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The Atom & Subatomic Particles Atomic Number atomic = size nuclear charge = number protons determines identity element orders elements on periodic table For number: neutral atoms: atomic number = number electrons What is an atom? What we knew by 1932: Relative Charge Relative Mass Electron, 0e -1 .0005486 amu (or 0 amu) Proton, 1p or 1H +1 1.0073 amu (or 1 amu) 0 1.0087 amu (or 1 amu) -1 1 1 Neutron, 1n 0 Location of Subatomic Particles • Electrons located outside nucleus • Protons & neutrons located inside nucleus • Protons & neutrons = nucleons Isotopes atoms of same element: different # neutrons (mass # is different) # protons stays same! (atomic # is same) How Dalton’s theory was modified: 1. 2. atom is divisible (protons, neutrons, electrons) atoms same element can be different (different # neutrons) Mass Number Mass number = # protons + # neutrons Notation 12C 6 •left superscript is mass number •left subscript is atomic number Notation 12C 6 12 = # protons + neutrons 6 = # protons How many neutrons in this atom? 12 – 6 = 6 neutrons 17 O 8 Mass number is ? 17 Atomic number is ? 8 # of neutrons is ? 17 – 8 = 9 # of electrons in atom is? 8 15 N 8 Mass number is ? 15 Atomic number is ? 7 # of neutrons is ? 15 – 7 = 8 # of electrons in atom is? 7 19F Mass number is ? 19 Atomic number is ? 9 # of neutrons is ? 19 – 9 = 10 # of electrons in atom is? 9 Other Notations Might also see: C-12 number following symbol is mass number! Need to look up atomic number What’s the difference between H-1, H-2, and H-3? All H’s have 1 proton H-1: mass # = 1 H-2: mass # = 2 1 proton, 0 neutrons 1 proton, so it must have 1 neutron H-3: mass # = 3 1 proton, so it must have 2 neutrons Consider U-234, U-235, & U-238 What’s the atomic number of U? 92 How many protons in U? 92 How many neutrons in U-234? 234 – 92 = 142 How many neutrons in U-235? 235 – 92 = 143 How many neutrons in U-238? 238 – 92 = 146 How many electrons in U? 92 How many neutrons in Po-217? What’s How So the atomic number? 84 many protons? 84 the neutrons are … 217 – 84 = 133 neutrons! IONS Atoms: electrically neutral so ... # electrons EQUAL # protons IONS = atoms that gained or lost electrons protons and electrons ARE NOT equal anymore, so ions are not neutral they carry a charge (+/-) IONS Calculate charge of ion: # protons minus # electrons (subtract the electrons since are negative) IONS If atom loses electrons, it has more positive charge than negative (p+ > e-) What kind of ion is it? positive If atom gains electrons, it has more negative charge than positive (e- < p+) negative What kind of ion is it? Charge of Ions Ion charge written as right superscript Cl-1 Na+1 a sodium ion with a charge of +1 O-2 a chloride ion with a charge of -1 an oxygen ion with a charge of -2 If no right superscript, it’s understood to be zero and therefore a neutral atom Putting it all together How many protons, neutrons, & electrons in each of the following 23Na+1 1 Lost 1 11 p, 12 n, 10 e 25Mg+2 12 Lost 2 12 p, 13 n, 10 e 34S-2 16 Got 2 16 p, 18 n, 18 e 64Zn+2 30 Lost 2 30 p, 34 n, 28 e What is an amu? atomic amu mass unit 1/12 mass of C-12 atom C-12: used as reference for atomic mass Atomic Weight or Mass Atomic mass is relative 1st H-1 used as standard: 1 atom of H = 1 amu next O combines with many elements 1 atom of O = 16 amu's Now O-16 used as standard: C-12 is the standard: 1 atom of C-12 has a mass of exactly 12 amu's