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Intensive Set Chapter 2 Basic 1. If an atom contains 16 protons and 18 neutrons, what is its mass number? Write the shorthand representation for that atom and name it. 2. If a neutral atom has a mass number of 13 and an atomic number of 6, how many protons, neutrons, and electrons are in that atom? Write the shorthand representation for that atom and name it 3. Natural oxygen consists of 99.76% 16O (15.9949 u), 0.0400% 17O (16.9991 u) and 0.02000% 18O (17.9992 u). What is the average atomic mass of oxygen? 4. Calculate the average atomic mass of magnesium. Magnesium consists of three isotopes: 24Mg = 23.985 u with a percent abundance of 78.99%, 25Mg = 24.986 u with a percent abundance of 10.00%, the rest is 26Mg = 25.983 u. 5. Write the molecular and empirical formulas of each of the following compounds: a. an organic compound, heptanol, has 7 carbon atoms , 16 hydrogen atoms, and 1 oxygen atom b. Vitamin C, ascorbic acid, has six carbon atoms, eight hydrogen atoms, and six oxygen atoms c. Aspartane, an artificial sweetener, has 14 carbon atoms, 18 hydrogen atoms, and 5 oxygen atoms 6. Give the total number of atoms in TNT, C6H2CH3(NO2)3 and in Ge[S(CH2)4CH3]4. 7. Which of the following are correct formulas for ionic compounds? For those that are not, give the correct formula. a. Ca2O b. SrBr2 c. Li2O 8. Write formulas for the ionic compounds that can be formed by combining the cations, NH4+, Ni+2 with the anions CO3-2, SO4-2. 9. Give an example of each of the following: a. b. c. d. e. f. g. halogen transition metal noble gas nonmetal lanthanide alkaline earth metal actinide h. metalloid i. alkali metal Involved 1. Name the following ions. CN- ____________________ NO2- ____________________ PO43- ____________________ OH- ____________________ NH4+ ____________________ 2. Name the following compounds Na2S ____________________ BF3 ____________________ H3PO4(aq) ____________________ SO2 ____________________ Mg3(PO4)2 ____________________ N2O5 ____________________ LiNO3 ____________________ HCl(aq) ____________________ KMnO4 ____________________ P4S3 ____________________ 3. Write formulas for the following compounds. Tin (II) chloride ____________________ Nitric acid ____________________ Sulfur hexafluoride ____________________ Lithium phosphide ____________________ Barium sulfate ____________________ Titanium (IV) oxide ____________________ 4. Show that the following experiment is consistent with the law of conservation of mass (within the limits of experimental error): A 10.00 g sample of calcium carbonate was dissolved in 100.0 mL of hydrochloric acid solution (d = 1.148 g/mL). The products were 120.40 g of solution and 2.22 L of carbon dioxide gas (d = 0.0019769 g/mL). 5. Antimony has two stable isotopes, 121Sb and 123Sb, with masses of 120.9038 u and 122.9042 u respectively. Calculate the percent abundances of each of these isotopes. 6. Fill in the table Symbol Number of protons Number of neutrons Number of electrons 10 10 30 25 Name of the atom 58 Ni S 33 Challenging 1. The table below gives numbers of electrons, protons, and neutrons in atoms or ions of elements represented by A, B, C, …. Answer the following using the table: a. Which of the species are neutral? b. Which are negatively charged? c. Which are positively charged? d. Use the shorthand discussed in class to represent each of the species. A B C D E F G Number 5 10 18 28 36 5 9 of electrons Number 5 7 19 30 35 5 9 of protons Number 5 7 20 36 46 6 10 of neutrons 2. One isotope of a nonmetallic element has a mass number of 127 and 74 neutrons in the nucleus. The anion derived from this isotope has 54 electrons. Write the symbol for the anion. 3. Consider an atom of 64Zn. a. Calculate the density of the nucleus in g/cm3, knowing that the nuclear diameter is 9.6 x 10-6 nm and the mass of the 64Zn nucleus is 1.06 x 10-22 g. Recall that the volume of a sphere is (4/3)r3. b. Using the same formula for volume, calculate the density of the space occupied by the electrons in the zinc atom in g/cm3, given that the atomic radius is 0.125 nm and the electron mass is 9.11 x 10-31 kg. c. Having calculated the previous densities, what statement can you make about the relative densities of the parts of the atom?