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Igneous Rocks Intrusions and Volcanoes Igneous rocks are associated with molten material. This material can be from the mantel or melted crust material. Texture, iron content and silica content determine the type of igneous rock. The texture determines the cooling temperature. Rapid cooling gives small to no crystal formation. This means that the rock formed on the surface. The main minerals for igneous rocks are quartz, feldspar, mica pyroxene amphibole and olivine. Mantel rock will have mainly olivine, and pyroxene. Melted crustal rock has large amounts of quartz in it. Texture is a clue to the environment, internal (intrusive) or external (extrusive). This was known for 200 years and later confirmed with the developing of polarizing microscope and the careful grinding of a rock thin section (ground rock so thin light can pass through it). Texture is created by cooling temperatures. Ions in hot magma have too much energy to bond together and form a crystal. As cooling proceeds the ions lose energy and can then form crystals. Pressure will also help in this since it forces ions together regardless of the heat energy. If the cooling proceeds slowly as in intrusive material you have large crystals, if ejected into the surface you get small crystals or no crystals. Intrusive rocks are coarse textured (phanorytic.) These rocks have slow cooling regimes cooling over thousands and thousands of years in the crust of our planet. The heat is held in by the overlaying rock. Elephant rocks in Missouri are a perfect example of such a rock. This is an igneous intrusive body injected into the crust over a billion of years ago. Extrusive rocks have different types of appearances, one composed of fine grained aphenitic another by glassy (no crystals) rocks. These categories are dependent on how they erupted from the volcanoes. Lavas have a range of appearances dependent on their chemical make-up and temperature. Pyroclastic formation is characterized by violent eruption with lava thrown into high into the air. If the material is ejected rapidly and cools rapidly it forms volcanic glass- mineral free since amorphous. Pumice is a form of igneous rock that forms from volcanic glass with air pockets or vesicles. These vesicles are formed by the degassing of the molten material (CO2, H2O, etc.). Volcanic ash is composed of fragmented rocks, lavas and/or volcanic glass. It is thrown high in the air and smaller fragments will travel around the globe. Bombs have a range of shapes and made up of solidified lava. They are tossed into the air and fall along the sides of the volcanic cone. The last two are scoria and pumice. These are gas filed lava. Pumice (to the left) is so light that it floats. There is one more texture, a mixed texture indicating two different cooling regimes. This is called porphyritic texture or porphyry. Here a slow cooling regime starts and large visible crystals form. These are then there is a volcanic eruption before more large crystals can grow and this gives us the two different crystal types. Igneous material is also classified by chemical content. We break the material into four types according to the proportion of silicate minerals. Specific minerals form at specific temperatures. Minerals with a high proportion of iron and magnesium and calcium compared to silica form this group and are called mafic from magnesium. The mafic and felsic mineral suites are on page 112 in your book. The feldspar group is divided into potassium rich (orthoclase), sodium rich plagioclase and calcium rich plagioclase. The last two the sodium and the calcium are end the members of a solid solution where the plagioclase Labradorite- tectosilicate formula is NaAlSi3O8;CaAl2Si2O8. The more calcium in the plagioclase the more mafic the forming rock and - Ca(50-70%) Na(50-30%) (Al, Si)AlSi2 O8 the higher the melting temperature to the right is an example of these mixture. The more sodium, the more felsic the magma melt and the lighter the igneous rock( look at the chart on page 113). Mafic Rocks a have large amounts of olivine and pyroxenes giving the rocks their characteristic dark colors. There may be a small to moderate amount of calcium plagioclase. The lava form of this is called basalt. There are several areas of sheets of basalt such the Columbian Plateau along the Columbia River in Washington. India as an even larger area, the Deccan Traps, where kilometers thick layers of basalt contributed to the Cretaceous extinction event and another in Siberia with an area as large if not larger also associated with an extinction event (Permian). There is another mafic rock form. This form is called ultra-mafic. The mineral suite is primarily made up of olivine with a small amount of pyroxene. This is the material that makes up the upper mantel. The basalt upwelling at the spreading centers formed the ocean crust. Felsic Rocks are poor in iron and magnesium. They are also poor in calcium. These rocks tend to be light in color and one of the most abundant intrusive igneous rocks. They contain approximately 70% silica and are abundant in quartz and orthoclase feldspar with some sodium feldspar (albeit minerals). The intrusive form of this igneous rock is Granite, the extrusive form is Rhyolite. These rocks can appear as light brown, salt and pepper, pink, or orange or in some cases almost purple (Missouri rhyolite). The Picture on the left is an image of this rhyolite. Notice that it is porphyritic. Between the end members of these two rock types are the rocks that are called the intermediate. These rocks have less silica then the felsic and more than the mafic. They have some quartz, micas and may have some pyroxene. They may also have amphiboles. The intermediate is divided into granodiorite and diorite. Granodiortite is very difficult to differentiate from granite. This is done by looking at difference in the percentages of quartz, orthoclase and sodium plagioclase. We will then only talk about diorite and its extrusive form andesite. This material has a mineral suite with pyroxene like mafic and calcium plagioclase but it also has amphiboles, micas, a mix of the sodium/calcium plagioclase minerals and some quartz. The variation in the amount of silica gives its melt a variety of properties that can swing from one extreme to another. The last is the composition factor impacting the melting is the chemical formula. The more mafic the melt, the higher the melting temperature for mineral formation and mafic melts are characterized by less silica in the melt and more iron and magnesium. Conversely the more felsic the melt represented by more silica, the lower the melting temperature. ` We know from seismic waves that the Earth is solid until we reach the liquid outer core. Where does the magma come from? While we are still working on this question we do know some factors that impact the temperature at which this solid will melt. One of the big ones is pressure. Most of these solids are at such a high temperature that they should have melted. The pressure prevents this by preventing atoms from moving apart thereby keeping it a solid. The only way to overcome this is an even greater temperature. Water content also impacts this. Water enters the system at convergent plate boundaries and by water circulating naturally close to a magma body (think Yellowstone geysers). The last is the composition factor impacting the melting is the chemical formula. The more mafic the melt, the higher the melting temperature for mineral formation and mafic melts are characterized by less silica in the melt and more iron and magnesium. Conversely the more felsic the melt represented by more silica, the lower the melting temperature. Looking more closely at temperature it was found that a magma chamber only undergoes partial melting. This partial melt is determined by the temperature of the chamber and the mineral composition of the magma. Only certain minerals will melt at a given temperature. It is like the new "lava cake" desert. The cake turned solid at one temperature but the temperature wasn't low enough for the chocolate center to turn solid. As water enters the melt this temperature will lower for many of the minerals and there will be a more complete melt. We geologist use this information to determine how different kinds of magma form in different regions of the Earth's interior. Since magma is formed from rock in which only the minerals with the lowest temperature melts. As you go deeper into the Earth the pressure increases. This increase in pressure (as mentioned earlier) increases the melting temperature. Because of the convection currents mantel material will move to an area of lesser pressure in the region of the spreading centers. This allows for the decompression melting of the mantel creating the basalt of our seafloor. Water impacts the behavior on the melting temperatures. The impact of large amounts of water on melting temperatures can be seen with the mineral albite which melts at 1000oC. When water is added to the melt drops to 800oC. Water is present as a gas and dissolves into the molten albite. There is a rule to explain this. This states that if you dissolve one material into another lowers the melting temperature of the solution. It also impacts the melting temperature of mixture of other sedimentary and other rocks .These rocks are often water rich and will melt. Magma chambers are formed by the change in density as material is heated. The magmatic material will rise through and upward. Being fluid the partial melt moves up through the pores and boundaries of surrounding rock. As the drops of molten material rises they can coalesce into larger bodies. It also cam melt the host rock forming magma chambers or cavities in the lithosphere. Magmatic differentiation can partially account for the different types of igneous rock found on this planet. In the chamber as it cools high temperature mineral will form. This will remove more iron, magnesium and calcium/silica tetrahedrons creating the ultramafic and mafic material. This leaves behind more silicate tetrahedrons per cation so more high temperature minerals that are silica rich and felsic form. These only form, though, as the melt cools. The process is called fractional crystallization and gives different minerals in the same chamber. By studying the Bowin's Reaction Series (bottom of last page)you can predict a magma temperature by the minerals present. The diagram to the left demonstrates magmatic differentiation and fractional crystallization. The initial minerals that come out of the melt are more rich in iron and magnesium. As they crystalize out then remove these cations leaving behind a progressively more silica rich melt. By the time there is later crystallization the magma body has cooled and the excess silica gives you the minerals found on the lower portion of the Bowin’ s reaction series. While magmatic differentiation and fractional crystallization explains how there are different minerals in a magmatic intrusion it doesn't answer the questions of where did all of the granite come from. Granite is one of the most common igneous continental rocks. The idea rose of a complicated process that had both partial melting giving basaltic magma at the spreading centers followed by the formation of intermediate andisitic magma with the mixing of basaltic magma and sedimentary rocks at ocean-ocean convergent plate boundaries while the melting of igneous, metamorphic and continental crust at ocean-continental convergent plate boundaries might melt to produce granite if magmas. formation of rifts and is presently happening in the magma can then intrude into these fractures. Igneous intrusions take place as the rising magma intrudes into the country rock. They wedge open the overlying rock as the magma lifts up the overlying rock in extension. This lifting up and fracturing cam be seen with the Basin and Range of our own west. The As the body rises by breaking off the overlying rocks which may or may not melt into the chamber. If the rock pieces melt they will change the composition of the melt in that region. If they don't melt they remain as xenoliths in the magma that can be seen when the material cools and is exposed by weathering. The structures that form by these process are called Plutons and can be from one cubic kilometer to hundreds of kilometers in size. The largest of these plutons is called a Batholith. These large structures make up not a single mountains but entire chains of mountains such as the Sierra Nevada Mountains. Smaller plutons are called stocks and laccoliths are often the size of a single mountain. Material that squeezes through the cracks from these bodies can cut across the country rock making dikes. These magma bodies can also create their own cracks from the pressure they exert as they rise. These are not a linear structure as they appear in a road cut but are actually a three dimensional structure or can invade the country rock and spread along it in a horizontal structure called a sill. You can view a dike here in Missouri at the Silver Mines State Park and on State Highway 72 on the way to Arcadia. The last features associated with igneous bodies are hydrothermal veins. This can also be seen in sedimentary and metamorphic rocks. These can be as small as millimeters or as large as a km in size. These veins can be in the form of hydrothermal solutions often with quartz and valuable minerals dissolved in it. These originate as water that permeates the country rock (ground water) and forms into hydrothermal If they cool quickly they form small crystals forming a sheet like tabular structure. These veins are an important source of metallic ores. Magmas form at two types of plate boundaries, the mid-oceanic ridges, where there is divergence. The other plate boundary where magma is common is at the convergent plate boundaries. There is another major source of magma, the mantle plumes. This are not associated with plate boundaries and are the result of partial melting and form near the core-mantle boundary. At the mid-oceanic ridge there is a decompression melt which then seeps up the fissures at the divergent plate boundaries. The magma forms pillow lava of basalt. These columns of basalt are cut by dykes cutting into the basalt country rock. Below this is the magma chamber. In the magma chamber magmatic differentiation takes place with the olivine and pyroxenes precipitate out to form a peridotite layer. Adjacent to the magma chamber is a layer of gabbro. The gabbro layer is adjacent to the hotter magma layer becoming metamorphosed. Above the basalt layer is layers of sediment and sedimentary rocks. These form the Ophiolite Suites on land. This appears when to plates move so fast that the ocean plate is forced on and over the lighter continental crust. As the plates move further from the magma more gabbro forms. The areas of subduction are another area in which magma makes its way to the surface. The composition of the magmas are dependent on what is being subducted. With this form of magma there is fluid induced melting. The water in the subducting oceanic crust decreases the melting temperature of the overlaying mantel material (peridotite rich) and the basaltic crust. There is also a portion of sediment that is left on this subducting oceanic crust. This material has a very low melting temperature and melts readily. The composition of these magmas should be basaltic considering they are formed from the basaltic oceanic crust and the peridotite layer but there is a lot of variation. This variation comes from the amount of accumulated sediment and sedimentary rock that is incorporated. As the magma rises up and through the overlaying lithosphere there is also the effect of fractional crystallization giving an increasingly more silica rich melt. When the oceanic crust is subducted beneath a continental crust felsic rock melts and contribute to this melt. The different compositions of these melts and the amount of gases present have a major impact in the eruption style of the volcanoes that are formed in this area. The last type of "magma factories" is the mantle plume. They originate in the mantle itself and is thought as a mechanism for cooling the core. It forms a column of nucleated rock that rises up through the rest of the mantel in the shape of a diapere. When it reaches the lithosphere this flattens out and undergoes a decompression melt forming the magma and the models predict large scale of eruptions that can last millions of years such as the Deccan Traps in India and the Siberian Traps in Russia. While the models predict millions of years eruptions this is often not the case. This plume is often postulated to be fixed with the overlaying plate moving over it giving a string of volcanoes from the same magma chamber but of different ages. While this is often true there are other plumes that are geographically stable such as the one in Iceland and the Azores off of the coast of Africa. While plumes can either form flood basalts or strings of volcanoes the volcanic composition can very. The plume material itself is basalt with high temperature minerals containing a high iron and magnesium content and low silica content when they appear below a continent other process can take place. The underlying basalt magma can melt the continental rock; both the granite and the sedimentary rocks creating a more felsic melt with high silica content. Volcanic Eruptions Basaltic lavas are mafic in composition (high iron, magnesium and calcium) with the lowest of all magma compositions. The eruption temperatures from these lavas are high, anywhere from 1000 to 1200oC (1832-2192oF). This lava has the fastest downhill speed (62 mph) on a steep slope due to this high temperature and low silica content. This gives three different basaltic lava appearances. The high temperature fast moving is called pahoehoe a Hawaiian word. This gives pahoehoe aa a ropey appearance to the lava field. As the lava cools a skin forms over the flow with hot lava continues to flow beneath. As the lava cools and slows the "aa" forms. This forms a thick skin that breaks as it flows giving an angular blocky appearance. The last form that basaltic lava forms is pillow lava. This lava captures air as the lava flows over itself moving forward. This form develops as the magma erupts under water. This forms a bulbous form that resembles "pillows". Andesitic lavas from the andesitic magmas have a higher silica content than the basaltic lava this Pillow Lava means that the minerals formed at this lava is made up of lower temperature minerals, no olivine. This decreases the speed and distance of the flows. Their flows are stick forming blocky with few or no air vesicles. They seldom get beyond the intermediate area of the volcano itself. Rhyolite lavas are the highest in silica content (over 68%). The minerals are low temperature in nature and the silicate minerals are high in sodium and potassium. The temperature of this lava is 600-800oC (1,112-1,472oF). This lava seldom leaves the crater and moves 10 times slower than basaltic flows. Volcanic eruptions are not always in the form of lavas. If water comes into contact with hot, gas charged magma you can have a phreatic or steam explosion. One of the largest in history involved the island Krakatau. This eruption started from an andesite chamber. The volcanic islands magma chamber had emptied and collapsed (caldera formation) and sea water poured in triggering a violent phreatic explosion that sent a major tsunami into much Indonesia as well as sending ash and debris travelled over water onto the adjacent island of Sumatra. Pyroclastic flows and debris form when water and gases come out of the magma. Pressure in the magma chamber will keep these volatiles from escaping. When the pressure drops during an eruption the gases come out of solution. This can form an explosive eruption. This will shatter the overlaying rock and also form gas charged fragments in the air. Pyroclastics or tephra have different sizes and these different sizes have different names: 1. ash, 2. lapelli, 3. agglutinates, 4. bombs and 5. blocks The smallest is the volcanic ash and are less than 2 mm in size and are usually glass in nature. If you have larger blobs different things are formed. Blocks can are greater than 64 mm in size and are formed from angular solid rocks from the plugs in the volcano itself. Bombs are greater than 64 mm but are formed from molten magma and can have different shapes. Agglutinates form either cinders (scoria) or pumice depending on are 2-64 mm in Pumice size and are formed from smaller vesicular blobs. Pumice is formed from volcanic glass and the air filling the vesicles. Pumice is characterized by being able to float on water. The caldera eruption takes place when the magma chamber partially empties itself and triggers a collapse of the unsupported material (roof of the chamber). This then triggers a cataclysmic eruption with the pieces forcing upward and out with much of the remaining magma in the camber. The volcano doesn't present a cone at this stage but a large valley ringed by the edges of the former magma chamber. Calder eruptions can take place with any volcano but are common with volcanoes such as Yellowstone and stratovolcanoes. Volcanic processes- The anatomy of a volcano can vary depending on the volcano type. The common features for all volcanoes include a magma chamber and a transport mechanism. The magma chamber which lies in the crust portion of the lithosphere. The chamber is filled by rising magma from the asthenosphere or by the melting of the overlying rock by the rising magma. Next is the transport mechanism. This can be in the form of a central vent and side vents or from a fracture or fissure through the overlaying rocks and into the magma chamber. If there is magmatic eruption from a vent system you then get these volcanic features. The most common is the volcanic cone. The overall shape of this structure is dependent on the eruption type and the magma type. Craters are a bowel shaped pit at the summit of the volcanic cone. This is over type volcanic central vent. Another structure is the volcanic dome. This structure is associated with a more felsic magma and can act as a plug to the central vent trapping magma and gas beneath them. Here the pressure will increase until there is an explosion. The last feature is the caldera. Here the magma has escaped at such a rapid rate that the chamber can no longer support the overlaying rock. This rock then collapses into the chamber. This often leads to an even more violent eruption as the remaining melted material is expelled from the chamber. The picture on the left is the famous Crater Lake in Oregon. It is a 6 mile wide caldera that formed after the volcano Mt. Mazamo erupted over 7,000 years ago. The volcano in the center (Wizard Island) formed much later. Volcano Types Fissure volcanos are characterized by large lava fields that latter form plateaus. They are basaltic in nature and have little to no gas. If gases are present then you will see other volcanic forms associated with them. Massive flood basalts from fissure volcanoes have been linked to at least one extinction event, the Permian and possible another, the Cretaceous. There have been many smaller flood basalts from fissures, one of these is the Columbia Plateau in Washington and Oregon. Other examples of fissure volcanism are the massive spreading centers at the divergent plate boundaries. Shield volcanoes have a melt with gases as well as basalt magma. There is a central vent as well as side vents. The temperature and speed of flow gives the shape of this volcano. The initial lava is pahoehoe. This gives the gentle angle of the shield near the central vent. As the lava cools it forms aa and has a steeper angle along the sides of the volcano giving it the characteristic shield shape. These volcanoes are common in areas of divergence as well as oceanic hot spots such as Hawaii and the Galapagos islands. There are often fissures and side vents opening up on the sides of the shields. Stratovolcanoes form from two different types of eruptions. You have an alternation of pyroclastics and lava. This is due to the characteristics of the intermediate melt. When there is a high gas content combined with a silica rich melt (more felsic minerals such as sodium plagioclase, micas and quartz) you have an explosive eruption and the cone that forms is of rock fragments and assumes a steep angle. This material can be covered in a subsequent by lava when the melt is more basaltic in nature having less silica in it. This melt would have more high temperature minerals, plagioclases with more calcium and less sodium, pyroxenes and little mica. This coats the rock fragments and maintains the steep angle of the cone. These volcanoes are seen along convergent plate boundaries such as the Andes, the Cascades, Japan and the Aleutians. The last volcanic cone is the cinder-cone. This is made up by solid fragments builds up into a cone, this allows for a steep angled cone. These have a small central vent and the magma is gas charged. These can form on the flanks of shield volcanoes and stratovolcanoes. Once the gases have been expelled from the magma a side vent often opens and lava flows out. These volcanoes erupt only once then their vent seals with cold magma. There are multiple hazards with a volcanic eruption but while we have heard of many of these hazards such as lava and massive explosions. VOG or volcanic “smog” is seldom looked at. Volcanic gases vary in composition. Two of the most common gases are CO2 and H2O. The amount of CO2 is 0.25 gigatons a year. Large eruptions can have profound effects on global warming. Other gases include H2O. Other toxic gases include: HCL (hydrochloric acid), HF (hydrofluoric acid), CO (carbon monoxide) SO2 (sulfur dioxide) and H2S (hydrogen sulfide). The sulfur compounds will interact with water to form sulfuric acid. The picture to the right shows the gases exiting Kilauea’s central vent. These acidic gases cause widespread devastation to plant and animal life on both land and in the sea. This gas is reportedly equivalent to over a pack of cigarettes a day. To complicate things if the sulfur compounds enter the upper atmosphere the droplets from the acid they form reflects sunlight and causes widespread cooling. The eruption of Tambora caused a year without summer in 1815 and widespread starvation. The eruption of Toba approximately seventy thousand years ago is credited with a ten year volcanic winter and 1,000 years of cooling. We are overdue for such an eruption from Yellowstone and Long Valley volcanoes in the United States. Ash is a pyroclastic product. It is small enough in size that it and can travel miles away (smaller particles go worldwide) from the source. Ash clogs the stomata of plants preventing the exchange of gases and suffocating the plants. Ash is rock and volcanic glass shards. When animals breathe in ash it enters the lungs and damaging the alveoli. Exposure can and often does prematurely age these lungs. This material can also turn into a concrete like material and suffocate people and animals. Both ash and pumice adds weight to structures roofs. This weight can collapse buildings. One more problem with the ash is the impact on engines. These can get clogged by the ash and stop working. Jet engines are very susceptible to the ash and are the reason that jets are routed around or cancelled when there are ash clouds. The picture on the right shows layers of ash from Mt. St. Helens. This is a record of not just the 1980’s eruption of many past eruptions. Another hazard is the lahar. This is a mud flow is a mixture of volcanic debris and water. The water can be from melting glaciers as in Mt. St. Helens, or rain fall as in Mt. Pinatubo’s eruption. This mud flow can cover landscapes to hundreds of feet deep, destroys bridges and homes. With speeds up to 10-60miles/hour a lahar can be linked to thousands of deaths. They travel along existing water ways onto floodplains. The deadliest hazard of them all is the pyroclastic flows and surges. Both of these are a mixture of ash and toxic gases with temperatures as high as 1,000 °C (1,830 °F). Their speed is controlled by the slope of the volcano (steeper slope more speed) 700 km/h (450 mph). These are normally caused by the eruption column collapse. There are two layers, the basal layer will hug close to the ground and contains larger courser material. The upper layer is the extremely hot ash plume mixed with the toxic gases. There is mixing of the cold atmosphere and the hot gases due to the turbulence causing expansion and convection. The pyroclastic surge has less material and more gas making it act differently than the flow. Lacking the courser material makes the surge more turbulent and it can rise over ridges and hill crest while flows are more constrained. The first thing that I will talk about in predicting volcanic eruptions is what constitutes an active volcano. If there has been an eruption in the last 10,000 years the volcano or volcanic field it is active. After saying this there are exception to this rule. These are volcanoes that haven’t had an eruption in over 10,000 years. They are called active if they have indication of an active magma chamber beneath them such as thermal features (hot springs, geysers and mud pots), magmatic gases (sulfur gases, and CO2) and seismic activity. Two examples of ancient volcanoes that haven’t erupted in thousands of years are Long Valley and Yellowstone. To predict the eruption you monitor the region for the things that indicate activity. The first can be seismicity. There is a type of earthquake called the harmonic tremor that indicates magma entering a chamber. The seismogram to the right shows Mt. St. Helens harmonic tremors prior to eruption. Below is a seismogram supposedly shows Yellowstone with harmonic tremors during 2008. You also look for an increase in the release of magmatic gases such as CO2 and H2S and SO2. Both Long Valley and Yellowstone shows such an increase. Another indication of an impending eruption is ground deformation. This is normally measured by a tilt meter and indicated magma moving upward towards the vent. Below is a false color map showing not one bulge in Yellowstone but two. With magma moving upward closer to the surface you will also find an increase in surface temperatures. In 2002 the Norris Geyser Basin (arrow on the left) ground temperature rose to the temperature to the temperature of boiling water. I have been using both Long Valley and Yellowstone as examples of earthquake prediction for several reasons. The most obvious is that they both have all of the eruption indicators but haven’t erupted. The second reason is what such an eruption from these volcanoes would mean to mankind. The image to the right shows the extent of Yellowstone’s last eruption. The area stripped of vegetation is the area where large amounts of ash would be deposited. This ash deposit impacts the continental United States as far east as Louisiana and as far south as far as Mexico. This region is the bread basket of the world as well as the United States. So famine would fallow. It would propel sulfuric acid and ash into the stratosphere leading to a global winter for 10 years. The last time there was an eruption close to this magnitude (Toba ~74,000 years ago) there where many extinctions and close extinctions. The current theory is that the population of the Earth was reduced to 1,000 humans.