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K.J. INSTITUTE OF ENGG. & TECH. BRANCH= MECHANICAL(A) SEM=3 SUBJECT:- ENGINEERING THERMODYNAMICS Concept of Energy energy, in physics, the capacity for doing work. It may exist in potential, kinetic, thermal, electrical, chemical, nuclear, or other various forms. There are, moreover, heat and work—i.e., energy in the process of transfer from one body to another. After it has been transferred, energy is always designated according to its nature. Hence, heat transferred may become thermal energy, while work done may manifest itself in the form of mechanical energy. Concept of Energy Energy can be converted from one form to another in various ways. Usable mechanical or electrical energy is, for instance, produced by many kinds of devices, including fuel-burning heat engines, generators, batteries, fuel cells, and magnetohydrodynamic systems. The SI unit of energy is the joule (J) or newton-meter (N * m). The joule is also the SI unit of work APPLICATION of Energy Texas Industrial Energy Efficiency: Fifty-three percent of the energy used in Texas is consumed by the industrial sector. Water Energy Uses in California: Water use in California consumes significant amounts of electrical energy. Preliminary estimates indicate that total energy used to pump and treat this water exceeds 15,000 GWh per year, or at least 6.5 percent of the total electricity used in the State per year. APPLICATION of Energy This energy use is expected to increase due to a growing population, increasing reuse of wastewater, the remoteness or lower quality of alternative water sources, and increasingly stringent treatment requirements due to a variety of water quality and environmental protection concerns. Natural Gas: Natural gas is the second most used energy source in industry, trailing only electricity. APPLICATION of Energy Solar Energy and its Uses: Solar Energy information, news and facts. Freesolaronline gives user a step by step guide for Solar Energy Education and it's free uses as a permanent. How the Body Uses Its Food Energy: The human body is incredibly complex. Every second, millions of physiological and chemical reactions take place in order to maintain good health. APPLICATION of Energy The body both creates things (eg. heat, muscle, proteins, RNA, hair, nails, enzymes, fat tissue, bones) and breaks things down (food, stored fat, etc.). These anabolic and catabolic processes, along with all organs and systems, need fuel to enable them to function. The fuel or energy that the body uses, comes from the food and drink that we consume in our diet. In a nutshell, food is human gasoline. APPLICATION of Energy Industrial activity is also more common place in the North which uses more energy than the agriculture which takes place in the South. However the underlying disparity is the difference in the standards of livings between the two areas, with most of the North making do with cars, televisions etc… and those in the South having to make do without. Concept of Entropy Entropy is the quantitative measure of disorder in a system. The concept comes out of thermodynamics, which deals with the transfer of heat energy within a system. Instead of talking about some form of "absolute entropy," physicists generally talk about the change in entropy that takes place in a specific thermodynamic process. Concept of Entropy Calculating Entropy :- In an isothermal process, the change in entropy (delta-S) is the change in heat (Q) divided by the absolute temperature (T): delta- S = Q/ T In any reversible thermodynamic process, it can be represented in calculus as the integral from a processes initial state to final state of dQ / T . The SI units of entropy are J/K (joules/degrees Kelvin). Concept of Entropy Entropy & The Second Law of Thermodynamics :One way of stating the second law of thermodynamics is: In any closed system, the entropy of the system will either remain constant or increase. One way to view this is that adding heat to a system causes the molecules and atoms to speed up. It may be possible (though tricky) to reverse the process in a closed system (i.e. without drawing any energy from or releasing energy somewhere else) to reach the initial state, but you can never get the entire system "less energetic" than it started ... the energy just doesn't have anyplace to go. APPLICATION of Entropy The entropy of a system depends on its internal energy and the external parameters, such as the volume. In the thermodynamic limit this fact leads to an equation relating the change in the internal energy to changes in the entropy and the external parameters. This relation is known as the fundamental thermodynamic relation. If the volume is the only external parameter, this relation is:- APPLICATION of Entropy Since the internal energy is fixed when one specifies the entropy and the volume, this relation is valid even if the change from one state of thermal equilibrium to another with infinitesimally larger entropy and volume happens in a non-quasistatic way (so during this change the system may be very far out of thermal equilibrium and then the entropy, pressure and temperature may not exist). The fundamental thermodynamic relation implies many thermodynamic identities that are valid in general, independent of the microscopic details of the system. Important examples are the Maxwell relations and the relations between heat capacities. Concept of Exergy In thermodynamics, the exergy of a system is the maximum useful work possible during a process that brings the system into equilibrium with a heat reservoir. When the surroundings are the reservoir, exergy is the potential of a system to cause a change as it achieves equilibrium with its environment. Exergy is the energy that is available to be used. After the system and surroundings reach equilibrium, the exergy is zero. Determining exergy was also the first goal of thermodynamics. Concept of Exergy The term "exergy" was coined in 1956 by Zoran Rant (1904–1972) by using the Greek ex and ergon meaning "from work", but the concept was developed by J. Willard Gibbs in 1873. The destroyed exergy has been called anergy. For an isothermal process, exergy and energy are interchangeable terms, and there is no anergy. Application of Exergy Application of exergy to unit operations in chemical plants was partially responsible for the huge growth of the chemical industry during the 20th century. During this time it was usually called availability or available work. As a simple example of exergy, air at atmospheric conditions of temperature, pressure, and composition contains energy but no exergy when it is chosen as the thermodynamic reference state known as ambient. Application of Exergy Individual processes on Earth like combustion in a power plant often eventually result in products that are incorporated into a large atmosphere, so defining this reference state for exergy is useful even though the atmosphere itself is not at equilibrium and is full of long and short term variations. In recent decades, utilization of exergy has spread outside of physics and engineering to the fields of industrial ecology, ecological economics, systems ecology, and energetics. Defining where one field ends and the next begins is a matter of semantics, but applications of exergy can be placed into rigid categories. Application of Exergy EXERGY develop, design and manufacture the most efficient Organic Rankine Cycle (ORC) biomass plants, using the innovative and pioneering Radial Outflow Turbine (ROT). Industrial Process Heat Recovery is an area ideally suited to the Organic Rankine Cycle (ORC). As opposed to steam heat recovery systems, ORC can give better efficiency for lower temperature applications, as well as eliminating the requirement for water treatment and make up.EXERGY use the innovative and pioneering Radial Outflow Turbine (ROT) technology in the development of our heat recovery plants. Application of Exergy The Organic Rankine Cycle (ORC) is ideally suited for exhaust heat recovery from both engines and small gas turbines. As opposed to steam heat recovery systems, ORC can give better efficiency for modern low temperature engines, as well as eliminating the requirement for water treatment and make up. EXERGY use the innovative and pioneering Radial Outflow Turbine (ROT) technology in the development of our heat recovery plants.