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Chapter 5 Measurements and Calculations 1 Scientific Measurements In science we have two types of observations: Qualitative: observations of color, odor, appearance, etc. Quantitative: observations of measurement. 2 Scientific Measurements Scientific measurements must always be represented as a number and a unit. During a lab, if units are not included, or improperly included, it could result in drastically different results. 3 Scientific Notation When using scientific notation for very large numbers: 1. Move the decimal to the left until there is only one digit between 1 and 10. 2. Count the number of places you move the decimal and make this the power of 10. 3. Rewrite your number as a decimal times 10 to the power of x. X= the number of places you moved the decimal. 4 Scientific Notation EXAMPLE: 930 1. Move the decimal to make the number between 1 and 10. 930 => 9.30 2. Multiply by 10 raised to a power of 2, because the decimal was moved 2 places. 9.3x 102 5 Scientific Notation When a very small number is involved, the decimal must be moved to the right instead of the left, in this case we make the power of 10 a negative number. 0.0000093 => move the decimal 6 places to the right. 9.3 x 10-6 6 Scientific Notation EXAMPLES: Convert to scientific notation: 1. 8,000 2. 75,600,000,000 3. 0.000000546 4. 0.0004876 7 Scientific Notation Multiplication and Division of Scientific Notation: When multiplying 2 numbers with exponents, you must add the exponents. EXAMPLE: (3.2 x 104)(2.8 x 103)= (3.2 x 2.8) x 104+3= 9.0 x 107 When dividing you subtract the exponents. EXAMPLE: 6.4 x 103 = 6.4/8.3 x 103-5 8.3 x 105 =0.77 x 10-2 = 7.7 x 10-3 8 Scientific Notation Addition and subtraction of scientific notation requires that all the numbers are raised to the same power of 10 EXAMPLE: 1.31 x 105 + 4.2 x 104 = 13.1 x 104 + 4.2 x 104 =(13.1 + 4.2) x 104 = 17.3 x 104 = 1.73 x 105 9 Dimensional Analysis In order to solve this problem and many others in chemistry we are going to use a process called dimensional analysis. We are going to analyze the dimensions or units involved here. First we must figure out the conversion factors. These are the numbers that help us convert from one unit to another. 1 dozen = ? cookies 1 package = ? cookies 10 Dimensional Analysis So the conversion factor for the first is 1 dozen = 12 cookies, also if we read the problem we can learn that 1 package = 6 cookies We can now use this information to calculate how many packages we need. 3 dozen x 12 cookies x 1 package = 6 pkgs. 1 1 dozen 6 cookies We can cancel units that are the top and bottom of the equation because this equals 1. 11 Dimensional Analysis If you divide 2 this equals 1. The same rule 2 applies when dividing units. Cookies = 1 cookies Or elephants = 1 elephants It does not matter what the unit is, if it is on the top and bottom of the equation, they equal 1. And anything times one is anything. 2x1= 2 or cookies x 1 = cookies 12 Dimensional Analysis So let’s look at our problem again. 3 dozen x 12 cookies x 1 package = 6 pkgs. 1 1 dozen 6 cookies The dozen cancels, the cookies cancel and we are left with only packages as a unit. IT IS VERY IMPORTANT TO ALWAYS CLEARLY WRITE DOWN YOUR UNITS!!! If you do not, you WILL lose track and your answer will become incorrect. 13 Dimensional Analysis Earlier we measured the length of a pin. We found this pin to be 2.85 cm, how many inches is this? There are 2.54 cm in 1 inch. 1. Before we start the problem, read carefully and find what we piece of information we are trying to calculate here. How many inches is the pin? 2. Then write down the information you are given. The pin is 2.85 cm and 2.54 cm = 1 in. 14 Dimensional Analysis Now we can set up our problem. 3. Always start with the given value, in this case it would be 2.85 cm. 2.85 cm x 1 inch = ? 1 2.54 cm 4. Next write in your conversion factor(s). 5. Now check your units and see if they cancel. If they don’t….then you need to find the missing units. 15 Dimensional Analysis 6. Draw a light line through your canceled units. 2.85 cm x 1 inch = 1.12 inches 1 2.54 cm 7. Multiply and divide you answer and add your final units to your answer. 8. Check your significant figures. 9. Ask whether your answer makes sense. 16 Dimensional Analysis 1. The length of a marathon race is approximately 26.2 miles. What is this distance in kilometers? HINT: 1 mi = 1760 yd and 1 m = 1.094 yd 17 Dimensional Analysis Your set up: 26.2 mi x 1760 yd x 1 m = 1 1 mi 1.094 yd Do the units cancel? What units is the answer supposed to be in? 18 Dimensional Analysis 26.2 mi x 1760 yd x 1 m x 1km = 1 1 mi 1.094 yd 1000 m Do your units all cancel? How many significant figures? What is the correct answer? Does this seem reasonable? 19 Temperature Conversions There are three scales used for measuring temperature: Fahrenheit – Part of the English System Celsius – Used in the metric system Kelvin – The base unit in the SI units and also known as the absolute scale. 20 Temperature Conversions The thermometers indicate the freezing pts and boiling pts on each scale. Notice there is an equal distance between the 2 pts on the Celsius and Kelvin scales, but not the Fahrenheit. 21 Temperature Conversions There are simple equations you can use to convert temperatures from one scale to another. Celsius -> Kelvin Because these units are equal, all we have to do is add 273 to the Celsius temperature. T°C + 273 = TK Kelvin -> Celsius TK - 273 = T°C 22 Temperature Conversions When converting with the Fahrenheit scale we must do more math because the scales are not equal units. Celsius ->Fahrenheit T°F=1.80(T°C)+32 Fahrenheit -> Celsius T°C= T°F – 32 1.80 23 Temperature Conversions Convert the following: 1. 145 °C = K 2. 373 K = °C 3. 25 °C = K 24 5.8 Density Objective: To define density and its units. Density: the amount of matter present in a given volume of substance or is mass per unit volume. In mathematical terms this means: Density = mass volume 25 Density What type of units would you use for density? Mass => ? Units Volume => ? Units Mass = grams (g) Volume = milliliters (ml) = cubic cm = cm3/cc So density units = g/ml or g/cm3 26 Density So what does the term density really mean? If something is very dense...what does that mean? What if something is not very dense? You know how to calculate density, but how would you measure density? What type of instruments would you need? 27