreat of the Aegir ridge via leftlateral transform zones (Scott et al., 2005). Tentative placing of the Wiedemann Fjord–Kronborg Gletscher (WK) tectonic lineament (Pedersen et al., 1997) and alkaline intrusions are also shown. c) Illustrates the overlapping spreading model of Kolbeinsey and Aegir ridges (∼ 30 Ma) of Lundin (2002). Abbreviations: IP = Iceland plume; WJMFS and EJMFS = Western and Eastern Jan Mayen Fracture Zone, respectively. 496 C. Tegner et al. / Lithos 101 (2008) 480–500 of the proto-Kolbeinsey ridge, via the Jan Mayen Fracture Zone, to the Mohns Ridge at 23 Ma, establishing the present-day spreading configuration of the Northeast Atlantic (Fig. 1a) (Nunns, 1983). 6.2. Model for the formation of post-breakup intrusions The age of seafloor basalts given by the magnetochrons along the continent–ocean boundary is compared to the age of intrusions in Fig. 10. In the northern part of the study area, the oldest seafloor basalts formed roughly contemporaneously with the ∼ 52–36 Ma plutons and dykes in the Wiedemann Fjord–Kronborg Gletscher lineament. The north–south trend of the Wiedemann Fjord–Kronborg Gletscher lineament (Figs. 1 and 6) leads us to suggest that this magmatism represents a continental rift zone related to the northward propagation of the proto-Kolbeinsey ridge (Fig. 10c), perhaps into a pre-existing tectonic lineament (Pedersen et al., 1997; Karson and Brooks, 1999). This rifting attempt failed, probably because it propagated into thick, cold continental lithosphere. At more or less the same time (∼ 55–40 Ma) abundant and voluminous syenite, granite and gabbro plutons were emplaced into the Kangerlussuaq Fjord lineament (Figs. 1 and 5). This lineament has been interpreted as a failed arm of a major triple junction (Brooks, 1973; Karson and Brooks, 1999) and coincides with the continent-ward extension of the transform fault separating the proto-Reykjanes and proto-Aegir ridges (Fig. 11a). We therefore explain the plutons of the Kangerlussuaq Fjord as a result of prolonged off-axis mantle melting beneath a pre-existing tectonic lineament (Fig. 11a). In contrast to the coastal area south of Kangerlussuaq Fjord where magmatic activity is confined to three time windows at 56–54 Ma, 50–47 Ma and 37–35 Ma (Tegner et al., 1998a), magmatism in the Kangerlussuaq Fjord lineament appears to be continuous but with most activity in these time windows (Fig. 10) (Holm et al., 2006). This reinforces the view of an origin by off-axis magmatism focused in a major tectonic lineament. We note that the Snaefellsnes Volcanic Zone in Iceland (Fig. 1b) bears many similarities to the Kangerlussuaq Fjord lineament. Here it has been suggested that contraction of the lithosphere during cooling of the thick hotspot-generated crust created a zone of weakness triggering renewed magmatism (Steinthorsson et al., 1985). Such a mechanism could contribute to prolonged alkaline activity of the Kangerlussuaq Fjord lineament. Below we discuss the role of the Iceland mantle plume in driving post-breakup magmatism in East Greenland. Many islands and headlands south of Kangerlussuaq Fjord are composed of layered gabbro plutons cut by syenite and granite intrusions (Fig. 4) (Myers, 1980; Brooks and Nielsen, 1982). The plutons are most abundant in the vicinity of the tectonic lineaments outlined by Karson and Brooks (1999). The intrusive activity is confined to three time windows at 56–54 Ma, 50–47 Ma and 37–35 Ma (Fig. 10). The activity at 56–54 Ma, that includes the oldest part of the Imilik Gabbro Complex (Tegner et al., 1998a) and the seawardly-rotated part of the dyke complex (Lenoir et al., 2003) relates to the breakup event. Most of these intrusions are 50–47 Ma (Fig. 10) and have been interpreted as renewed magmatism caused by the crossing of the East Greenland margin over the axis of the Iceland plume (Tegner et al., 1998a; Bernstein et al., 1998b). The origin of the 37– 35 Ma syenite, granite, and diorite intrusions of the Kialineq area (Fig. 4) is more difficult to explain. Passage of the rifted margin over the plume axis, for example, cannot explain peaks in magmatic activity both at 50–47 Ma and 37–35 Ma. The magmatic hiatus between 47 and 37 Ma (Fig. 10) and the distance to the proto-Reykjanes spreading ridge at the time suggest that off-axis magmatism is not a viable explanation either. Apatite FT thermochronology demonstrates a pronounced regional uplift of the rifted margin at ∼36 Ma (Brooks, 1973; Gleadow and Brooks, 1979; Hansen and Brooks, 2002). This uplift has been correlated to magmatism and offers the best explanation for the generation of these intrusions, and possibly relate to plate-tectonic reorganization associated with cessation of spreading in the Labrador Sea (Nunns, 1983; Brooks et al., 2004). 6.3. Role of the Iceland plume Brooks (1973) and Morgan (1981) explained the anomalously thick oceanic crust of the ∼300 km wide Greenland–Iceland–Faroes rise as the trace of voluminous plume magmatism centred on the spreading ridge of the Northeast Atlantic (Fig. 1a). This view is adopted by many subsequent workers (Larsen and Jacobsdottir, 1988; White and McKenzie, 1989; Saunders et al., 1997). Holbrook et al. (2001) showed that the thickness of igneous crust of the Greenland–Iceland Rise is nearconstant at ∼ 30 km and requires continuous melting of upwelling mantle plume material. Plate-kinematic reconstructions, however, show that the Iceland plume was located beneath Greenland at the time of breakup and the rifted margin crossed over the plume axis after breakup (Lawver and Müller, 1994; Torsvik et al., 2001). Bernstein et al. (1998b) and Tegner et al. (1998a) argued that the abundance of 50–47 Ma layered gabbro C. Tegner et al. / Lithos 101 (2008) 480–500 complexes in East Greenland (Fig. 10) recorded this crossing. As discussed above, the magnetic seafloor anomalies offshore the Blosseville Kyst demonstrate a time gap between the main flood basalt succession in East Greenland erupted at 56–55 Ma (Storey et al., 2007a) and the oldest oceanic crust at the continent– ocean boundary (∼47–23 Ma) (Fig. 1b). Larsen (1988) explained this by initiation of spreading at the protoKolbeinsey ridge close to the East Greenland continent– ocean boundary caused by a westward relocation of spreading towards the axis of plume upwelling. Likewise, Müller et al. (2001) argued that thermal weakening due to the crossing of a young (b 25 m.y. old), volcanic rifted margin over a plume stem resulted in relocation of the spreading ridge over the plume. The rifting of the Jan Mayen micro-continent away from East Greenland was suggested as an example of this process (Müller et al., 2001). The isotopic similarities between the uncontaminated rocks of alkaline plutons in East Greenland (see above) and Iceland corroborated to the causal role of the Iceland mantle plume in post-breakup magmatism and prolonged rift-to-drift transition. 7. Conclusions Precise 40Ar–39Ar age determinations for syenite, granite, gabbro, diorite, nephelinite, basanite, lamprohyre, and strongly undersaturated alkaline intrusions revise the chronology of breakup and post-breakup magmatism of the central East Greenland volcanic rifted margin. South of Kangerlussuaq Fjord the plutons are mainly emplaced in the coastal zone close to coastorthogonal tectonic lineaments and are confined to three time windows at 56–54 Ma, 50–47 Ma and 37–35 Ma. In the Kangerlussuaq Fjord, which coincide with a major tectonic lineament possibly representing the failed arm of a triple junction, the ages of plutons span from 56 to 40 Ma. A north–south trending tectonic and magmatic lineament at Wiedemann Fjord–Kronborg Gletscher cuts the continental flood basalts of the Blosseville Kyst and includes alkaline plutons and dykes ranging from 52 to 36 Ma. Such prolonged post-breakup magmatism cannot be explained by a simple rift-to-drift transition of a volcanic rifted margin. We show that post-breakup magmatism of the East Greenland rifted margin was linked to reconfiguration of spreading ridges in the central Northeast Atlantic Ocean basin. The protoKolbeinsey ridge was established at ∼ 47 Ma close to the continent–ocean boundary of central East Greenland due to a westward relocation of spreading and propagated northwards splitting the Jan Mayen micro- 497 continent away from the Blosseville Kyst. We explain the intrusions of the Wiedemann Fjord–Kronborg Gletscher lineament as a failed continental rift in the early spreading history of the proto-Kolbeinsey ridge. The alkaline post-breakup intrusions of the Kangerlussuaq Fjord lineament are explained as off-axis magmatism to the proto-Kolbeinsey ridge. The crossing of the central East Greenland rifted margin, which was moving in a westerly direction, over the axis of the Iceland mantle plume was instrumental in causing a prolonged rift-to-drift transition and widespread and prolonged post-breakup tholeiitic and alkaline magmatism. This explains the asymmetry in the magmatic history of conjugate rifted margins of the central Northeast Atlantic. Acknowledgements We thank Dennis K. Bird, Kresten Breddam, Paul Martin Holm and Asger Ken Pedersen for providing samples SA-1, P-175, 85659, 40160, and 436094. Lew Hogan and John Huard (Oregon State University) are thanked for assistance with analytical work. We appreciate reviews by Ingrid Ukstins Peate, Anthony A. P. Koppers and an anonymous colleague, and editorial handling by Nelson Eby. 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