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DANYLO HALYTSKY LVIV NATIONAL MEDICAL UNIVERSITY DEPARTMENT of GENERAL, BIOINORGANIC, PHYSICAL and COLLOIDAL CHEMISTRY V.V. Ogurtsov, O.M. Roman, O.V. Klenina MULTIPLY CHOICE QUESTIONS ON INORGANIC CHEMISTRY (Module 2. Inorganic Chemistry) For the 1st year students оf pharmaceutical faculty L’VIV – 2012 Chapter 1. General characteristic of s-elements. Hydrogen and its compounds 1.1. Solutions of alkalis react with the following simple matters: А. Zn, Cu, Mn B. C O2, P C. Cl2, S N2 D. Cl2, P, Zn E. Si, Al, Cu 1.2. Hydrogen peroxide can take part in all listed reactions, the exception is only: А. to be as a oxidizing agent B. production of hydrogen C. production of oxygen D. E. to be as a reducing agent 1.3. Presence of what salts predefines temporal hardness in water? А. CaCO3 and MgCO3 B. Mg(HCO3)2 and Ca(HCO3)2 C. KHCO3 and NaHCO3 D. Na2SO4 and CaSO4 E. KHCO3 and Ca(HCO3)2 1.4. Which of the listed salts can predefine permanent hardness of water? А. Mg(HCO3)2 B. Na2SO4 C. NaCl D. Ca(HCO3)2 E. K2SO4 1.5. Which one of the given elements forms peroxide at the reaction with oxygen? А. potassium B. sodium and potassium C. all alkaline metals D. sodium E. lithium 1.6. From elements of the IIA group amphoteric property has: А. calcium B. beryllium C. magnesium D. all elements of IIA group E. beryllium and magnesium 1.7. As a result of hydrolysis of magnesium silicide such products of reaction forms: А. complex compound B. silane and magnesium hydroxide C. silicium oxide, magnesium oxide and hydrogen D. silicon, magnesium oxide and hydrogen E. silane and magnesium oxide 1.8. Between the molecules of water there are the following types of connections: А. ionic B. covalent C. hydrogenic D. metallic E. covalent and ionic 1.9. Sodium hydrogen carbonate is used as: А. cholagogue B. laxative C. diuretic D. sedative E. antacidic 1.10. Sodium iodide is used in medicine as: А. diuretic B. antacidic C. source to the microelement of iodine D. sedative E. 1.11. Which one of the given carbonates is stable at the heating? А. magnesium carbonate B. copper carbonate C. silver carbonate D. calcium carbonate E. sodium carbonate 1.12. Which of the listed salts can predefine permanent hardness of water? А. MgCl2 B. Mg(HCO3)2 C. KCl D. Na3PO4 E. Ca(HCO3)2 1.13. Which of the given compounds can be used for softening of water? А. CaCO3, Ca(OH)2 B. MgSO4, H2SO4 C. Na3PO4, CaCl2 D. Na2CO3, NaCl E. Na2CO3, NAOH 1.14. Natural water always contains dissolved salts. Which of the listed salts can predefine temporal hardness of water? А. Mg(HCO3)2 B. CaÑl2 C. NaCl D. MgCl2 E. Ca3(PO4)2 1.15. Which from the given reactions is used for laboratory preparation of hydrogen? А. Fe + H2O → Fe3O4 + H2 B. CH4 + 2H2O → CO2 + 4H2 C. Zn + 2HCl → ZnCl2 + H2 D. CH4 → C + 2H2 E. C + H2O → CO + H2 1.16. The ions of what chemical element influence on electrolyte balance of brain and what salt of this element is used for treatment of psychical diseases: А. Mg, MgSO4 B. I, KI C. Cl, NaCl D. Li, Li2CO3 E. Ca, CaCl2 1.17. Salts of this alkaline metal are used in psychiatry. Burning on air or in the atmosphere of oxygen it forms the oxide E2O. What metal is the question about? А. Na B. Rb C. Li D. Cs E. K 1.18. What is the type of connection in the molecule of NaCl? А. covalently arctic B. Ionic C. metallic D. covalently unpolar E. hydrogenic 1.19. The reaction is between sodium and water: А. exothermic, connection B. endotermic C. exothermic, substitution D. exothermic, exchange E. endothermic, substitution 1.20. Sodium hydrogen carbonate reacts with hydrochloric acid with forming a gas of: А. B. C. D. E. CH4 CO2 H2 Cl2 CO 1.21. Which one from the given formulas corresponds to sodium thiosulphate? А. Na2S2O4 B. NaHSO4 C. Na2S2O5 D. Na2S2O3 E. Na2SO3 1.22. At heating oxygen reacts only as exception with: А. Cl2 B. Ne C. N2 D. Au E. Cu 1.23. Temporal hardness of water is predefined by a presence in water of next salts of calcium and magnesium А. chlorides B. sulfides C. sulfates D. nitrates E. hydrogen carbonates 1.24. Which of the listed chemical reactions can be used for the preparation of hydrogen? А. Zn + HNO3 B. Zn + NAOH C. Fe + KOH D. Mg + HNO3 E. Cu + H2SO4 1.25. Whish one of the given methods can be used foe preparation of metallic sodium? А. - B. hydrometallurgy C. electrolysis of fusions of salts D. aluminothermy E. electrolysis of solutions of salts 1.26. Chouse the formula which is named lime: А. Ca(OH)2 B. CaO2 C. CaCO3 D. CaCl2 E. CaO 1.27. Which one from the simple matters reacts with water at the room temperature? А. Copper B. Nitrogen C. Chlorine D. Silicon E. Gold 1.28. Which element reacts with oxygen to produce peroxide? А. Al B. Na C. Cu D. Fe E. K 1.29. NaNO2 shows reducing properties in relation with: А. NH3 B. KMnO4 C. H2S D. NaHCO3 E. KI 1.30. What element most widely distributed on the earth? А. Silicon B. Oxygen C. Nitrogen D. Carbon E. Hydrogen 1.31. Which of the given elements corresponds to s–elements? А. P, S, Cr B. Be, Mg, Al C. S, P, Cl D. Mn, Br, Mo E. K, Ca, Sc 1.32. Which compounds react to give as a product only Fe(OH)3? А. FeO and H2O B. Fe(OH)2 and H2O2 C. Fe and H2O D. Fe2O3 and H2O E. Fe and O2 1.33. Which one of the given reactants is used for identification of Ca2+ cation? А. (NH4)2C2O4 B. HNO3 C. KCl D. HCl E. NaBr 1.34. Which one from the resulted reactions is used in submarine boats for the regeneration of air? А. 2Na2O2 + 2CO2 = 2Na2CO3 + O2 B. 2KClO3 = 2KCl + 3O2 C. 2NaNO3 = 2NaNO2 + O2 D. 2H2O2 = 2H2O + O2 E. 2KMnO4 = K2MnO4 + MnO2 + O2 1.35. Hydrogen in the periodic system of elements disposes in: А. VIIB and IA groups B. IIA group C. IB group D. IA and VIIA groups E. VIIA group 1.36. Hydrogen in compounds shows the following oxidation numbers: А. 0, +1, +2 B. +1 C. -1, 0, +1 D. 0, -1 E. +1, +2 1.37. Which one of the listed reaction is possible at the room temperature? А. Au + HCl → B. Na + H2O → C. Cr2O3 + H2 → D. Cu + H2O → E. Fe + H2SO4 (conc.) → 1.38. Which one from the given salts does not hydrolyze: А. KNO2 B. CrCl3 C. Al2(SO4)3 D. ZnSO4 E. KI 1.39. In solution [OH–] = 1•10–6 mol/L. What is the pH of solution?. А. 8 B. 1 C. 4 D. 7 E. 6 Chapter 2. s-Elements of the І group of the Periodic Table. Alkali metals 2.1. What is the electronic configuration of Lithium atom? А. 1s22s1 B. 1s22s22p63s23p64s1 C. 1s22s22p63s1 D. 1s12s1 E. 1s22s2 2.2. Electronic formula of Sodium atom. А. 1s22s1 B. 1s22s22p63s1 C. 1s22s22p63s23p64s1 D. 1s22s22p63s23p64s2 E. 1s22s22p63s2 2.3. Electronic formula of Potassium atom. А. 4s1 B. 1s22s22p63s23p64s23d105s1 C. 1s22s22p62d103s1 D. 1s22s22p63s1 E. 1s22s22p63s23p64s1 2.4. Electronic formula of Rubidium atom. А. 1s22s22p63s1 B. 1s22s22p62d103s1 C. 1s22s1 D. 5s1 E. 1s22s22p63s23p64s23d104p65s1 2.5. Electronic configuration of external level of Cesium atom : А. 6s1 B. 6s2 C. 1s22s1 D. 6s1 E. 1s22s22p63s23p64s23d105s1 2.6. Electronic formula of Lithium cation: А. 1s12s1 B. 1s22s22p63s1 C. 1s22s2 D. 1s2 E. 1s1 2.7. Electronic formula of Sodium cation: А. 4s1 B. 1s22s22p5 C. 1s22s22p63s1 D. 1s22s1 E. 1s22s22p6 2.8. Electronic formula of Potassium cation: А. 3s23p64s1 B. 5s1 C. 1s22s22p63s23p64s1 D. 1s22s22p63s23p6 E. 3s23p6 2.9. Electronic formula of Rubidium cation: А. 1s22s22p63s23p64s23d10 B. 4s23d104p6 C. 5s1 D. 1s22s22p63s23p64s23d105s1 E. 1s22s22p63s23p64s23d104p6 2.10. By a Lithium to Cesium atomic radii of elements: А. decreases B. increased to Potassium, and then decreases C. does not change D. increases E. decreases to Potassium, and then increased 2.11. By a Lithium to Cesium ion radii of the elements E +: А. does not change B. decreases to Potassium, and then increased C. increased to Potassium, and then decreases D. decreases E. increases 2.12. By a Lithium to Cesium atom ionization energy: А. decreases to Sodium, and then increased B. decreases C. increases D. increased to Sodium, and then decreases E. does not change 2.13. Value of standard electrode potential from Lithium to Cesium: А. decreases to Sodium, and then increased B. increased to Sodium, and then decreases C. increased D. does not change E. decreases 2.14. The most negative value of standard electrode potential has: А. Lithium B. Potassium C. Sodium D. Rubidium E. Cesium 2.15. Among alkaline metals more active is: А. Rubidium B. Potassium C. Cesium D. Lithium E. Sodium 2.16. Lithium with properties similar to: А. Calcium B. Sodium C. Beryllium D. Potassium E. Magnesium 2.17. Chemical formula of halite. А. LiAlPO4F B. NaCl C. Na2SO4·10H2O D. KCl·MgCl2·6H2O E. NaCl·KCl 2.18. Chemical formula of sylvinite. А. NaCl B. Na2SO4·10H2O C. LiAlPO4F D. NaCl·KCl E. KCl·MgCl2·6H2O 2.19. Chemical formula to carnallite. А. LiAlPO4F B. NaCl·KCl C. Na2SO4·10H2O D. NaCl E. KCl·MgCl2·6H2O 2.20. Chemical formula of ambligonite. А. NaCl·KCl B. NaCl C. Na2SO4·10H2O D. KCl·MgCl2·6H2O E. LiAlPO4F 2.21. Chemical formula Glauber salt: А. NaCl B. KCl·MgCl2·6H2O C. LiAlPO4F D. NaCl·KCl E. Na2SO4·10H2O 2.22. To the macroelements belong: А. Sodium and Lithium B. Lithium and Potassium C. Sodium and Rubidium D. Sodium and Potassium E. Cesium and Lithium 2.23. Which of the listed methods are used for preparation of metallic sodium? А. method of hydrometallurgy B. method of carbothermy C. method of aluminothermy D. electrolysis of fusions of salts E. electrolysis of solutions of salts 2.24. Which of the listed methods are used for preparation of metallic lithium? А. electrolysis of fusions of salts B. electrolysis of solutions of salts C. method of hydrometallurgy D. method of aluminothermy E. method of carbothermy 2.25. Which of the alkaline metals can be obtained by the following reaction? MeCl + Na → Me + NaCl А. rubidium and lithium B. potassium and rubidium C. lithium and францій D. potassium and lithium E. lithium and cesium 2.26. With the direct interaction with oxygen peroxide forms: А. rubidium B. sodium and potassium C. sodium D. potassium E. lithium 2.27. With the direct interaction with oxygen oxide forms: А. sodium and potassium B. lithium C. potassium D. cesium E. sodium 2.28. With the direct interaction with oxygen supperoxide forms: А. sodium and potassium B. sodium and lithium C. potassium and rubidium D. sodium and rubidium E. cesium and lithium 2.29. Under normal conditions, nitrogen reacts with: А. potassium B. sodium C. lithium D. cesium E. sodium and potassium 2.30. The oxidation number of hydrogen in hydrides of alkali metals is: А. +2 B. -2 C. +1 D. –1 E. 0 2.31. The oxidation number of Oxygen in the alkali metal peroxides is: А. 0 B. –2 C. +1 D. –½ E. –1 2.32. The oxidation number of Oxygen in the alkali metal supperoxides is: А. 0 B. –1 C. –2 D. –½ E. +1 2.33. What type of chemical bonds present in the hydrides of alkali metals? А. B. nonpolar covalent C. polar covalent D. ionic E. metallic 2.34. What alkaline metal, burning on air or in the atmosphere of oxygen forms the oxide of E2O? А. K B. Rb C. Na D. Li E. Cs 2.35. When dissolved in water alkaline oxide is formed: А. alkalis and water B. alkalis and hydrogen C. alkalis D. alkalis and oxygen E. hydride of metal and oxygen 2.36. When dissolved in water alkaline peroxide is formed: А. hydride of metal and oxygen B. alkalis C. alkalis and water D. alkalis and hydrogen E. alkalis and oxygen 2.37. When dissolved in water alkaline superoxide is formed: А. alkalis and oxygen B. alkalis and water C. alkalis D. hydride of metal and oxygen E. alkalis and hydrogen 2.38. Which of the alkali metal hydroxide has the worst solubility in water? А. sodium B. cesium C. lithium D. rubidium E. potassium 2.39. Which one of the given reactants is used for identification of the ion of K+. А. NaH2SbO4 B. NaHC4H4O6 C. Na2S D. Na2CO3 E. (NH4)2C2O4 2.40. Which one of the given reactants is used for identification of the ion Na+. А. H2S B. NH4SCN C. KH2SbO4 D. NH4Cl E. NaH2PO4 2.41. Chemical formula of soda is: А. K2CO3 B. Na2CO3 C. Na2CO3·10H2O D. NaHCO3 E. NaOH 2.42. Chemical formula of drinking (baking) soda is: А. Na2CO3·10H2O B. NaOH C. K2CO3 D. NaHCO3 E. Na2CO3 2.43. Chemical formula of crystalline soda is: А. NaOH B. NaHCO3 C. Na2CO3 D. Na2CO3·10H2O E. K2CO3 2.44. Chemical formula of potassium carbonate is: А. Na2CO3·10H2O B. NaHCO3 C. K2CO3 D. Na2CO3 E. NaOH 2.49. Solutions of alkalis react with the following simple matters: А. C O2, P B. Cl2, S N2 C. Zn, Cu, Mn D. Cl2, P, Zn E. Si, Al, Cu 2.45. Which of the following reactions are used in submarines for air regeneration? А. 2Na2O2 + 2CO2 = 2Na2CO3 + O2 B. 2KMnO4 = K2MnO4 + MnO2 + O2 C. 2NaNO3 = 2NaNO2 + O2 D. 2H2O2 = 2H2O + O2 E. 2KClO3 = 2KCl + 3O2 2.50. Sodium iodide is used in medicine as: А. B. diuretic C. sedative D. antacidic E. source to the microelement of iodine 2.46. Chemical formula of caustic soda is: А. K2CO3 B. NaOH C. Na2CO3 D. NaHCO3 E. Na2CO3·10H2O 2.47. Sodium hydrogen carbonate is used as: А. sedative B. antacidic C. diuretic D. cholagogue E. laxative 2.48. The ions of what chemical element influence on electrolyte balance of brain and what salt of this element is used for treatment of psychical diseases: А. I, KI B. Rb, RbCl2 C. Li, LiCl D. Li, Li2CO3 E. Cl, NaCl 2.51. Mass percentage of sodium chloride in hypertonic solution is: А. 0,9 % B. 0,18 % C. 5 % D. 1 % E. 0,09 % 2.52. Which of the given compounds can be used for softening of water? А. CaCO3, Ca(OH)2 B. MgSO4, H2SO4 C. Na3PO4, CaCl2 D. Na2CO3, NaOH E. Na2CO3, NaCl 2.53. What is the type of bonds in the molecule of NaCl? А. polar covalent B. ionic C. nonpolar covalent D. metallic E. hydrogenic 2.54. The reaction is between sodium and water: А. endothermic, substitution B. exothermic, substitution C. endothermic D. exothermic, connection E. exothermic, exchange 2.55. Which one from the given formulas corresponds to sodium thiosulphate? А. Na2S2O4 B. NaHSO4 C. Na2SO3 D. Na2S2O3 E. Na2S2O5 2.56. Which of the given elements corresponds to s-elements? А. Mn, Br, Mo B. P, S, Cr C. K, Ca, Cs D. S, P, Cl E. Be, Mg, Al 2.57. Which one of the listed reaction is possible at the room temperature? А. Au + HCl → B. Cr2O3 + H2 → C. Fe + H2SO4 (conc.) → D. Na + H2O → E. Cu + H2O → 2.58. Which one from the given salts does not hydrolyze: А. ZnSO4 B. KI C. Al2(SO4)3 D. KNO2 E. CrCl3 2.59. The concentration of [OH–] = 1•10–6 mol/L. What is the pH of this solution? А. 8 B. 6 C. 7 D. 1 E. 4 Chapter 3. s-Elements of the ІІ groups of the Periodic Table. Beryllium, Magnesium, and Alkaline earth metals 3.1. What is the electronic configuration of Beryllium atom А. 1s12s1 B. 1s22s2 C. 1s22s22p63s1 D. 1s22s0 E. 1s22s22p63s23p64s1 3.2. Electronic formula of Magnesium atom. А. 1s22s22p63s23p64s2 B. 1s22s22p63s2 C. 1s22s22p63s1 D. 1s22s22p63s23p64s2 E. 1s22s2 3.3. Electronic formula of Calcium atom. А. 4s1 B. 1s22s22p63s23p64s2 C. 1s22s22p63s23p64s23d105s1 D. 1s22s22p63s1 E. 1s22s22p62d103s1 3.4. Electronic formula of Strontium atom. А. 1s22s22p63s23p64s23d104p65s2 B. 1s22s22p63s2 C. 1s22s1 D. 5s1 E. 1s22s22p62d103s1 3.5. Electronic configuration of external level of Barium atom. А. 1s22s22p63s23p64s23d105s1 B. 1s22s1 C. 6s1 D. 6s1 E. 6s2 3.6. Electronic formula of Beryllium cation. А. 1s12s1 B. 1s22s22p63s1 C. 1s22s2 D. 1s1 E. 1s2 3.7. Electronic formula of Magnesium cation. А. 1s22s22p63s1 B. 1s22s22p6 C. 4s1 D. 1s22s22p5 E. 1s22s1 3.8. Electronic formula of Calcium cation. А. 5s1 B. 3s23p6 C. 1s22s22p63s23p64s1 D. 1s22s22p63s23p6 E. 3s23p64s1 3.9. Electronic formula of Strontium cation. А. 1s22s22p63s23p64s23d10 B. 4s23d104p6 C. 5s1 D. 1s22s22p63s23p64s23d104p6 E. 1s22s22p63s23p64s23d105s1 3.10. Atomic radius from Beryllium to Barium of elements: А. increases B. decreases to Calcium, and then increases C. increases to Calcium, and then decreases D. does not change E. decreases 3.11. Ionic radius of ions from Beryllium to Barium of E2+ of elements: А. decreases B. decreases to Calcium, and then increases C. does not change D. increases to Calcium, and then decreases E. increases 3.12. Ionization energy From Beryllium to Barium atom: А. decreases to Calcium, and then increases B. decreases C. increases to Calcium, and then decreases D. does not change E. increases 3.13. Metallic properties from Beryllium to Barium: А. does not change B. increases C. decreases to Calcium, and then increases D. decreases E. increases to Calcium, and then decreases 3.14. Value of standard electrode potential from Beryllium to Radium: А. decreases B. increases C. does not change D. increases to Calcium, and then decreases E. decreases to Calcium, and then increases 3.15. The most negative value of standard electrode potential has: А. Barium B. Magnesium C. Strontium D. Beryllium E. Calcium 3.16. Among the metals of IIA group radioactive is: А. Calcium B. Beryllium C. Strontium D. Radium E. Magnesium 3.17. Magnesium with its properties reminds alkali metal: А. Lithium B. Potassium C. Rubidium D. Sodium E. Cesium 3.18. Beryllium with its properties similar to: А. sodium B. boron C. lithium D. potassium E. aluminum 3.19. Alkaline earth metals are: А. Ba, Sr, Ra B. Mg, Sr, Ra C. Be, Sr, Mg D. Ca, Sr, Ba E. Be, Ra, Mg 3.20. Which one of the listed elements of IIA group shows amphotheric property: А. Magnesium B. all elements of IIA group C. Calcium D. Beryllium and Magnesium E. Beryllium 3.21. Chemical formula of magnesite; А. MgSO4·10H2O B. MgCO3·СaCO3 C. KCl·MgCl2·6H2O D. MgCl2·KCl E. MgCO3 3.22. Chemical formula of dolomite: А. MgSO4·10H2O B. MgCO3·СaCO3 C. MgCl2·CaCl2 D. KCl·MgCl2·6H2O E. Mg3(PO4)2 3.23. Chemical formula of chalk; А. СaCO3 B. MgCO3 C. Mg3(PO4)2 D. CaCl2 E. СаSO4 3.24. Chemical formula of anhydrite: А. СaCO3 B. CaCl2 C. MgCO3 D. СаSO4 E. Mg3(PO4)2 3.25. Chemical formula of limestone: А. СaO B. СaCO3 C. Ca(OH)2 D. CaCl2 E. СаSO4 3.26. Chemical formula of calcite; А. СaCO3 B. Ca(OH)2 C. СaO D. CaCl2 E. СаSO4 3.27. Chemical formula of celestite; А. SrSO4 B. SrCO3 C. CaSO4 D. СaCO3 E. KCl·MgCl2·6H2O 3.28. Chemical formula of gypsum: А. KCl·MgCl2·6H2O B. СaCO3 C. СаSO4·2Н2О D. SrCO3 E. CaSO4 3.29. Chemical formula of fluorite: А. KF·MgF2·6H2O B. CaSO4 C. CaF2 D. SrF2 E. СaCO3 3.30. Chemical formula of barite: А. ВаSO4 B. ВаCl2 C. СaCO3 D. SrSO4 E. ВaCO3 3.31. Chemical formula of lime: А. Ca(OH)2 B. CaO C. CaCl2 D. CaO2 E. CaCO3 3.32. Which of the listed methods are used for preparation of metallic beryllium? А. hydrometallurgy B. aluminothermy C. electrolysis of fusions of salts D. electrolysis of solutions of salts E. carbothermy 3.33. Which of the listed methods are used for preparation of metallic magnesium? А. method of carbothermy B. electrolysis of solutions of salts C. method of aluminothermy D. electrolysis of fusions of salts E. method of hydrometallurgy 3.34. At the reaction with oxygen elements of IIA group form the oxides of the following composition: А. МеО and Ме2О B. Me2O C. MeO D. Ме2О3 E. Ме3О4 3.35. What metal of IIA group at reaction with oxygen can form peroxide? А. beryllium B. calcium C. barium D. magnesium E. strontium 3.36. What metal of IIA of group does not react with hydrogen? А. calcium B. beryllium C. magnesium D. strontium E. barium 3.37. What metal of IIA of group does not react with water? А. magnesium B. beryllium C. strontium D. calcium E. barium 3.38. Basic properties of hydroxides from Be(ОН)2 to Ba(ОН)2: А. decreases to Magnesium, and then increases B. increases to Magnesium, and then decreases C. does not change D. increases E. decreases 3.39. Under ordinary conditions with water does not react: А. magnesium B. calcium C. barium D. strontium E. radium 3.40. The concentrated sulfuric acid passive: А. strontium B. magnesium C. beryllium D. barium E. calcium 3.41. The concentrated passive: А. calcium B. beryllium C. barium D. strontium E. magnesium nitric acid 3.42. What is the pH of water solution of calcium sulfide? А. basic B. weak basic C. acidic D. neutral E. strongly acidic 3.43. What reagent is used for the identification of Ca2+ ion? А. HNO3 B. H2S C. NH4SCN D. HCl E. (NH4)2C2O4 3.44. What reagent is used for the identification of Mg2+ ion? А. HCl B. H2S C. NaH2PO4 D. NaHC4H4O6 E. KH2SbO4 3.45. What reagent is used for the identification of Ba2+ ion? А. НI B. Н2C2O4 C. Н2SO4 D. НNO3 E. НCl 3.46. What reagent is used for the identification of Sr2+ ion? А. HCl B. K2CrO4 C. NaHC4H4O6 D. H2S E. (NH4)2C2O4 3.47. Do the ions of Ca2+ paint the flame in what color? А. reddish-orange B. green C. violet D. yellow E. greenish-yellow 3.48. Do the ions of Ba2+ paint the flame in what color? А. violet B. yellow green C. yellow D. reddish-orange E. red 3.49. Do the ions of Sr 2+ paint the flame in what color? А. reddish-orange B. carmine-red C. yellow D. greenish-yellow E. violet 3.50. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Sr + H2 → the sum of the coefficient in the equation. Ca + P → А. 7 B. 4 C. 8 D. 6 E. 5 3.54. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Mg + F2→ А. 6 B. 4 C. 8 D. 5 E. 3 3.51. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Be + C → А. 7 B. 5 C. 4 D. 6 E. 8 А. 6 B. 4 C. 3 D. 8 E. 5 3.55. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Mg + S→ 3.52. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Mg + N2 → А. 7 B. 8 C. 9 D. 5 E. 6 3.53. Complete and balance the equation of the reaction. Point out А. 8 B. 5 C. 3 D. 4 E. 6 3.56. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Ca + C → А. 8 B. 4 C. 7 D. 5 E. 6 3.57. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Ca + H2O → А. 6 B. 7 C. 4 D. 8 E. 5 Mg + NH4Cl (conc.) → 3.58. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Mg + HCl (dil) → А. 5 B. 8 C. 4 D. 7 E. 6 А. 8 B. 6 C. 9 D. 4 E. 5 3.62. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Be + HF (conc.) → 3.59. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Be + HCl (dil) → А. 6 B. 4 C. 7 D. 8 E. 5 А. 7 B. 6 C. 4 D. 8 E. 5 3.63. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. BeО + HNO3 (conc.) → 3.60. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Be + NaOH (conc.) → А. 5 B. 7 C. 8 D. 4 E. 6 3.61. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. А. 6 B. 8 C. 7 D. 4 E. 5 3.64. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Be(ОН)2 +HNO3 (conc.) → А. 7 B. 6 C. 5 D. 4 E. 8 3.65. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Ca(ОН)2 +HNO3 (conc.) → А. 7 B. 6 C. 4 D. 8 E. 9 3.66. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. CaO + HNO3 (conc.) → А. 7 B. 8 C. 5 D. 4 E. 6 3.67. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. CaCO3 + HNO3 (conc.) → А. 8 B. 7 C. 5 D. 4 E. 6 3.68. Complete and balance the equation of the reaction. Point out the sum of the coefficient in the equation. Mg(ОН)2 + HNO3 (conc.) → А. 5 B. 4 C. 6 D. 8 E. 7 3.69. The presence of which salts in water predefines temporal hardness of water? А. CaCO3 and MgCO3 B. Mg(HCO3)2 and Ca(HCO3)2 C. KHCO3 and NaHCO3 D. Na2SO4 and CaSO4 E. KHCO3 and Ca(HCO3)2 3.70. The presence of what salts in water predefines permanent hardness of water? А. СаSO4 B. Ca(HCO3)2 C. Mg(HCO3)2 D. K2SO4 E. NaCl 3.71. The presence of which salts in water predefines permanent hardness of water? А. Mg(HCO3)2 B. Na3PO4 C. KCl D. Ca(HCO3)2 E. MgCl2 3.72. The presence of which salts in water predefines temporal hardness of water? А. MgCl2 B. NaCl C. Ca3(PO4)2 D. Mg(HCO3)2 E. CaСl2 3.73. Temporary hardness is caused by the presence in water alcium and magnesium: А. chlorides B. sulfides C. nitrates D. hydrogencarbonates E. sulfates 3.74. To the macroelements belongs biotmetals: А. Barium and Magnesium B. Barium and Radium C. Beryllium and Magnesium D. Calcium and Magnesium E. Strontium and Radium 3.75. Which one of the given salts is used for the X-ray examination of the gastrointestinal tract? А. calcium chloride B. strontium sulfate C. magnesium sulfate D. barium sulfate E. magnesium oxide 3.76. Choose the formula of Epson salt which has sedative, spasmolytic and laxative effect. А. MgSO4·7H2O B. (MgOH)2CO3 C. CaSO4·2H2O D. Na2CO3·10H2O E. CaSO4·0,5H2O 3.77. Chemical formula of medical hypsus: А. CaSO4·3H2O B. CaSO4·2H2O C. CaSO4·5H2O D. CaSO4·H2O E. CaSO4·0,5H2O 3.78. The radio-nuclidess of what element adsorbed by the body and causes damage of blood-forming organs and formation of cancer cells? А. beryllium B. barium C. calcium D. magnesium E. strontium 3.79. The high toxic action show compounds of: А. calcium B. – C. magnesium D. strontium E. beryllium 3.80. The high toxic action show soluble compounds of: А. barium B. calcium C. strontium D. magnesium E. – Chapter 4. General characteristic of p-Elements. Boron and Alluminium 4.1. Which of the given metals react with hydrochloric acid releasing hydrogen gas? А. Hg B. Au C. Cu D. Al E. Pt 4.2. Which of the given metals does not react with concentrated nitric acid? А. Al B. Hg C. Ag D. Na E. Cu 4.3. Which of the given metals react with sulfuric acid releasing hydrogen gas? А. Hg B. Pt C. Ag D. Al E. Cu 4.4. What is the рН of aluminum chloride AlCl3 solution? А. pH=7 B. pH=9 C. pH=8 D. pH<7 E. pH>7 4.5. What is the рН of aluminum nitrate solution Al(NO3)3? А. pH=8 B. pH=9 C. pH>7 D. pH=7 E. pH<7 4.6. What is the рН of aluminum sulfate solution Al2(SO4)3? А. pH=7 B. pH=9 C. pH>7 D. pH=8 E. pH<7 4.7. Concentrated nitric acid HNO3 will react with: А. Cu B. Fe C. Cr D. Au E. Al 4.8. Aluminum in the reactions with other compounds: А. gains 2 electrons B. gains 3 electrons C. loses 2 electrons D. loses 1 electron E. loses 3 electrons 4.9. Point out the sum of the coefficients in the equation between aluminum Al and sodium hydroxide solution NaOH: А. 18 B. 16 C. 20 D. 15 E. 17 4.10. Calculate a molar mass of gas which is evolved at the hydrolysis of aluminum Al2S3 sulfide: А. 64 B. 34 C. 32 D. 80 E. 2 4.11. What is the product of hydrolysis of aluminum chloride AlCl3 on the first stage: А. AlOHCl2 B. Al(OH)2Cl C. Al(OH)3 D. Al2O3 E. [Al(H2O)6]Cl3 4.12. What is the product of hydrolysis of aluminum nitrate Al(NO3)3 on the second stage: А. Al(OH)2NO3 B. [Al(H2O)6](NO3)3 C. Al2O3 D. AlOH(NO3)2 E. Al(OH)3 4.13. What is the product of hydrolysis of aluminum sulfate Al2(SO4)3 on the first stage: А. AlOHSO4 B. Al(HSO4)3 C. Al(OH)3 D. (Al(OH)2)SO4 E. Al2O3 4.14. Which of the given salts have the acidic medium? А. CaCO3, BaSO4 B. NaCl, KNO3 C. KCl, Na3PO4 D. CaCl2, Na2CO3 E. FeCl2, Al(NO3)3 4.15. Choose the true statement for aluminum hydroxide Al(OH)3? А. dissolves in water B. does not dissolve in in alkalis C. does not decompose at heating D. does not has oxidizingreduction properties E. does not dissolve in acids 4.16. Al2(SO4)3 does not form as a result of reaction between: А. Al + SO3 → B. Al + H2SO4 → C. Al2O3 + H2SO4 → D. Na3[Al(OH)6]+ H2SO4 → E. Al(OH)3 + H2SO4 → 4.17. What product forms under the reaction (precipitate) between aluminum chloride AlCl3 and sodium carbonate Na2CO3? А. B. Al(OH) C. Al2(CO3)3 D. Al2O3 E. NaAlO2 4.18. What product forms under the reaction (precipitate) between aluminum sulfate solution Al2(SO4)3 and ammonium sulfide (NH4)2S ? А. Al2O3 B. Al(OH)3 C. (NH4)2SO4 D. Al2S3 E. AlOHSO4 4.19. What product forms under the reaction (precipitate) between aluminum chloride AlCl3 solution and sodium sulfide Na2S? А. Al2S3 B. Al2O3 C. AlOHSO4 D. Al2(SO4)3 E. Al(OH)3 4.20. Which one of the listed elements has oxidation and reducing properties: А. Tl B. Al C. In D. Ga E. B 4.21. Which one of the listed oxides has acidic properties only? А. In2O3 B. Tl2O3 C. Al2O3 D. B2O3 E. Ga2O3 4.22. Which of the listed oxides has basic properties only? А. In2O3 B. Ga2O3 C. Al2O3 D. B2O3 E. Tl2O3 4.23. What mass of chlorine Cl2 will react with aluminum Al. Mass of aluminum equal 9 g? А. 1,42 B. 35,5 C. 0,355 D. 0,71 E. 71 4.24. Which of the listed compounds of boron is found in nature? А. B2O3 B. H3BO3 C. B2H6 D. Mg3B2 E. NaBO2 4.25. The oxide of boron has the properties: А. B. acidic C. basic D. Mixed E. amphoteric 4.26. The oxide of boron when dissolved in water forms: А. amphoteric hydroxide B. does not form acids or bases C. metaboric acid D. ortoboric acid E. tetraboric acid 4.27. In which compounds boron has the oxidation state –3? А. NaBO2 B. H3BO3 C. Mg3B2 D. Na2B4O7 E. B2O3 4.28. Which one of the given oxides does not dissolve in alkalis? А. In2O3 B. Al2O3 C. Tl2O3 D. B2O3 E. Ga2O3 4.29. Which one of the given hydroxides has the basic properties? А. Tl(OH)3 B. Al(OH)3 C. B(OH)3 D. In(OH)3 E. Ga(OH)3 4.30. Which one of the given hydroxides has the acidic properties? А. Al(OH)3 B. Ga(OH)3 C. B(OH)3 D. Tl(OH)3 E. In(OH)3 4.31. Which of the given hydroxides have the amphoteric properties? А. Tl(OH)3, Ba(OH)2 B. Ga(OH)3, In(OH)3 C. Mg(OH)2, Tl(OH)3 D. Fe(OH)2, B(OH)3 E. Ga(OH)3, B(OH)3 4.32. Which of the given oxides have the amphoteric properties? А. FeO, NO2 B. B2O3, BaO C. CaO, SO3 D. BeO, Al2O3 E. MgO, P2O3 4.33. What volume of hydrogen H2 (L) will be released at the reaction of aluminum Al by mass 9 г with the diluted sulfuric acid H2SO4? А. 5,6 B. 22,4 C. 67,2 D. 44,8 E. 11,2 4.34. What metals react with solutions of alkalis? А. Ca, Fe B. Cr, К C. Hg, Cd D. Mn, Na E. Zn, Al 4.35. Which of the listed hydroxides have amphoteric properties? А. LiOH, Sr(OH)2 B. Mg(OH)2, KOH C. Ca(OH)2, NaOH D. Al(OH)3, Cr(OH)3 E. Cr(OH)2, Fe(OH)2 4.36. Which of the listed compounds can not exist in the same solution simultaneously? А. AlCl3, Ca(NO3)2 B. NaCl, Al(NO3)3 C. Na2SO4, Al(NO3)3 D. Na2SO3, Al2(SO4)3 E. NaCl, AlCl3 4.37. What will be one of the products of the reaction between aluminium Al and concentrated sulfuric acid H2SO4? А. H2S B. SO2 C. SO3 D. S E. H2 4.38. Reducing properties of simple substances from B to Tl: А. B. decrease C. does not change D. decrease at first, then increase E. increase 4.39. What metals do not react with concentrated sulfuric acid H2SO4: А. Fe, Cr, Al B. Al, Zn, Be C. Fe, Cr, Zn D. Cr, Na, Mg E. Al, К, Mg 4.40. From the listed pair of hydroxides choose insoluble in water, but soluble in acids and alkalis: А. Ca(OH)2, Bi(OH)3 B. Mg(OH)2, Cu(OH)2 C. Al(OH)3, Zn(OH)2 D. Mg(OH)2, Sn(OH)2 E. Cr(OH)2, Fe(OH)2 4.41. Which of the listed electronic configurations corresponds to 13Al atom? А. [Ne] 3s03p0 B. [Ne] 3s23p1 C. [Ne] 3s23p3 D. [Ne] 3s23p4 E. [Ne] 3s13p0 4.42. Which of the listed electronic configurations corresponds to 5B atom? А. [He] 2s22p4 B. [He] 2s22p3 C. [He] 2s22p1 D. [He] 2s22p5 E. [He] 2s22p2 4.43. Which of the listed electronic configurations corresponds to Al3+ ion? А. [Ne] 3s23p1 B. [Ne] 3s03p0 C. [Ne] 3s13p0 D. [Ne] 3s23p4 E. [Ne] 3s23p3 Chapter 5. р-Elements of IVА Group. Carbon, Silicon 5.1. Which of the listed substances are not allotropes of carbon? А. diamond B. anthracite C. carbine D. graphite E. fullerene 5.2. Why properties of allotropes of carbon substantially differ between themselves? А. they have different values of Gibs’s free energy B. they consist of different isotopes of carbon C. they have different aggregate state D. they have different heats of formation E. they have different structure of crystalline grate 5.3. Which reagent is used for determination of СО in air? А. silver nitrate B. PdCl2 C. Nesler reagent D. – E. bromine water 5.4. Which crystalline grate is in the structure of diamond? А. ionic B. atomic C. molecular D. – E. metallic 5.5. What allotrope modification of carbon is the most hardness? А. fullerene B. carbine C. graphite D. diamond E. – 5.6. What is the activated charcoal? А. charcoal heating at the temperature 500-6000С B. charcoal cleaned by heating with steam C. brown coal cleaned by acid D. charcoal cleaned by mineral acid E. – 5.7. An activated charcoal has a high adsorbtivity, because it has: А. solubility in water B. high chemical activity of this compound C. low density D. low chemical activity of this compound E. a large surface area 5.8. Which of the listed electronic configurations corresponds to the р-elements of IVA groups? А. ns2np3 B. ns2np1 C. ns2np2 D. ns2np0 E. ns1np3 5.9. What oxidation states are the most typical for carbon and silicon? А. –2, –4 B. C. D. E. +2, –4 +2, +4 only +4 +4, –4 5.10. To what group of oxides carbon (ІІ) oxide CO belongs? А. B. basic C. acidic D. that cannot forms the salts E. amphoteric 5.11. For the obtaining of carbon (ІІ) oxide in laboratory is used such compounds: А. CH3OH, HCOOH B. CH3COOH, HCOOH C. СаСО3 MgCO3 D. НСООН, Н2С2О4 E. СаСО3⋅MgCO3, FeCO3 5.12. Carbonates are natural compounds of carbon. Which of the listed mineral does not belongs to this group? А. dolomite B. malachite C. carnelian D. magnesite E. shalk 5.13. Activated charcoal is used in medical practice at those cases: А. B. at poisonings and gastric diseases C. at an alkalosis (increasing of рН blood) D. at аcidosis (decreasing of рН blood) E. at the sepsis 5.14. What gas is formed as a result of reaction between CaC2 and water? А. acetylene B. ethylidene C. methanol D. ethane E. methane 5.15. What is the “dry ice”? А. carbonic acid in the hard state B. carbon (IV) oxide in the hard state C. saturated solution of СО2 in water D. carbon (ІІ) oxide in the hard state E. concentrated carbonic acid 5.16. Mixture of СО + Н2 is named: А. B. water gas C. coke gas D. generator gas E. smeech gas 5.17. What concentration of СО in air is mortal for a human? А. 0.25%. B. 0.5%. C. 0.05%. D. 0.01%. E. 0.2%. 5.18. What compounds are the main air pollutions? А. oxides of all non-metals B. oxides of sulfur and all halogens C. oxides of carbon, sulfur and nitrogen D. compounds of hydrogen with carbon, sulfur and nitrogen E. halogens 5.19. Which salt of carbonic acid (H2CO3) does not hydrolyze: А. (NH4)2CO3 B. MgCO3 C. K2CO3 D. Na2CO3 E. NaHCO3 5.20. Which one of the given salts does not decompose at heating? А. СаCO3 B. NH4НCO3 C. Са(НCO3)2 D. K2CO3 E. КНCO3 5.21. Compounds of Fe, Ni, Co, with СО are named: А. carbides B. carboniles C. hydrogen carbonates D. carbonates E. methanides B. 1, 3, 5 C. 1, 4 D. 2, 4, 5 E. 4, 5 5.25. Determination of carbonate-ion СО32– is: А. decomposition of carbonates at heating B. formation of basic medium at a hydrolysis C. evolving of CO2 at action of strong acids D. evolving of CO2 at action of alkalis E. obtaining of a precipitate at action of mineral acids 5.22. What is the optimum concentration of СО2 in air: А. 0.3% B. 0.02% C. 0.5% D. 0.03% E. 0.2% 5.26. Aluminium carbide Al4C3 reacts with water releasing: А. water gas B. carbon dioxide C. acetylene D. ethane E. methane 5.23. Carbonic acid corresponds to: А. strong, polyprotic B. monoprotic, stable C. very weak, polyprotic D. weak, polyprotic, unstable E. monoprotic 5.27. Complete and balance the reaction of the hydrolysis of aluminium carbide Al4C3. 5.24. Which of the listed reactions corresponds to redox reaction? 1. CO2 + NaOH → NaHCO3 2. CO2 + 2Mg → 2MgO + C 3. C + 2H2 → CH4 4. CO2 + H2O → H2CO3 5. CS2 + Na2S → Na2CS3 А. 2, 3 Point out the sum of the coefficients in the equation. А. 17 B. 14 C. 20 D. 16 E. 18 5.28. Complete and balance the reaction of the hydrolysis of calcium carbide CaC2 Point out the sum of the coefficients in the equation. А. 6 B. C. D. E. 5 9 8 7 5.29. Write molecular equation of transformation of sodium hydrogencarbonate NaHCO3 into a sodium carbonate Na2CO3 at heating. Point out the sum of the coefficients in the equation: А. 4 B. 7 C. 8 D. 6 E. 5 5.30. Write molecular equation of transformation of calcium carbonate CaCO3 into a calcium hydrogencarbonate Ca(HCO3)2. Point out the sum of the coefficients in the equation: А. 7 B. 4 C. 6 D. 5 E. 8 5.31. Silicon reacts with such compounds: 1. HCl 2. NaOH 3. HNO3 4. H2O 5. HF + HNO3 6. HCl + HNO3 А. 2, 3, 4 B. 2, 4, 5 C. 1, 2, 3 D. 5, 6 E. 1, 3, 5 5.32. Silicon dioxide (IV) SiO2 corresponds to the acidic oxides, but it reacts with the next acid: А. nitric acid (conc.) HNO3 B. nitric acid (dil.) HNO3 C. fluoric acid HF D. phosphoric acid E. hydrochloric acid HCl 5.33. Amorphous silicon does not react even at heating with: А. hydrogen B. oxygen C. carbon D. metals E. nitrogen 5.34. How to get silicon in industry? А. reduction of its oxide by carbon (IV) oxide B. method of electrolysis C. method of hydrometallurgy D. E. reduction of its oxide SiO2 by active metals 5.35. How do silanes burn? А. with the releasing of silicic acid H2SiO3 and water B. with the releasing of water, silicon dioxide and heat C. with the releasing of hydrogen, silicon SiO2 dioxide and heat D. with absorption of heat, formation of water and silicon dioxide E. with the releasing of water, silicon and heat 5.36. What number of hydrochloric acid needs to be taken for the complete decomposition of 2.5 mole of calcium silicide? А. 4 moles B. 15 moles C. 10 moles D. 0,1 mole E. 8 moles 5.37. Silicagel is an effective adsorbent. Choose the correct formula of silicagel? А. dimetasilicic acid H2Si2O5 B. silicic acid H2SiO3 C. micronized quartz D. mixture of polysilicic acids E. powder of SiO2 5.38. Complete and balance the reaction of the hydrolysis of silicon tetrachloride SiCl4. Point out the sum of the coefficients in the equation. А. 5 B. 7 C. 9 D. 8 E. 10 5.39. Complete and balance the reaction of the melting of silicon Si with alkali NaOH. Point out the sum of the coefficients in the equation. А. 6 B. 9 C. 10 D. 7 E. 8 5.40. Silicic acid can be obtained by the reaction: А. Si + H2O → H2SiO3 B. CaSiO3 + H2 → H2SiO3 + Ca C. SiO2 + H2O → H2SiO3 D. Na2SiO3 + 2HCl → H2SiO3 + 2NaCl E. SiO2 + H2O→ H2SiO3 5.41. What volume of hydrogen at STP will be released at dissolving of silicon Si (mass of Si = 14 g) in alcali? А. 18,4 L B. 5,6 L C. 22,4 L D. 11,2 L E. 10,5 L 5.42. What is the pH of potassium silicate solution K2SiO3? А. week acidic B. neutral C. basic D. week basic E. acidic Chapter 6. р-Elements of IVА Group. Germanium family elements (Germanium, Tin, and Lead) 6.1. β - modification (white tin) can be transformed into α - modification (grey tin) at the condition of: А. increased temperature B. treating with an alkali C. treating with an acid D. constant temperature E. decreased temperature 6.2. What is the behavior of Ge, Sn, Pb elements at the normal conditions in the presence of water and the air: А. do not react B. react forming corresponding hydroxides C. form oxides D. react releasing a gas E. react 6.3. What is the product of the reaction between tin and НСl concentrated? А. Н2[SnС14] B. SnCl 4 C. SnO D. SnCl 2 E. SnO2 6.4. Which elements of the Germanium family are situated behind Hydrogen in the electrochemical series of metals? А. Sn B. Pb C. Sn, Pb D. Ge, Pb E. Ge forming: А. basic salts B. hydroxides C. hydroxocomplex compounds D. mixed oxides E. neutral salts 6.8. Select the formulas of oxides which are forming when the Germanium family elements are heating in the air: А. GeO2, SnO, Рb2О3 B. GeO, SnO, РbО2 C. GeO2, SnO2, РbО2 D. GeO, SnO, РbО E. GeO2, SnO2, РbО 6.9. What is the behavior of Ge, Sn, Pb oxides in water? А. slightly soluble B. react releasing a gas C. react vigorously D. form hydroxocomplexes with water E. well soluble 6.5. Which elements of the Germanium family do not react with nonoxidizer acids? А. Ge, Pb B. Ge C. Sn D. Sn, Pb E. Pb 6.10. What are the products of the reaction between РbО2 and H2SO4 concentrated? А. Pb3О4, Н2О B. SO3, PbО, Н2О C. PbO, О2, Н2О D. PbSO4, Н2О E. PbSO4, О2, Н2О 6.6. What are the products of the reaction between lead and HNO3 concentrated? А. Pb(NO3)2 + NO B. Na2[Pb(OH)4] + H2O C. Pb(NO3)2 + NO D. Na2[Pb(OH)4] E. Pb(NO3)2 + NO2 6.11. What are the products of the reaction При взаємодії РbО2 + NaOH + Н2 О? А. Na4[Рb(ОН)6] B. Na[Рb(ОН)4] C. Na4[Рb(ОН)4] D. Na2[Рb(ОН)6 ] E. Na2[Рb(ОН)4] 6.7. Sn і Pb can react with alkalis aqueous solutions under heating 6.12. α - stannic and β - stannic acids (H2SnO3) can be prepared according to the following reaction: А. SnO2 + 4Н2О; Sn + HNO3(conc.) B. SnCl4 + NH3 +·H2O; Sn + HNO3(conc.) C. SnO2 + хН2О; SnО + HNO3(conc.) D. SnO2 + хН2О; SnO2 + HNO3(conc.) E. SnCl2 + 2Н2О; Sn + HNO3(conc.) 6.13. Select the proper formulas of german, Stannan and Plumban. А. Ge3N4,Sn3N4, Рb3N4 B. GeO, SnO, РbО2 C. GeO2, SnO2, РbО2 D. GeH4, SnH4, РbН4 E. GeO2, SnO, Рb2О3 6.14. What are the products of the reaction between the Germanium family elements with chlorine? А. GeCl2; SnCl2; РbС14 B. GeCl4; SnCl4; РbС12 C. GeCl4; SnCl4; РbС14 D. GeCl4; SnCl2; РbС12 E. GeCl2; SnCl4; РbС12 6.15. Which of the Germanium family elements can be dissolved in aqueous alkalis solutions? А. Ge, Sn, Pb B. Sn, Pb C. Ge, Pb D. Pb E. Ge, Sn 6.16. What is the product of SnCl2 hydrolysis? А. H2[Sn(OH)4] B. [Sn(H2O)4]2+ C. Sn(OH)2 D. Sn(OH)Cl E. SnO 6.17. What is the product of SnCl4 hydrolysis? А. Sn(OH)2 B. [Sn(OH)(H2O)3]Cl3 C. Sn(OH)Cl3 D. H2SnO3 E. Sn(OH)2Cl2 6.18. Select the proper general formulas of the Germanium family elements existing oxides. А. ЕО and Е2О3 B. ЕО2 C. Е2О3 and ЕО2 D. ЕО and ЕО2 E. ЕО 6.19. The acidic properties of the elements hydroxides become stronger in the following sequence: А. Pb(OH)4– Ge(OH)4– Sn(OH)4 B. Sn(OH)4– Ge(OH)4– Pb(OH)4 C. Sn(OH)4– Pb(OH)4– Ge(OH)4 D. Pb(OH)4–Sn(OH)4– Ge(OH)4 E. Ge(OH)4–Sn(OH)4–Pb(OH)4 6.20. The basic properties of the elements hydroxides become stronger in the following sequence: А. Sn(OH)2– Pb(OH)2– Ge(OH)2 B. Sn(OH)2– Ge(OH)2– Pb(OH)2 C. Pb(OH)2– Ge(OH)2– Sn(OH)2 D. Ge(OH)2–Sn(OH)2–Pb(OH)2 E. Pb(OH)2–Sn(OH)2– Ge(OH)2 6.21. Select the strongest oxidation agent through the listed compounds: А. PbO B. PbO2 C. GeO2 D. SnO E. SnO2 6.22. Select the strongest reduction agent through the listed ions: А. Ge2+ B. Sn2+ C. Sn4+ D. Ge4+ E. Pb2+ 6.23. Select the formulas of all oxides lead can form А. PbO, Pb3O4, PbO2 B. Pb3O4, PbO2 C. PbO, PbO2 D. PbO, Pb3O4 E. PbO, Pb3O4, PbO3 6.24. α-stannic acid in contrast to βstannic acid: А. is a strong acid B. can dissolve in acids and alkalis C. can dissolve in alkalis D. can dissolve in acids E. is insoluble in water 6.25. Which of the Germanium family elements can react with nonoxidizer acids? А. Sn, Ge B. Ge, Sn, Pb C. Pb D. Ge, Pb E. Sn, Pb 6.26. What is the electronic configuration of Pb2+ ion? А. [Xe] 6s26p1 B. [Xe] 6s26p2 C. [Xe] 6s16p0 D. [Xe] 6s16p1 E. [Xe] 6s26p0 6.27. What is the electronic configuration of Pb4+ ion? А. [Xe] 6s16p1 B. [Xe] 6s26p0 C. [Xe] 6s06p0 D. [Xe] 6s16p0 E. [Xe] 6s16p0 Chapter 7. р-Elements of VА Group. Nitrogen and its compounds in the negative oxidation states 7.1. Water solution of ammonia shows: А. reducing and acidic B. reducing and weak basic C. oxidizing and strong acidic D. oxidizing, weak basic E. oxidizing і acidic 7.2. The degree of dissociation of ammonia increases with: А. concentration of solution B. adding of the salt of ammonia C. adding of alkali D. dilution of solution E. cooling of solution 7.3. Specify the formula of compound that has both ionic and covalent bonds: А. N2O5 B. NH4NO3 C. Са2N3 D. NH3 E. NCl3 7.4. For which of the following compounds most characteristic hydrogen bonds? А. NH3 B. PH3 C. AsH3 D. CaH2 E. NaH 7.5. One of the products of hydrazine combustion under normal conditions are: А. NO2 B. NH3 C. NO D. N2O E. N2 7.6. Nitric acid diluted HNO3 at the reaction with one of the given metals forms compound of nitrogen with oxidation number 3: А. Cu B. Mg C. Pt D. Pb E. Ag 7.7. Ammonium hydrogencarbonate decomposes with formation of mixture of gases: А. N2O, CO B. NO, CO2 C. NH3, CO2 D. NO2, CO2 E. NH3, CO 7.8. What will be the product of reduction of nitrogen at the reaction of nitric acid HNO3 (very diluted) with magnesium Mg? А. N2 B. N2O C. NO D. NH4NO3 E. NO2 7.9. Which one of the given metals does not react with concentrated nitric acid at the ordinary conditions? А. K B. Ca C. Mn D. Fe E. Co 7.10. At the boiling of ammonium chloride solution with magnesium powder following gases are released: А. NН3 and Н2 B. NH3 C. Н2 D. NO2 and NH3 E. NО and Н2 7.11. Very diluted nitric acid HNO3 reduces by active metals to such compound: А. NO2 B. NO C. NH4NO3 D. N2O E. N2 7.12. At the interaction of ammonia with sodium hypochlorite one of the products is: А. N2H4 B. HN3 C. N2O D. N2 E. NH2OH 7.13. Specify the reaction of medium in an aqueous solution of hidrazonium salt N2H5Cl. А. acidic B. alkaline C. weak alkaline D. strongly alkaline E. neutral 7.14. What properties more typical for hydrazine and its derivatives? А. strong acidic B. acidic C. reducing and oxidizing D. oxidizing E. reducing 7.15. Specify the formula of substance that can be used for draining of ammonia. А. Н2SO4(dil) B. СаCl2(anhydrous) C. Н2SO4(conc.) D. Р2О3(solid) E. Р2О5(solid) 7.16. Which one of the listed compounds has the oxidation number of nitrogen -2? А. N2H4 B. HCN C. NH3 D. NH4Cl E. NH2OH 7.17. Nitrogen is formed at decomposition of such salt of ammonium: А. NH4HCO3 B. .(NH4)2CO3 C. NH4NO3 D. NH4Cl E. NH4NO2 7.18. Which of the listed electronic configurations corresponds to the atom of Nitrogen? А. 1s22s22p4 B. 1s22s22p63p1 C. 1s22s22p2 D. 1s22s22p3 E. 1s22s22p5 7.19. At decomposition of what salt is possible to get ammonia NH3? А. NaNO3 B. NH4NO2 C. NaNO2 D. NH4HCO3 E. NH4NO3 7.20. Which one of the listed compounds has the oxidation number of nitrogen -1? А. N2O B. NH2OH C. N2H4 D. NH4OH E. NaNO2 7.21. As a result of decomposition of what salt it is possible to get nitrogen N2? А. AgNO3 B. NH4NO3 C. KNO3 D. NH4Cl E. NH4NO2 7.22. What from the given reactions is the reaction of substitution? А. NH3 + HCl → B. Na + NH3 → C. NH3 + CuO → D. Cl2 + NH3 → E. NH3 + СuSO4 → 7.23. Ammonia NH3 can burn in the presence of the catalyst with forming: А. NO2 B. NO C. N2 D. N2O E. N2O3 7.24. Ammonia NH3 can burn in the atmosphere of oxygen with forming: А. NO B. NO2 C. N2 D. NH3 E. N2O 7.25. What is the product of reduction of nitric acid very diluted when it reacts with calcium: Сa + HNO3 (very diluted) →? А. NO B. NO2 C. N2 D. N2O E. NH4NO3 7.26. Which one from the resulted reactions is the reaction of connection? А. NO2 + NH3 B. NH3 + CuSO4 C. NH3 + Na D. NO + H2 E. NH3 + O2 7.27. Which of the listed nitrates hydrolyses in a water solution? А. KNO3 B. NaNO3 C. Sr(NO3)2 D. Ba(NO3)2 E. NH4NO3 7.28. Which of the given formulas corresponds to hydroxilamine? А. NH2OH B. N2H4 C. HN3 D. NaNH2 E. NH4OH 7.29. Which of the given equation describes reaction of hydroxilamine NH2OH with water? А. NH2OH+HOH=NH3 + 2OHB. NH2OH+HOH= NH4+ +2OHC. NH2OH+HOH=[NH3OH]+OHD. NH2OH+HOH=NH2+ + 2OHE. NH2OH+HOH= NH3OH+ + H+ 7.30. Water solution of hydroxilamine NH2OH has the properties: А. weak basic B. strong acidic C. amphoteric D. strong basic E. weak acidic Chapter 8. р-Elements of VА Group. Nitrogen and its compounds in the positive oxidation states 8.1. In which of the resulted reactions it is impossible to get NaNO3? А. Cu(NO3)2 + NAOH B. Na2CO + HNO3 C. NAOH + HNO3 D. NaCl + HNO3 E. NAOH + NO2 + NO + O2 8.2. Which of the given nitrates decomposes with formation of a metal? А. B. C. D. E. Al(NO3)2 AgNO3 Cа(NO3)2 NaNO3 Pb(NO3)2 8.3. Nitric acid diluted reacts without formation of gaseous products of reaction with: А. S B. Cu C. Mg D. P E. Pb 8.4. NaNO2 has the reduction properties when reacts with: А. KMnO4 B. NaHCO3 C. KI D. H2S E. NH3 8.5. Which one of the given metals does not react with nitricHNO3 acid? А. Pt B. Mg C. Pb D. Cо E. Cu 8.6. Nitric acid diluted HNO3 at the reaction with one of the given metals forms compound of nitrogen with oxidation number 3: А. Pb B. Cu C. Ag D. Mg E. Pt 8.7. Choose from the following equations one that characterizes the property of nitrate acid form the reaction of exchanging: А. 5HNO3 + 3P + 2H2O = 3H3PO4 + 5NO B. CaCO3 + 2HNO3 = Ca(NO3) 2 + CO2 + H2O C. 4Ca + 10HNO3 = 4Ca(NO3) 2 + N2O + 5H2O D. Cu2O + 6HNO3 = Cu(NO3) 2 + 2NO2 + 3H2O E. Cu + 4HNO3 = Cu(NO3) 2 +2NO2 + 2H2O 8.8. Nitrogen released during thermal decomposition of such ammonium salt: А. NH4HCO3 B. NH4NO2 C. NH4Cl D. NH4NO3 E. .(NH4)2CO3 8.9. Which one of the given metals does not react with concentrated nitric acid at the ordinary conditions? А. Co B. K C. Fe D. Mn E. Ca 8.10. What is the product of reduction of nitric acid diluted when it reacts with phosphorus? А. NO2 B. N2O C. NH3 D. N2 E. NO 8.11. Very diluted nitric acid HNO3 reduces by active metals to such compound: А. N2 B. NO C. NO2 D. N2O E. NH4NO3 8.12. Which of the listed oxides is an anhydride of nitric acid HNO3? А. N2O B. N2O3 C. N2O5 D. NO E. NO2 8.13. Which of the listed oxides is an anhydride of nitrous acid HNO2? А. NO B. NO2 C. N2O3 D. N2O4 E. N2O5 8.14. Oxides which have an acidic properties are in a row: А. N2O, N2O3, N2O5 B. N2O3, NO2, N2O5 C. NO, N2O3, N2O5 D. NO, N2O3, N2O5 E. N2O, NO, NO2 8.15. Concentrated nitric acid does not react with a following simple substance: А. sulfur B. phosphorus C. carbon D. copper E. gold 8.16. Which one of the given metals does not react with concentrated nitric acid? А. Cr B. Zn C. Na D. Mg E. Cu 8.17. What gas forms in a result of action of the concentrated nitric acid HNO3 on a sulfur? А. N2O B. N2O C. NO2 D. NO E. N2O 8.18. Which of the given oxides can be oxidizing agents only: А. NO B. N2O4 C. NO2 D. N2O5 E. N2O3 8.19. Which of the given compounds of nitrogen has the oxidizingreduction properties: А. NO2 B. HNO3 C. NH3 D. NH4Cl E. N2O5 8.20. What oxide can be obtained in the result of reaction of nitrogen with oxygen? А. N2O5 B. NO C. NO2 D. N2O5 E. N2O 8.21. Nitrogen has a positive value of the oxidation state in the compounds with: А. magnesium B. calcium C. hydrogen D. chlorine E. potassium 8.22. Which of the given compounds of nitrogen can be oxidizing agents only? А. B. C. D. E. NH3 HNO3 HNO2 N2O NO2 8.23. Choose the formula of nitrogen oxide, which is used for anesthesia? А. N2O B. NO2 C. NO D. N2O4 E. N2О3 8.24. Which of the listed electronic configurations corresponds to the atom of Nitrogen? А. 1s22s22p2 B. 1s22s22p5 C. 1s22s22p4 D. 1s22s22p63p1 E. 1s22s22p3 8.25. Nitrogen has a positive oxidation number in compounds with: А. calcium B. hydrogen C. lithium D. oxygen E. magnesium 8.26. What is the “royal water”? А. Mixture of HCl and HNO3 B. Mixture of HCl and HNO2 C. Mixture of HF and HNO3 D. Mixture of HCl and HN3 E. Mixture of H2SO4 and HNO3 8.27. Decomposition of which of the listed salts can be obtained ammonia? А. NH4NO3 B. C. NaNO2 D. NH4HCO3 E. NaNO3 8.28. What nitrate is decomposed at heating with formation of nitrite? А. NaNO3 B. AgNO3 C. Hg(NO3)2 D. Ca(NO3)2 E. Cu(NO3)2 8.29. Nitrogen (ІІ) oxide NO corresponds to the oxides which are: А. amphoteric B. does not forming a salt C. D. basic E. acidic 8.30. What is the product of reduction of nitric acid very diluted when it reacts with calcium: Сa + HNO3 (very diluted) →? А. NO2 B. N2O C. N2 D. NH4NO3 E. NO 8.31. What is the product of reaction of mercury Hg with surplus of concentrated nitric acid HNO3? H2O А. Hg(NO3)2 + NO2 + B. Hg2(NO3)2 + N2O5 + H2O C. Hg2(NO3)2 + NO + H2O D. Hg(NO3)2 + NO + H2O E. Hg(NO3)2 + N2O + H2O 8.32. What is the product of reduction of nitric acid concentrated when it reacts with magnesium Mg? А. N2O B. NH3 C. NO2 D. NO E. N2O5 8.33. What is the product of oxidation of sulfur S with HNO3 concentrated? А. H2SO3 B. SO2 C. S D. H2S E. H2SO4 8.34. Which one of the given nitrates decomposes with formation of oxide of metal? А. KNO3 B. NaNO3 C. Pb(NO3)2 D. Hg(NO3)2 E. AgNO3 8.35. Choose the compound in which nitrogen can be an oxidizing agent only: А. NO2 B. HNO2 C. N2O D. KNO3 E. NH3 to give corresponding compounds: А. Ag, NO2, O2 B. AgO, NO2 C. AgNO2, O2 D. Ag, NO2 E. AgO, N2O3 8.37. Which of the listed electronic configurations corresponds to the atom of nitrogen in a nitrogen oxide (ІІІ) N2O3? А. [He] 2s22p0 B. [He] 2s22p2 C. [He] 2s22p3 D. [He] 2s12p1 E. [He] 2s22p1 8.38. Which of the listed electronic configurations corresponds to the atom of nitrogen in a nitric acid HNO3? А. [He] 2s12p2 B. [He] 2s22p3 C. [He] 2s02p0 D. [He] 2s12p1 E. [He] 2s22p2 8.36. Silver nitrate AgNO3 decomposes Chapter 9. р-Elements of VА Group. Phosphorus and its compounds 9.1. What is the color of phenolphtalien in solution of potassium orthophosphate? А. raspberry B. red C. yellow D. colourless E. dark blue 9.2. What is the equivalent mass of orthophosphoric acid? А. 32.67 B. 49 C. 24.5 D. 98 E. 49.65 9.3. Pyrophosphoric acid is prepared by heating of orthophosphoric acid. Which chemical formula through the listed ones corresponds to pyrophosphoric acid? А. H2[HPO3] B. H4P2O7 C. H3PO4 D. H[H2PO2] E. HPO3 9.4. Which chemical formula through the listed ones corresponds to a salt of orthophosphoric acid? А. – B. NaPO3 C. Na2[PO3H] D. NaH2PO4 E. NaH2PO2 9.5. What is the oxidation state of Phosphorus in hypophosphorus acid? А. +3 B. +1 C. –3 D. +5 E. +4 9.6. What is the oxidation state of Phosphorus in phosphoric acid? А. +4 B. –3 C. +3 D. +1 E. +5 9.7. What is the oxidation state of Phosphorus in phosphorus acid? А. –3 B. +3 C. +1 D. +4 E. +5 9.8. In how many stages does dihydrogenphosphate ion dissociate? А. in two stages: after the first – completely, after the second – partly B. in two stages: after the first – partly, after the second – completely C. in two stages, after each – partly D. in one stage – partly E. in one stage – completely 9.9. Which acid through the listed ones is monoprotic? А. phosphorus B. pyrophosphoric C. hypophosphorus D. sulfuric E. phosphoric 9.10. What ions are present in the highest amount is the aqueous solution of orthophosphoric acid? А. OH– B. HPO42– C. H2PO4– D. H+ E. PO43– 9.11. What products are forming when phosphorus has been dissolving in solution of NaOH? А. PH3 and NaH2PO2 B. PH3 and Na2HPO3 C. PH3 and NaН2PO4 D. PH3 and Na2НPO4 E. PH3 and Na3PO4 9.12. What is the product of phosphine oxidation with the acidic solution of potassium permanganate? А. – B. C. D. E. H3PO4 HPO3 H3PO3 H3PO2 9.13. What are the products of PCl3 hydrolysis? А. H3PO4 and HCl B. H3PO3 and HCl C. H3PO4 and HClO D. H3PO2 and HCl E. PH3 and HCl 9.14. What are the products of PCl5 hydrolysis? А. H3PO2 and HCl B. H3PO3 and HCl C. H3PO4 and HClO D. PH3 and HCl E. H3PO4 and HCl 9.15. The is the product of hypophosphorus acid oxidation? А. metaphosphoric acid B. orthophosphoric acid C. pyrophosphoricacid D. – E. phosphorus acid 9.16. What are the products of the selfoxidation self-reduction reaction of hypophosphorus acid? А. H3PO4 and Р B. H3PO3 and Н3РО4 C. H3PO4 and РН3 D. H3PO3 and Р E. H3PO3 and РН3 9.17. What are the products of the selfoxidation self-reduction reaction of phosphorus acid? А. H3PO2 and Н3РО4 B. H3PO4 and Р C. H3PO4 and РН3 D. H3PO2 and РН3 E. H3PO2 and Р 9.18. What compound forms when phosphorus trioxide P2O3 is acted by the excess of sodium hydroxide? А. Na3PO3 B. NaH2PO4 C. Na2HPO3 D. Na2HPO4 E. Na3PO4 9.19. What electronic configuration corresponds to Arsenic (As) atom? А. [Ar]3d104s24p3 B. [Kr] 4d105s25p3 C. [Ne] 3s23p3 D. [He] 2s223 E. [Xe] 4f145d106s26p3 Chapter 10. р-Elements of VА Group. Arsenic family elements (Arsenic, Antimony, and Bismuth) 10.1. What electronic configuration corresponds to Antimony (Sb) atom? А. [Ne] 3s23p3 B. [He] 2s223 C. [Ar]3d104s24p3 D. [Kr] 4d105s25p3 E. [Xe] 4f145d106s26p3 10.2. What electronic configuration corresponds to Bismuth (Bi) atom? А. [Kr] 4d105s25p3 B. [Ar]3d104s24p3 C. [He] 2s223 D. [Xe] 4f145d106s26p3 E. [Ne] 3s23p3 10.3. What electronic configuration corresponds to Arsenic As (+3)? А. [Ar]3d104s24p0 B. [Ar]3d104s14p1 C. [Ar]3d94s14p3 D. [Ar]3d104s24p6 E. [Ar]3d74s24p3 10.4. What electronic configuration corresponds to Arsenic As (–3)? А. [Ar]3d104s24p0 B. [Ar]3d94s14p3 C. [Ar]3d104s14p1 D. [Ar]3d74s24p3 E. [Ar]3d104s24p6 10.5. What electronic configuration corresponds to Antimony Sb (+3)? А. [Kr] 4d105s25p6 B. [Kr] 4d95s25p1 C. [Kr] 4d85s15p3 D. [Kr] 4d95s05p3 E. [Kr] 4d105s25p0 10.6. What electronic configuration corresponds to Bismuth Bi (+3)? А. [Xe] 4f145d76s26p3 B. [Xe] 4f145d106s06p2 C. [Xe] 4f145d106s26p6 D. [Xe] 4f145d106s26p0 E. [Xe] 4f115d106s26p3 10.7. What electronic configuration corresponds to Antimony Sb (– 3)? А. [Kr] 4d95s25p1 B. [Kr] 4d95s05p3 C. [Kr] 4d105s25p6 D. [Kr] 4d105s25p0 E. [Kr] 4d85s15p3 10.8. What electronic configuration corresponds to Arsenic As (+5)? А. [Xe] 4f145d106s26p6 B. [Xe] 4f115d106s26p3 C. [Xe] 4f145d76s26p3 D. [Xe] 4f145d106s26p0 E. [Xe] 4f145d106s06p2 10.9. As, Sb, Bi can react with the following acids: А. H3PO4, HNO3, H2SO4 (diluted) B. CH3COOH, HCl, H2SO4 conc) C. HNO3, H2SO4 conc), HClO3 D. HCl, H3PO4, CH3COOH E. H3PO4, HNO3, H2SO4 10.10. What is the product of Antimony treating with concentrated sulfuric acid? А. H[Sb(OH)6] B. HSbO3 C. H2S D. Sb2(SO4)3 E. Sb2O3 10.11. What is the product of Arsenic oxidation with concentrated nitric acid? А. H3AsO3 B. H3AsO4 C. As2O5 D. As2O3 E. HAsO2 10.12. What is the product of Bismuth treating with concentrated sulfuric acid? А. HBiO3 B. Bi2O3 C. H2S D. Bi2(SO4)3 E. SO3 10.13. Which of the given elements does not react with concentrated nitric acid? А. S B. Sb C. P D. As E. Bi 10.14. What is the molar mass (in g/mole) of the gas which is releasing under the reaction of Bismuth with diluted nitric acid? А. 44 B. 28 C. 64 D. 32 E. 30 10.15. Which of the given oxides can dissolve in water and sodium hydroxide? А. As2O3 B. Sb2O3 C. Bi2O3 D. Sb2O5 E. 10.16. Which of the given oxides series can dissolve in water? А. Sb2O3, Sb2O5 B. Bi2O3, Sb2O5 C. Bi2O3, Sb2O3 D. As2O3, Sb2O3 E. As2O3, As2O5 10.17. What properties Bismuth(ІІІ) oxide posses? А. amphoteric B. acidic C. those which can not form salts D. basic E. combined 10.18. What properties Arsenic (ІІІ) oxide posses? А. basic B. amphoteric with acidic properties prevailing C. amphoteric with basic properties prevailing D. acidic E. those which can not form salts 10.19. What properties Antimony(ІІІ) oxide posses? А. those which can not form salts B. amphoteric C. acidic D. combined E. basic 10.20. What is the change of the electrons donor ability of molecules in the consequence NH3 – PH3 – AsH3 – SbH3 – BiH3 ? А. − B. increases C. does not change D. decreases E. changes without any regularity 10.21. Which of the given compounds is the less stable and its molecules are the less polar? А. PH3 B. SbH3 C. NH3 D. AsH3 E. BiH3 E. Sb2S3 10.22. Which of the given compounds posses the strongest electrons donation ability? А. SbH3 B. BiH3 C. AsH3 D. PH3 E. NH3 10.27. What are the products of As(III) and Sb(III) sulfides with ammonium sulfide interaction? А. As2S5, Sb2S5 B. (NH4)3AsS3, (NH4)3SbS3 C. (NH4)3AsS4, Sb2S5 D. As2S5, (NH4)3SbS4 E. (NH4)3AsS4, (NH4)3SbS4 10.23. In which of the given oxides the mass percentage of Oxygen is the least? А. P2O5 B. Cl2O5 C. N2O5 D. As2O5 E. Sb2O5 10.28. What are he products of ammonium thioarsenate treatment with hydrochloric acid? А. As2S5, Н2S B. As2S3, Н2S C. As2О5, Н2S D. NH3, SO2 E. As2О5, SО3 10.24. In which of the given sulfides the mass percentage of Sulfur is the least? А. Bi2S3 B. Sb2S3 C. As2S3 D. Al2S3 E. P2S3 10.25. In which of the given oxides the mass percentage of Oxygen is the least? А. As2O3 B. Bi2O3 C. P2O3 D. N2O3 E. Sb2O3 10.26. The mixture of the elements suldides was treated with Na2S solution. Which of the given sulfides does not dissolve? А. Bi2S3 B. As2S3 C. As2S5 D. Sb2S5 10.29. What are the products of ammonium thioarsenite treatment with hydrochloric acid? А. As2S5, Н2S B. NH3, SO2 C. As2О3, SО3 D. As2S3, Н2S E. As2О3, Н2S 10.30. The Marsh’ reaction is based on the following property of the elements compounds: А. the solubility of Arsenic oxides in water B. the ability of bismuthates to posses oxidation properties C. The interaction of Arsenic (III) oxide with hydrochloric acid D. the solubility of Arsenic sulfides in concentrated nitric acid HNO3 E. the ability of arsin to decompose under heating 10.31. What is the change of acidic properties for the compounds consequence: As(OH)3 – Sb(OH)3 – Bi(OH)3? А. do not change B. − C. change without any regularity D. decrease E. increase 10.32. Which of the given hydroxides have amphoteric properties? А. Sb(OH)3, Cr(OH)3 B. Ca(OH)2, Bi(OH)3 C. Mg(OH)2, As(OH)3 D. Bi(OH)3, As(OH)3 E. Fe(OH)2, Bi(OH)3 10.33. Which of the given hydroxides are insoluble in water but are soluble in acids and alkalis? А. Bi(OH)3, Fe(OH)2 B. Bi(OH)3, As(OH)3 C. Cr(OH)3, Sb(OH)3 D. Ba(OH)2, Cu(OH)2 E. As(OH)3, Ca(OH)2 10.34. What is the product of Antimony(III) chloride hydrolysis reaction? А. Sb(OH)3 B. Sb(OH)2Cl C. SbOHCl2 D. Sb2O3 E. SbOCl 10.35. What is the product of Antimony(III) nitrate hydrolysis reaction? А. Sb(OH) 2NO3 B. SbOH(NO3)2 C. Sb(OH)3 D. SbONO3 E. Sb2O3 10.36. What is the product of Bismuth(III) chloride hydrolysis reaction? А. Bi(OH)2Cl B. Bi2O3 C. BiOHCl2 D. Bi(OH)3 E. BiOCl 10.37. What is the product of Bismuth(III) nitrate hydrolysis reaction? А. Bi(OH) 2NO3 B. Bi2O3 C. Bi(OH)3 D. BiOH(NO3)2 E. BiONO3 10.38. What is the molar mass (in g/mole) of the gas which is releasing under the hydrolysis of calcium arsenide? А. 92 B. 32 C. 46 D. 64 E. 78 10.39. What are the oxidation numbers of Arsenic in the following compounds: AsH3, Na3AsO4, H3AsO3? А. –3, +5, +3 B. +5, –3, +3 C. +3, +5, –3 D. +5, +3, –3 E. –3, +3, +5 10.40. What are the oxidation numbers of Antimony in the following compounds: Mg3Sb2, Na[Sb(OH)6], Sb2(SO4)3? А. –3, +3, +5 B. +5, –3, +3 C. –3, +5, +3 D. +3, +5, –3 E. +5, +3, –3 10.41. What are the oxidation numbers of Bismuth in the following compounds: Ca3Bi2, NaBiO3, BiONO3? А. +5, –3, +3 B. –3, +3, +5 C. +5, +3, –3 D. –3, +5, +3 E. +3, +5, –3 10.42. What is the change of oxidation ability for the compounds consequence: As+5 – Sb+5 – Bi+5 ? А. − B. does not change C. changes without any regularity D. decreases E. increases 10.43. What is the change of reduction ability for the compounds consequence: As+3 – Sb+3 – Bi+3 ? А. increases B. changes without any regularity C. decreases D. does not change E. − the reduction agent and the sum of the coefficients in the following reaction: As2O3 + Zn + HCl → А. –1, 30 B. 0, 30 C. –1, 19 D. 0, 29 E. 0, 20 10.45. Point out the oxidation state of the oxidation agent and the sum of the coefficients in the following: K3AsO4 + KI + H2SO4 → А. –1, 8 B. +5, 8 C. +5, 7 D. +6, 8 E. +6, 6 10.46. Point out the oxidation state of the reduction agent and the sum of the coefficients in the following reaction: Na3AsO3 + I2 + KOH → А. +3, 8 B. +3, 6 C. 0, 8 D. 0, 10 E. +3, 7 10.44. Point out the oxidation state of Chapter 11. р-Elements of VІІА Group. Halogens 11.1. What electronic configuration corresponds to Bromine atom in potassium bromate? А. 4s24p3 B. C. D. E. 4s24p5 4s24p0 4s14p6 4s04p5 11.2. What electronic configuration corresponds to Chlorine atom in potassium perchlorate? А. 3s13p5 B. 3s23p0 C. 3s03p0 D. 3s1p6 E. 3s23p5 11.3. What electronic configuration corresponds to Chlorine atom in chlorous acid? А. 3s23p5 B. 3s1p6 C. 3s23p2 D. 3s13p5 E. 3s23p0 11.4. What electronic configuration corresponds to Bromine atom in potassium hypobromite? А. 4s24p0 B. 5s25p5 C. 5s25p4 D. 4s24p4 E. 4s24p5 11.5. What is the electronic configuration of І– ion? А. 6s26p4 B. 6s26p5 C. 5s25p5 D. 5s25p6 E. 5s25p4 11.6. What is the electronic configuration of F– ion? А. 2s02p6 B. 2s22p4 C. 2s22p5 D. 2s02p5 E. 2s22p6 11.7. What is the electronic configuration of Br– ion? А. 5s25p6 B. 4s14p6 C. 4s04p5 D. 4s24p6 E. 4s24p5 11.8. What is the regularity in the oxidation properties changing in the elements consequence F2Cl2-Br2-I2? А. decrease B. increase, then decrease C. increase D. don’t change E. decrease, then increase 11.9. The reduction properties in the compounds consequence HCl – HBr – HI will: А. decrease, then increase B. increase, then decrease C. decrease D. don’t change E. increase 11.10. The atomic radii of the elements in the elements consequence F – Cl – Br – I – At will: А. increase B. increase, then decrease C. don’t change D. decreaseз E. decrease, then increase 11.11. The electronegativity of the elements in the consequence F – Cl – Br – I – At will: А. decrease B. increase C. decrease, then increase D. increase, then decrease E. don’t change 11.12. The non-metallic properties of the elements in the consequence F – Cl – Br – I – At will: А. decrease, then increase B. increase C. increase, then decrease D. don’t change E. decrease 11.13. Which of the given elements can easily transform into the gaseous state? А. Cl B. Br C. At D. F E. I 11.14. Which of the given elements can have only one oxidation number in its compounds? А. Br B. I C. Cl D. F E. At 11.15. What is the type of chemical binding in Cl2 molecule? А. metallic B. hydrogen C. covalent polar D. ionic E. covalent unpolar 11.16. What is the type of chemical binding in HBr molecule? А. ionic B. covalent polar C. hydrogen D. donor-acceptor E. covalent unpolar 11.17. The strength of the acids in the consequence HF – HCl – HBr – HI will: А. decreases B. doesn’t change C. increases D. — E. changes without any correlation 11.18. The strength and stability of the acids in the consequence HClO – HClO2 – HClO3 – HClO4 will: А. decrease B. don’t change C. — D. change without any correlation E. increase 11.19. The oxidation ability of he acids in the row HClO – HClO2 – HClO3 – HClO4: А. decreases B. doesn’t change C. — D. change without any correlation E. increases 11.20. In a compound with which of the elements Oxygen has oxidation +2 ? А. F B. Br C. N D. S E. Cl 11.21. The destrouction of a glass is based on the reaction: А. 2HF + KOH → KHF2 + H2O B. SiO2 + 2NaOH → Na2SiO3 + H2O C. SiO2 + 6HF → H2[SiF6] + 2H2O D. SiO2 + Na2CO3 → Na2SiO3 + CO2 E. SiO2 + 2Mg → Si + 2MgO 11.22. Hydrogen chloride may be prepared under the reaction: А. NaCl(solid) + H2SO4(dil) → B. NaCl(solution) + H2SO4(conc) → C. all reaction may be used D. NaCl(solid) + H2SO4(conc) → E. NaCl(solution) + H2SO4(dil) → 11.23. The industrial preparation of chlorine is based on: А. HClconc + MnO2 → B. electrolysis of NaCl solution C. HClconc + PbO2 → D. HCldilute + MnO2 → E. electrolysis of molten NaCl 11.24. The reaction Cl2 + H2O → HCl + HClO belongs to the following type of redaction-oxidation reactions: А. intermolecular B. it’s not red-ox reactiopn C. intra-molecular D. self-oxidation self-reduction E. − 11.25. Which of the given salts doesn’t hydrolyze? А. AlCl3 B. FeCl2 C. BiCl3 D. ZnCl2 E. NaClO4 11.26. The acidic solution may be obtained by dissolving in water: А. NaCl B. KClO4 C. KBr D. FeCl3 E. KI 11.27. It is possible to increase the percent of alumunium chloride hydrolysis by adding: А. NaCl B. Na2CO3 C. NH4Cl D. ZnCl2 E. HCl 11.28. For which of the given salts the pH of its aqueous solution is less than 7? А. NaBr B. SnCl2 C. KClO4 D. KBr E. NaCl 11.29. What products will form when aqueous solutions of aluminium chloride and sodium sulfide will be mixed? А. Al(OH)3 + H2S B. Al2S3 + H2O C. Al(OH)2Cl + H2S D. AlOHCl2 + NaHS E. Al(OH)3 +NaHS 11.30. What products will form when aqueous solutions of CrCl3 and Na2CO3 will be mixed? А. CrOHCl2 + NaHCO3 B. Cr(OH)2Cl + NaHCO3 C. Cr2(CO3)3 + NaHCO3 D. Cr(OH)3 + H2CO3 E. Cr(OH)3 + NaHCO3 11.31. Which equation should be used for calculating the hydrolysis constant for ZnCl2? А. К Н 2О Кh = К base ⋅ К acid B. Кh = 10 −7 К base C. Кh = D. Кh = E. Кh = 10 −7 К acid К Н 2О К acid 10 −14 К base 11.32. Which equation should be used for calculating the constant of hydrolysis for ammonium bromide? А. К Н 2О h= С salt К B. h = Н О 11.34. Chose the solubility product constant expression for PbCl2 salt. А. [Pb]·[Cl] B. [Pb]·[Cl]2 C. [Pb2+]·[Cl–]2 D. [Pb2+]·[2Cl–] E. [Pb2+]·2[Cl–]2 11.35. Chose the expression for calculation the solubility of PbCl2 salt in mol/l. А. K S = 4 sp 27 B. K sp S =3 4 2 К base C. h = D. E. h= Кh Сsalt 11.33. Which equation should be used for calculating the constant of hydrolysis for FeCl3? А. 10 −7 Кh = К acid B. К = 10 −7 h K base C. К = К Н 2О h К base ⋅ К acid Кh = S =5 Кh Кh h= С salt D. C. 10 −14 К acid E. Кh = К Н О 2 К base K sp 108 D. S = K sp E. K sp S= 4 11.36. Chose the expression for calculation the solubility of AgBr salt in mol/l. А. K sp S =4 27 B. S = K sp C. S =3 D. S= E. S =5 K sp 4 K sp 4 K sp 108 11.37. Calculate the volume of oxygen which may be obtained under the thermal decomposition of 1 mole KClO3? А. 44.8 B. 33.6 C. 11.2 D. 22.4 E. 67.2 11.38. How many liters of chlorine may be prepared under the reaction of 3 moles of MnO2 with HCl? А. 33.6 B. 67.2 C. 22.4 D. 11.2 E. 44.8 11.39. How many liters of chlorine may be prepared under the reaction of 1 mole of KMnO4 with HCl? А. 22.4 B. 44.8 C. 56 D. 67.2 E. 33.6 11.40. How many liters of chlorine may be prepared under the reaction of 2 moles of PbO2 with HCl? А. 67.2 B. 44.8 C. 56 D. 33.6 E. 22.4 11.41. How many liters of chlorine may be prepared under the reaction of 0.1 mol of potassium dichromate with HCl? А. 6.72 B. 44.8 C. 4.48 D. 22.4 E. 11.2 Chapter 12. General characteristic of d-Elements. dElements of IВ Group. Copper, Silver, Gold 12.1. Which of the listed electronic configurations corresponds to Cd2+ ion? А. [Kr]4d95s0 B. [Kr]4d105s1 C. [Kr]4d105s2 D. [Kr]4d85s2 E. [Kr]4d105s0 12.2. Which of the listed electronic configurations corresponds to Hg1+ ion? А. [Xe]4f145d106s1 B. [Xe]4f145d106s1 C. [Xe]4f145d86s1 D. [Xe]4f145d96s2 E. [Xe]4f145d106s0 12.3. Which of the listed electronic configurations corresponds to 29Сu atom? А. [Ar] 3d10 4s1 B. [Ar] 3d8 4s2 C. [Ar] 3d7 4s2 D. [Ar] 3d9 4s2 E. [Ar] 3d6 4s2 12.4. Which of the listed electronic configurations corresponds to Cu2+ ion ? А. [Ar]3d104s2 B. [Ar]3d94s0 C. [Ar]3d84s2 D. [Ar]3d84s1 E. [Ar]3d104s1 12.5. Which of the listed electronic configurations corresponds to 47Ag atom? А. [Kr]4d105s1 B. [Kr]4d85s1 C. [Kr]4d95s2 D. [Kr]4d85s2 E. [Kr]4d105s0 12.6. What is the electronic configuration of Ag+ ion? А. [Kr]4d105s0 B. [Kr]4d105s2 C. [Kr]4d85s1 D. [Kr]4d95s1 E. [Kr]4d85s2 12.7. Which of the listed electronic configurations corresponds to 79Au atom? А. [Xe]4f145d106s2 B. [Xe]4f145d86s2 C. [Xe]4f145d96s2 D. [Xe]4f145d106s1 E. [Xe]4f145d96s1 12.8. What electronic configuration of ion Au3+? А. [Xe]4f145d86s0 B. [Xe]4f145d86s1 C. [Xe]4f145d96s2 D. [Xe]4f145d96s1 E. [Xe]4f145d106s0 12.9. What is the mass percentage of mercury in mercury (I) chloride (calomel)? А. 79% B. 91% C. 85% D. 48% E. 52% 12.10. The most important minerals of copper are chalcocite and malachite. What are the chemical formulas of these minerals? А. Cu2S, (CuOH)2CO3 B. CuO, Cu(NO3)2 C. CuS CuCl2 D. (CuOH)2CO3, CuF2 E. CuFeS2, Cu2O 12.11. What is the chemical formula of the natural mineral cinnabar? А. ZnS B. CdS C. HgS D. Hg2S2 E. Hg2S 12.12. What metal through the listed ones exists in a liquid state at STP: А. cadmium B. zinc C. none of the listed metals D. mercury E. all listed metals 12.13. What oxidation states are the most typical for cadmium: А. +2, +3 B. +1 C. +2, +1 D. +2 E. +3 12.14. What coordination numbers are common for zinc in coordination compounds? А. 2, 4 B. 2, 6 C. 4, 5 D. 4, 6 E. 3,6 12.15. What oxidation states are the most typical for copper in its compounds? А. +1, +4 B. +1, +2 C. +1, +3 D. +2, +4 E. +2, +3 12.16. What oxidation state is the most typical for gold in its compounds? А. +2, +3 B. +1, +2 C. +2, +5 D. +1, +3 E. +3, +4 12.17. What oxidation state is the most typical for silver in its compounds? А. +3 B. +1 C. +4 D. +5 E. +2 12.18. The chemical activity of substances in the consequence Cu–Ag–Au will: А. increase firstly, then decrease B. decrease C. decrease firstly, then increase D. do not change E. increase 12.19. Silver and copper can not dissolve in: А. concentrated sulfuric acid B. aqua regia (a mixture of hydrochloric and nitric acids) C. diluted hydrochloric and sulfuric acids D. diluted nitric acid E. concentrated nitric acid 12.20. Which metal can not be oxidized on air, even at strong heating: А. nickel B. zinc C. copper D. gold E. iron 12.21. In what acids through the listed ones silver may be dissolved? А. HCl, HNO3(conc.) B. HNO3(dil.), H2SO4(dil.), C. H2SO4(conc.), HCl D. H2SO4(conc.), HNO3(dil.) E. HCl, HNO3(dil.) 12.22. What are the products of the reaction of gold dissolving in aqua regia (a mixture of hydrochloric and nitric acids): А. Au(NO3)3, AuCl3, H2O B. AuCl3, NO2, H2O C. H[AuCl4], NO2, H2O D. H2[AuOCl3], NO, H2O E. H[AuCl4], NO, H2O 12.23. What will be the product of reduction of diluted nitric acid HNO3 by zinc? А. NH4NO3 B. N2O C. NO D. N2 E. NO2 12.24. What will be one of the products of the reaction between zinc and diluted sulfuric acid? А. H2 B. H2S C. SO3 D. SO2 E. S 12.25. What will be the product of reduction of concentrated sulfuric acid H2SO4 by zinc? А. S or H2S B. SO2 or H2S C. H2 D. S E. SO2 or S 12.26. Which IIB group metals through the listed ones do not react with alkalis? А. Zn, Cd B. Cd, Hg C. Cd D. Zn, Hg E. Zn, Hg, Cd 12.27. What compounds (listed in pairs) have amphoteric properties? А. Cu(OH)2, Au(OH)3 B. Cu2O, Ag2O C. Au2O3, Ag2O D. Cu2O, Au(OH)3 E. Cu(OH)2, AuOH 12.28. The concentration of H+ ions in copper nitrate Cu(NO3)2 solution is 1·10–5 mol/l. What is the рН of this solution? А. 13 B. 1 C. 7 D. 5 E. 9 12.29. What products are forming under the hydrolysis of copper sulfate CuSO4? А. the salt does not hydrolyze B. acidic salt and basic salt C. basic salt and acid D. acidic salt and base E. base and acid 12.30. What product forms under the reaction between copper sulfate CuSO4 and the excess of potassium hydroxide KOH? А. K2[Cu(OH)4] B. [Cu(OH)2(H2O)2] C. the reaction does not occur D. [Cu(H2O)4](OH)2 E. K[Cu(OH)3] 12.31. What product forms under the reaction between copper sulfate CuSO4 and the excess of ammonium hydroxide NH4OH? А. [Cu(OH)2(NH3)2] B. [Cu(NH3)4]SO4 C. [Cu(NH3)2](OH)2 D. Cu(OH)2 E. [Cu(NH3)2(H2O)2]SO4 12.32. What reagent should be used for identification Cu2+ ions in solution? А. K2[HgI4] B. NaCl C. Na3[Ag(S2O3)2] D. NаOH(excess) E. NH4OH(excess) 12.33. What are the products of the reaction between silver nitrate AgNO3 and solution of sodium hydroxide NaOH? А. Ag2O, NaNO3, H2 B. Ag2O, NaNO3, H2O C. AgOH NaNO3 D. the reaction does not occur E. AgNO2, Na, H2O 12.34. Complete and balance the reaction of a coordination compound formation: D. AgBr + Na2S2O3(excess) → ... . Point out the sum of the coefficients in the equation. А. 8 B. 7 C. 5 D. 6 E. 4 E. 12.35. What products are forming in the reaction of an Ag(I) compound with formaldehyde (reaction of “silver mirror”): А. Ag, HCOOH B. Ag H2CO3 C. Ag2O, СН3OН D. Ag CO2, H2O E. Ag2CO3, H2O 12.36. What is the molecular formula of diammindithiocyanocopper (II)? А. [Cu(NH3)2(SCN)2] B. [Cu(NH3)2(CN)2] C. (NH4)2[Cu(SCN)4] D. [Cu(NH3)4](CN)2] E. (NH4)2[Cu(CN)4] 12.37. Which equation through the listed ones is the mathematical expression for the ionization constant of [Au(OH)Cl3]+ complex ion? А. [Au(OH)Cl 3 ] + Кн = [Au 3+ ] ⋅ [OH − ] ⋅ [Cl − ] 3 B. [ Au 3+ ] ⋅ [ Au( OH)Cl 3 ] + Кн = [OH − ] ⋅ [Cl − ] 3 C. [OH − ] ⋅ [Cl − ] 3 Кн = [ Au 3+ ] ⋅ [ Au(OH)Cl 3 ] + Кн = Кн = [Au 3+ ] ⋅ [OH − ] ⋅ [Cl − ] [Au(OH)Cl 3 ] + [Au 3+ ] ⋅ [OH − ] ⋅ [Cl − ]3 [Au(OH)Cl 3 ]+ 12.38. What will be the color of methyl orange indicator in the gold(III) chloride AuCl3 solution? А. blue B. yellow C. orange D. pink E. purple 12.39. What are the oxidation numbers of the central metal ions in the coordination compounds [Cu(NH3)4]SO4 and H[AuCl4], respectively? А. +3, +2 B. +2, +3 C. +3, +1 D. +1, +2 E. +2, +1 12.40. What coordination numbers are the most typical for Cu2+ as a central metal ion in coordination compounds? А. 6, 8 B. 4, 6 C. 2, 4 D. 4, 8 E. 2, 6 12.41. What ІІВ group elements have amphoteric properties? А. zinc and cadmium B. cadmium and mercury C. zinc only D. mercury only E. all elements 12.42. Which ion through the listed ones will form under the reaction of zinc dissolving in alkalis? А. ZnO22– B. [Zn(H2O)4]2+ C. [Zn(NH3)4]2+ D. [Zn(OH)4]2– E. [ZnCl4]2– 12.43. What are the products of the reaction between mercury(II) nitrate Hg(NO3)2 and solution of potassium hydroxide KOH? А. Hg+KNO3+H2O B. HgO+KNO3+H2O C. HgNO3+KNO2+H2O D. HgNO3+KNO3+H2O E. Hg+KNO2+H2O 12.44. What products are forming under the hydrolysis of zinc sulfate ZnSO4? А. base and acid B. acidic salt and base C. basic salt and acid D. acidic salt and basic salt E. the salt does not hydrolyze 12.45. What will be the color of methyl orange indicator in zinc sulfate ZnSO4 solution? А. purple B. colourless C. orange D. yellow E. pink 12.46. Mercury forms compounds in which it has oxidation numbers +1 or +2. In which of the listed compounds mercury has +2 oxidation state? А. Hg2Cl2 B. Hg2(NO3)2•2H2O C. Hg2O D. Hg2SO4 E. K2[HgI4] 12.47. What ion through the listed ones is the central ion in the coordination compound K2[HgI4]? А. K+ B. I– C. HgI42– D. Hg2+ E. K2[HgI4] 12.48. Complete and balance the equation of the reaction: AgNO3 + KOH → ... . Point out the sum of the coefficients in the equation. А. 9 B. 12 C. 6 D. 8 E. 11 12.49. Complete and balance the equation of the reaction: Hg(NO3)2 + NaOH → ... . Point out the sum of the coefficients in the equation. А. 12 B. 8 C. 6 D. 7 E. 9 12.50. Complete and balance the equation of the reaction: Hg2(NO3)2 + NaOH → ... . Point out the sum of the coefficients in the equation. А. 9 B. 12 C. 8 D. 11 E. 6 Chapter 13. d-Elements of IІВ Groups. Zinc, Cadmium, Mercury 13.1. Which of the listed electronic configurations corresponds to Cd2+ ion? А. [Kr]4d105s0 B. [Kr]4d105s1 C. [Kr]4d105s2 D. [Kr]4d85s2 E. [Kr]4d95s0 13.2. Which of the listed electronic configurations corresponds to Hg1+ ion? А. [Xe]4f145d106s1 B. [Xe]4f145d86s1 C. [Xe]4f145d106s1 D. [Xe]4f145d96s2 E. [Xe]4f145d106s0 13.3. What is the mass percentage of mercury in mercury (I) chloride (calomel)? А. 52% B. 48% C. 79% D. 91% E. 85% 13.4. What is the chemical formula of the natural mineral cinnabar? А. Hg2S2 B. ZnS C. HgS D. Hg2S E. CdS 13.5. What metal through the listed ones exists in a liquid state at STP: А. none of the listed metals B. cadmium C. mercury D. all listed metals E. zinc 13.6. What oxidation states are the most typical for cadmium: А. +3 B. +2, +3 C. +2 D. +1 E. +2, +1 13.7. What coordination numbers are common for zinc in coordination compounds? А. 4, 5 B. 2, 6 C. 3,6 D. 2, 4 E. 4, 6 13.8. What will be the product of reduction of diluted nitric acid HNO3 by zinc? А. NO2 B. N2O C. N2 D. NH4NO3 E. NO 13.9. What will be one of the products of the reaction between zinc and diluted sulfuric acid? А. SO2 B. S C. SO3 D. H2 E. H2S 13.10. What will be the product of reduction of concentrated sulfuric acid H2SO4 by zinc? А. SO2 or H2S B. S C. S or H2S D. SO2 or S E. H2 13.11. Which IIB group metals through the listed ones do not react with alkalis? А. Zn, Cd B. Zn, Hg, Cd C. Cd, Hg D. Cd E. Zn, Hg 13.12. What ІІВ group elements have amphoteric properties? А. zinc only B. cadmium and mercury C. mercury only D. zinc and cadmium E. all elements 13.13. Which ion through the listed ones will form under the reaction of zinc dissolving in alkalis? А. [Zn(H2O)4]2+ B. [Zn(NH3)4]2+ C. [ZnCl4]2– D. ZnO22– E. [Zn(OH)4]2– 13.14. What are the products of the reaction between mercury(II) nitrate Hg(NO3)2 and solution of potassium hydroxide KOH? А. HgNO3+KNO2+H2O B. C. D. E. HgNO3+KNO3+H2O Hg+KNO2+H2O HgO+KNO3+H2O Hg+KNO3+H2O 13.15. What products are forming under the hydrolysis of zinc sulfate ZnSO4? А. basic salt and acid B. acidic salt and basic salt C. acidic salt and base D. base and acid E. the salt does not hydrolyze 13.16. What will be the color of methyl orange indicator in zinc sulfate ZnSO4 solution? А. yellow B. orange C. colourless D. purple E. pink 13.17. Mercury forms compounds in which it has oxidation numbers +1 or +2. In which of the listed compounds mercury has +2 oxidation state? А. Hg2O B. Hg2SO4 C. Hg2Cl2 D. K2[HgI4] E. Hg2(NO3)2•2H2O 13.18. What ion through the listed ones is the central ion in the coordination compound K2[HgI4]? А. K+ B. Hg2+ C. I– D. K2[HgI4] E. HgI42– 13.19. Complete and balance the equation of the reaction: Hg(NO3)2 + NaOH → ... . Point out the sum of the coefficients in the equation. А. 7 B. 9 C. 6 D. 12 E. 8 Hg2(NO3)2 + NaOH → ... . Point out the sum of the coefficients in the equation. А. 8 B. 9 C. 12 D. 11 E. 6 13.20. Complete and balance the equation of the reaction: Chapter 14. d-Elements of VІВ Group. Chromium elements family 14.1. Which of the listed electronic configurations corresponds to Cr6+ ion? А. [Ar]3d04s1 B. [Ar]3d44s0 C. [Ar]3d54s0 D. [Ar]3d54s0 E. [Ar]3d04s0 14.2. Which of the listed electronic configurations corresponds to Cr3+ ion? А. [Ar]3d44s1 B. [Ar]3d54s0 C. [Ar]3d34s0 D. [Ar]3d54s1 E. [Ar]3d44s0 14.3. Which of the listed electronic configurations corresponds to Cr2+ ion? А. [Ar]3d34s0 B. [Ar]3d24s0 C. [Ar]3d44s0 D. [Ar]3d54s0 E. [Ar]3d44s1 14.4. Which of the listed electronic configurations corresponds to the atom of Chromium? А. [Ar]3d64s1 B. [Ar]3d44s2 C. [Ar]3d54s1 D. [Ar]3d44s1 E. [Ar]3d54s2 14.5. Which of the listed electronic configurations corresponds to Molybdenum atom? А. [Kr]3d54s2 B. [Kr]3d44s1 C. [Kr]3d54s1 D. [Kr]3d64s1 E. [Kr]3d44s2 14.6. Which of the listed electronic configurations corresponds to the atom of Tungsten? А. [Xe]4d55s1 B. C. D. E. [Xe]4d45s2 [Xe]4d45s1 [Xe]4d65s1 [Xe]4d55s2 14.7. Chromium can form stable compounds in which it has the following oxidation numbers: А. +1; +5; +6 B. +1; +2; +6 C. +2; +4; +6 D. +2; +3; +6 E. +2; +3; +4 14.8. What oxidation state is the most typical for Molybdenym? А. +6 B. +4 C. +5 D. +3 E. +2 14.9. What oxidation state is the most typical for Tungsten? А. +6 B. +3 C. +4 D. +5 E. +2 14.10. The reduction properties of the elements in the consequence of Cr–Mo–W will: А. the most typical for Mo B. increase from W to Cr C. increase D. do not change E. decrease 14.11. What are the products of the oxidation reaction of Cr and Mo by the oxygen of the air? А. Cr2O3, Mo2O3 B. CrO3, MoO3 C. Cr2O3, MoO3 D. CrO, Mo2O3 E. CrO, MoO3 14.12. What are the products of the oxidation reaction of Cr and W by the oxygen of the air? А. CrO, W2O3 B. CrO, WO3 C. Cr2O3, W2O3 D. Cr2O3, WO3 E. CrO3, WO3 14.13. Which one of the following metals may be prepared by the reduction its oxide with aluminium? А. Re B. Tc C. W D. Mo E. Cr 14.14. What compounds of Molybdenum should be reduced with hydrogen to get metallic Molybdenum? А. MoO3 or Na2MoO4 B. Mo2O3 or MoF6 C. MoO3 or MoF6 D. Mo2O3 or MoO3 E. Na2MoO4 or MoF6 14.15. What compounds of Tungsten should be reduced with hydrogen to get metallic Tungsten? А. Na2WO4 or WF6 B. WO3 or Na2WO4 C. WO3 or WF6 D. W2O3 or WF6 E. W2O3 or WO3 14.16. In which of the listed acids chromium dissolves at room temperature? А. HCl, H2SO4 B. HCl, H2SO4(conc.) C. HNO3 (conc.), H2SO4(conc.) D. HCl, HNO3 (conc.) E. HNO3, H2SO4(conc.) 14.17. Chromium can be dissolved in: А. HNO3 (dilut.) B. HNO3 C. H2SO4 (conc.) D. H2SO4 E. HNO3 (conc.) 14.18. What oxidation numbers does Chromium have in its compounds with Oxygen? А. +1; +2; +3; +6 B. +2; +3; +4; +6 C. +2; +3; +4; +5 D. +2; +3; +6 E. +3; +6 14.19. Specify, in what manner the acid-base properties of the compounds change in the following row CrO–Cr2O3– CrO3? А. acidic properties decrease B. basic properties increase C. acid-base properties do not change D. acidic properties increase E. – C. +2 D. +4 E. +3 14.22. Which compounds of Chromium through the listed ones have amphoteric properties? А. Cr2O3 and Cr(OH)3 B. CrO and Cr2O3 C. CrO and Cr(OH)3 D. CrO3 and Cr(OH)3 E. CrO and Cr(OH)2 14.23. Which compound of Chromium through the listed ones has amphoteric properties: А. CrO3 B. Cr2O3 C. K2CrO4 D. Cr(OH)2 E. CrO 14.24. What will be the products of the reaction between Na2S and CrCl3 solutions? А. Cr(OH)3, H2S and Na2Cl B. Cr(HS)3 and NaCl C. – D. Cr2S3 and NaCl E. CrS, S and NaCl 14.20. Which of the listed compounds of Chromium have basic properties only? А. CrO and Cr(OH)2 B. CrO and Cr2O3 C. Cr2O3 and Cr(OH)3 D. CrO and Cr(OH)3 E. CrO3 and Cr(OH)3 14.25. Which compounds of Chromium through the listed ones have acidic properties? А. CrO B. CrO2 C. CrO2 and CrO3 D. CrO3 E. Cr2O3 14.21. In what oxidation state should be the atom of Chromium in its compounds for they will be strong reducing agents? А. +6 B. +2 and +3 14.26. Which compound of Chromium through the listed ones can act as the oxidation agent only in redox reactions? А. Cr2(SO4)3 B. K2Cr2O7 C. CrCl2 D. FeSO4 E. KI 14.27. The chemical transformation of Cr3+ → Cr2O72– is the process of: А. reduction in basic solution B. reduction in acidic solution C. oxidation in acidic solution D. none E. oxidation in basic solution 14.28. The chemical transformation of Cr+3 → CrO42– is the process of: А. reduction in basic solution B. oxidation in acidic solution C. reduction in neutral solution D. oxidation in basic solution E. reduction in acidic solution 14.29. Complete and balance the equation of the reaction: K2CrO4 + H2SO4 → . . Point out the sum of the coefficients in the equation. А. 6 B. 5 C. 8 D. 7 E. 4 14.30. Complete and balance the equation of the reaction: K2Cr2O7 + KOH → . . Point out the sum of the coefficients in the equation. А. 4 B. 6 C. 5 D. 7 E. 8 Chapter 15. d-Elements of VІІВ Group. Manganese elements family 15.1. Which of the listed electronic configurations corresponds to Mn6+ ion? А. [Ar]3d04s1 B. [Ar]3d54s0 C. [Ar]3d54s0 D. [Ar]3d44s1 E. [Ar]3d04s2 15.2. Which of the listed electronic configurations corresponds to Mn4+ ion? А. [Ar]3d44s1 B. [Ar]3d44s0 C. [Ar]3d24s2 D. [Ar]3d14s2 E. [Ar]3d24s1 15.3. Which of the listed electronic configurations corresponds to Mn 7+ ion? А. [Ar]3d04s0 B. [Ar]3d54s0 C. [Ar]3d04s1 D. [Ar]3d44s0 E. [Ar]3d54s1 15.4. Which of the listed electronic configurations corresponds to Mn2+ ion? А. [Ar]3d24s1 B. [Ar]3d04s2 C. [Ar]3d44s1 D. [Ar]3d34s2 E. [Ar]3d54s0 15.5. Which of the listed electronic configurations corresponds to atom of Mn? А. [Ar]3d44s2 B. [Ar]3d64s1 C. [Ar]3d34s2 D. [Ar]3d54s2 E. [Ar]3d44s1 15.6. Which of the listed electronic configurations corresponds to atom of Technetium? А. [Kr]4d44s1 B. [Kr]4d44s2 C. [Kr]4d34s2 D. [Kr]4d64s1 E. [Kr]4d54s2 15.7. Which of the listed electronic configurations corresponds to atom of Rhenium? А. [Xe]5d65s1 B. [Xe]5d55s2 C. [Xe]5d55s1 D. [Xe]5d45s2 E. [Xe]5d45s1 15.8. Manganese forms a stable compounds in the following oxidation states: А. +2; +3; +4; +6; +7 B. +2; +3; +4 C. +1; +5; +6; +7 D. +2; +4; +5; +7 E. +1; +2; +6 15.9. What oxidation state is the most typical for Technetium? А. +2 B. +5 C. +7 D. +6 E. +4 15.10. What oxidation state is the most typical for Rhenium? А. +3 B. +6 C. +7 D. +4 E. +5 15.11. Point out in what oxidation state Manganese and Chlorine have similar chemical properties: А. +7 B. +2 C. +3 D. 0 E. +4 15.12. How does ionization energy change in the row Mn–Tc–Re? А. increases B. Increases from Re to Tc C. the least for Tc D. diminishes E. The greatest for Tc 15.13. In the electrochemical series of metals left-of-hydrogen is situated: А. Technetium B. Manganese and Technetium C. Rhenium D. Technetium and Rhenium E. Manganese 15.14. In the electrochemical series of metals right-of-hydrogen is situated: А. Manganese B. Manganese and Technetium C. Technetium and Rhenium D. Technetium E. Rhenium 15.15. Industrial method of manganese obtaining is reduction of: А. Mn2O3 B. MnO C. MnO3 D. MnO2 E. Mn2O7 15.16. Pure Rhenium is obtained by the reduction (with the help of hydrogen) of the compound: А. ReO B. KReO4 C. ReO2 D. ReO3 E. ReO2 або ReO3 15.17. What substances are used in industrial method of manganese obtaining as reducing agents? А. Si B. H2 або Si C. Si або C D. H2 або C E. H2 15.18. What substance is used in industrial method of Rhenium obtaining as reducing agent? А. H2 B. Si або C C. H2 або Si D. Si E. H2 або C 15.19. Coordination number of VIB group elements is: А. 6 B. 4 і 6 C. 2 D. 4 E. 2 і 4 15.20. When oxidized with oxygen Manganese forms: А. MnO B. MnO3 C. Mn2O3 D. Mn2O3 E. MnO2 15.21. Technetium and Rhenium are burnt down with the forming of: А. Tc2О3, Re2О7 B. Tc2О3, Re2О3 C. Tc2О7, Re2О7 D. TcО3, ReО3 E. Tc3О4, Re3О4 15.22. When Rhenium is dissolved in nitric acid it forms: А. Re2O7 B. ReO3 C. HReO4 D. Re(NO3)4 E. Re(NO3)2 15.23. When Manganese is dissolved in nitric acid it forms: А. MnO3 B. HMnO4 C. MnO2 D. Mn(NO3)2 E. Mn(NO3)4 15.24. Which of the Manganese compounds displays amphoteric properties? А. MnO B. MnO3 C. Mn2O3 D. Mn2O7 E. MnO2 15.25. Which of the Manganese compounds display basic properties? А. MnO і Mn2O3 B. Mn2O3 і MnO2 C. MnO2 і MnO3 D. MnO3 і Mn2O7 E. MnO2 15.26. Which of the Manganese compounds display acidic properties? А. Mn2O3 і MnO2 B. MnO і Mn2O3 C. MnO3 і Mn2O7 D. MnO2 і MnO3 E. MnO2 15.27. Changing of acid-basic properties in compounds MnO – MnO2 – Mn2O7 corresponds to such rule: А. acidic properties intensify B. acid-basic properties don’t change C. no answer is right D. acidic properties decreases E. basic properties intensify 15.28. Which of the listed Manganese compounds can undergo selfreduction self-oxidation reaction in solution? А. K2MnO4 B. KMnO4 C. MnCl2 D. Mn(NO3)2 E. MnO2 15.29. Which of the listed Manganese compounds can’t be isolated in free state? А. HMnO4 B. MnO C. H2MnO4 D. Mn2O3 E. MnO2 15.30. What Manganese compound is formed in the reaction of potassium permanganate reduction in basic solution? А. MnO2 B. Mn(OH)4 C. К2MnO4 D. MnO E. MnSO4 15.31. What Manganese compound is formed in the reaction of potassium permanganate reduction in acidic solution? А. Mn(OH)2 B. К2MnO4 C. MnO D. MnO2 E. MnSO4 15.32. What Manganese compound is formed in the reaction of potassium permanganate reduction in neutral solution? А. MnSO4 B. MnO2 C. MnO D. Mn(OH)2 E. К2MnO4 15.33. Which one of the listed compounds displays only oxidizing properties in redox processes? А. Mn2O3 B. K2MnO4 C. KMnO4 D. MnCl2 E. MnO2 15.34. According to standard redox potentials values find the reaction where Manganese is the strongest oxidizer: А. MnO2 + 4H+ + 2e– = Mn2+ + 2H2O; E0 = 1,28 V B. MnO4– + 4 H2O + 3e– = Mn(ОH)4 + 4OH– ; E0 = 0,57 V C. MnO4– + 8H+ + 5e– = Mn2+ + 4H2O; E0 = 1,51 V D. MnO4– + e– = MnO42– (alkali medium); Е0 = 0,54 V E. MnO42– + 4H2O + 2e– = Mn(OH)4 + 4OH– ; E0 = 0,71 V 15.35. What substance is obtained in the reaction of thermal decomposition of potassium permanganate? А. O2 B. KOH C. H2 D. H2O2 E. Mn(OH)2 А. Reduction in acidic solution B. Reduction in basic solution C. Reduction in neutral solution D. Oxidation in acidic solution E. Oxidation in basic solution 15.37. Complete equation of reaction and balance it the Mn + O2 → ... . Point out sum of the coefficients in the equation. А. 6 B. 4 C. 7 D. 5 E. 3 15.36. Explain the transformation MnO4– → MnO2 Chapter 16. d-Elements of VІІІВ Group. Cobalt and Nickel compounds. Platinum metals 16.1. Which of the listed electronic configurations corresponds to Fe3+ion А. [Ar] 3d5 4s1 4p1 B. [Ar] 3d5 4s0 C. [Ar] 3d3 4s2 D. [Ar] 3d3 4s1 4p1 E. [Ar] 3d4 4s1 16.2. What is the oxidization number of central ion in coordination compounds Na2[Fe(CN)5NO]? А. 0 B. +3 C. +2 D. +1 E. +6 16.3. Which of the listed electronic configurations corresponds to Fe atom? А. 3d84s2 B. 3d74s2 C. 3d54s1 D. 4d65s2 E. 3d64s2 16.4. Which of the listed electronic configurations corresponds to Co2+ ion? А. 3d74s0 B. 3d64s2 C. 4d75s2 D. 3d54s2 E. 3d74s2 16.5. Which of the listed electronic configurations corresponds to Ni atom? А. 3d64s2 B. 4d85s2 C. 3d74s2 D. 3d84s2 E. 3d84s0 16.9. What is the maximal oxidization number of Fe in its compounds? А. 2 B. 6 C. 8 D. 4 E. 3 16.10. Complete and balance the equation of the reaction: 0 16.6. Which of the following equations represents the process of corrosion of iron: А. 4Fe + 8H2O + 3O2 → 4Fe(OH)3 B. Fe + 2H2O → Fe(OH)2 C. 4Fe + 2H2O → 2Fe2O3 D. 2Fe + O2 → 2FeO E. 3Fe + 4H2O → Fe3O4 + 4H2 16.7. Complete and balance the equation of the reaction: Ni + CO t → Point out the sum of the coefficients in the equation. А. 6 B. 12 C. 8 D. 5 E. 9 16.11. Complete and balance the equation of the reaction: Fe(OH)3 + NaOH → K4[Fe(CN)6]+ Cl2 → Point out the sum of the coefficients in the equation. А. 10 B. 3 C. 5 D. 6 E. 4 Point out the sum of the coefficients in the equation. А. 7 B. 6 C. 5 D. 9 E. 11 16.8. Complete and balance the equation of the reaction: 16.12. Complete and balance the equation of the reaction: FeCl2 + K3[Fe(CN)6] → FeSO4 + KCN → Point out the sum of the coefficients in the equation. А. 6 B. 5 C. 9 D. 10 E. 12 Point out the sum of the coefficients in the equation. А. 15 B. 8 C. 9 D. 11 E. 6 16.13. Which one of the listed element has the following electronic configurations: 3d74s2? А. Rh B. Mn C. Ni D. Fe E. Co 16.14. A mineral cobalt glance or cobaltite has the following structure: А. CoS B. CoAs C. Co2O3 D. CoAsS E. CoO 16.15. The most stable complexes with amino carbonic acids form ions of: А. Mn, Mg, Zn B. Mn, Ni, Fe C. Cu, Zn, Co D. Fe, Mn, Mg E. Co, Fe, Zn 16.16. In which of the following reactions it is possible to get the iron(ІІІ) chloride: А. Fe(NO3) 3 + HCl→ B. Fe(OH)3 + HCl → C. Fe2O3 + Cl2 → D. Fe + HCl → E. Fe2(SO4) 3 + HCl → 16.17. An iron-stone - hematite has the following structure: А. FeO B. FeO(OH) C. Fe2O3 D. FeS2 E. Fe3O4 16.18. The products of igniting a pyrite are: А. Fe + SO3 B. Fe + SO2 C. Fe3O4 + SO2 D. FeO + SO2 E. Fe2O3 + SO2 16.19. Iron forms a carbide with metallic conductivity, which has the following composition: А. FeC3 B. FeC C. Fe3C4 D. Fe2C E. Fe3C 16.20. An iron-stone - magnetite has the following structure: А. FeO B. Fe3O4 C. FeS2 D. FeO(OH) E. Fe2O3 16.21. Which compounds can form iron(ІІІ) hydroxide as a product of reaction? А. Fe2O3 + H2O B. Fe + NaOH C. Fe2O3 and NaOH D. FeCl3 and NaOH E. FeCl3 + H2O 16.22. Pyrite is: А. Fe2O3 B. FeSO4⋅7H2O C. Fe3O4 D. FeS2 E. FeS 16.23. Which of the listed acid dissolves iron at a room temperature and forms the salts of Fe(III) А. HNO3 diluted B. H2SO4 diluted C. HCl D. HNO3 conc E. H2SO4 conc 16.24. For analytical determination of the Fe2+ ions red prussiate of potash salt is used. Its formula: А. K4[Fe(CN)6] B. K4[Fe(OH)6] C. KFe[Fe(CN)6] D. K3[Fe(CN)6] E. K4[Fe(CNS) 6] 16.25. Which one of the given compounds is used as a reagent on the ions of iron (ІІІ)? А. K3[Fe(CN)6] and NH4CNS B. K3[Fe(CN)6] and KCNS C. KFe[Fe(CN)6] and NH4CNS D. KCNS and HNO3 E. K4[Fe(CN)6] and KCNS 16.26. Co can force other metals out of solutions of salts: А. CaCl2 B. NiSO4 C. Zn(NO3)2 D. KNO3 E. AlCl3 16.27. The expression of the solubility product constant Ksp for Co(OH)2: А. Ksp= [ Co2+]⋅[OH–]2 B. Ksp= [Co2+]⋅[OH–] C. Ksp= Co2+]+2[OH–] D. Ksp= [Co2+]⋅2[OH–] E. Ksp= [Co]⋅[OH]2 16.28. The expression of the solubility product constant Ksp for Fe(OH)2: А. Ksp= [Fe2+]+2[OH–] B. Ksp= [Fe]⋅[OH]2 C. Ksp= [Fe2+]⋅2[OH–] D. Ksp= [Fe2+]⋅[OH–] E. Ksp= [Fe2+]⋅[OH–]2 16.29. The expression of the solubility product constant Ksp for the salt Fe2S3: А. Ksp= 2[Fe3+]⋅3[S2–] B. Ksp= [Fe3+]3⋅[S2–]2 C. Ksp= [Fe]2⋅[S]3 D. Ksp= [Fe3+]⋅[S2–] E. Ksp= [Fe3+]2⋅[S2–]3 16.30. The expression of the solubility product constant Ksp for Ni(OH)2: А. Ksp= [Ni2+]⋅[OH–] B. Ksp= [Ni]⋅[OH]2 C. Ksp=[Ni2+]⋅[OH–]2 D. Ksp= [Ni2+]+2[OH–] E. Ksp= [Ni2+]⋅2[OH–] 16.31. The red prussiate of potash K3[Fe(CN)6] is a reagent on: А. FeO2– ions B. Fe3+ ions C. Ca2+ ions D. Fe2+ ions E. FeO42– ions 16.32. The yellow prussiate of potash K4[Fe(CN)6] is a reagent on: А. Fe2+ ions B. Fe3+ ions C. Ca2+ ions D. FeO42– ions E. FeO2– ions 16.33. What is the medium of solution of the salt FeCl2? А. acidic B. weak acidic C. neutral D. weak alkaline E. alkaline 16.34. What is the medium of solution of the salt CoCl2? А. acidic B. weak alkaline C. alkaline D. neutral E. weak acidic E. Kd = [Co 2+ ] ⋅ [ NH 3 ]6 ⋅ [Cl − ] 2 [[Co( NH 3 ) 6 ]Cl 2 ] 16.35. What is the medium of solution of the Ni(NO3)2 salt? А. alkaline B. weak acidic C. neutral D. acidic E. weak alkaline 16.36. Expression of dissociation constant Kd of complex ion K4[Fe(CN)6]: А. Kd = [Fe 2+ ] ⋅ [CN − ] 6 [[Fe(CN) 6 ] 4− ] + 4 4− B. K = [K ] ⋅ [[Fe(CN) 6 ] ] d [[Fe(CN) 6 ] 4− ] 2+ − C. Kd = [Fe ] ⋅ 6[CN ] [[Fe(CN) 6 ] 4− ] D. K = [[ Fe(CN ) 6 ]4− ] d [[ Fe(CN ) 6 ] 4− ] E. Kd = [ K + ]4 + [[ Fe(CN ) 6 ]4− ] [[ Fe(CN ) 6 ] 4− ] 16.37. Expression of dissociation constant Kd of complex ion [Со(NН3)6]Cl2: А. K = [Co 2+ ] + [ NH 3 ] 6 d B. Kd = [[Co( NH 3 ) 6 ] 2+ ] [Co 2+ ] ⋅ [ NH 3 ] 6 [[Co( NH 3 ) 6 ] 2+ ] C. K = [[Co( NH 3 ) 6 ] 2+ ] ⋅ [Cl − ] 2 d [[Co ( NH 3 ) 6 ]Cl 2 ] D. 2+ Kd = [Co ] ⋅ 6[ NH 3 ] [[Co( NH 3 ) 6 ] 2+ ] 16.38. The Mor salt is: А. basic salt B. complex salt C. double salt D. acidic salt E. middle salt 16.39. Fe(OH)3 has the amphoteric properties because: А. reacts only with acids B. C. reacts only with bases D. reacts with acids and bases E. decomposes at heating 16.40. The hydrolysis of what salt is described by ionic equation: Fe2+ + H2O ⇄ FeOH+ + H+? А. Fe sulfide B. Fe sulfate C. Fe sulfite D. E. Fe acetate 16.41. Iron reacts with hydrochloric acid and forms the salt: А. FeOHCl2 B. FeCl3 C. Fe(OH)2Cl D. FeOHCl E. FeCl2 16.42. The hydrolysis of what salt is described by ionic equation: Ni2+ + H2O ⇄ NiOH+ + H+? А. Ni nitrite B. C. Ni chloride D. Ni sulfide E. Ni acetate 16.43. The color of litmus in the solution FeCl2: А. red B. violet C. colourless D. raspberry E. dark blue Chapter 17. d-Elements of VІІІВ Group. Iron and its compounds 17.1. The Mor salt is: А. middle salt B. basic salt C. double salt D. acidic salt E. complex salt 17.2. Fe(OH)3 has the amphoteric properties because: А. decomposes at heating B. C. reacts with acids and bases D. reacts only with acids E. reacts only with bases 17.3. The hydrolysis of what salt is described by ionic equation: Fe2+ + H2O ⇄ FeOH+ + H+? А. B. Fe acetate C. Fe sulfite D. Fe sulfide E. Fe sulfate 17.4. Iron reacts with hydrochloric acid and forms the salt: А. FeOHCl B. FeCl3 C. FeOHCl2 D. Fe(OH)2Cl E. FeCl2 17.5. The hydrolysis of what salt is described by ionic equation: Ni2+ + H2O ⇄ NiOH+ + H+? А. Ni chloride B. Ni acetate C. Ni nitrite D. Ni sulfide E. 17.6. The color of litmus in the solution FeCl2: А. red B. dark blue C. colourless D. raspberry E. violet 17.7. Expression of dissociation constant Kd of complex ion K4[Fe(CN)6]: А. Kd = [Fe 2+ ] ⋅ 6[CN − ] [[Fe(CN) 6 ] 4− ] B. Kd = [ K + ]4 + [[ Fe(CN ) 6 ]4− ] [[ Fe(CN ) 6 ]4 − ] C. Kd = [[Fe(CN ) 6 ]4 − ] [[Fe(CN ) 6 ]4 − ] D. Kd = [Fe 2 + ] ⋅ [CN − ] 6 [[Fe(CN) 6 ] 4− ] E. Kd = [K + ] 4 ⋅ [[Fe(CN) 6 ] 4− ] 4− [[Fe(CN) 6 ] ] 17.8. The red prussiate of potash K3[Fe(CN)6] is a reagent on: А. FeO42– ions B. FeO2– ions C. Fe2+ ions D. Ca2+ ions E. Fe3+ ions 17.9. The yellow prussiate of potash K4[Fe(CN)6] is a reagent on: А. FeO42– ions B. Fe3+ ions C. Ca2+ ions D. FeO2– ions E. Fe2+ ions 17.10. What is the medium of solution of the salt FeCl2? А. weak acidic B. acidic C. alkaline D. neutral E. weak alkaline 17.11. The red prussiate of potash K3[Fe(CN)6] is a reagent on: А. Fe3+ ions B. FeO42– ions C. Fe2+ ions D. FeO2– ions E. Ca2+ ions 17.12. The expression of the solubility product constant Ksp for Fe(OH)2: А. Ksp= [Fe2+]⋅2[OH–] B. Ksp= [Fe2+]+2[OH–] C. Ksp= [Fe]⋅[OH]2 D. Ksp= [Fe2+]⋅[OH–]2 E. Ksp= [Fe2+]⋅[OH–] 17.13. The expression of the solubility product constant Ksp for the salt Fe2S3: А. Ksp= [Fe3+]3⋅[S2–]2 B. Ksp= [Fe3+]⋅[S2–] C. Ksp= [Fe]2⋅[S]3 D. Ksp= [Fe3+]2⋅[S2–]3 E. Ksp= 2[Fe3+]⋅3[S2–] 17.14. In which of the following reactions it is possible to get the iron(ІІІ) chloride: А. Fe(OH)3 + HCl → B. Fe(NO3) 3 + HCl→ C. Fe2O3 + Cl2 → D. Fe2(SO4) 3 + HCl → E. Fe + HCl → 17.15. An iron-stone - hematite has the following structure: А. FeO B. FeO(OH) C. Fe3O4 D. FeS2 E. Fe2O3 17.16. The products of igniting a pyrite are: А. FeO + SO2 B. Fe3O4 + SO2 C. Fe + SO2 D. Fe2O3 + SO2 E. Fe + SO3 17.17. Iron forms a carbide with metallic conductivity, which has the following composition: А. Fe3C4 B. FeC3 C. Fe2C D. Fe3C E. FeC 17.18. An iron-stone - magnetite has the following structure: А. FeS2 B. Fe3O4 C. FeO(OH) D. FeO E. Fe2O3 17.19. Which compounds can form iron(ІІІ) hydroxide as a product of reaction? А. Fe + NaOH B. Fe2O3 and NaOH C. FeCl3 and NaOH D. Fe2O3 + H2O E. FeCl3 + H2O 17.20. Pyrite is: А. Fe3O4 B. Fe2O3 C. FeS D. FeS2 E. FeSO4⋅7H2O 17.21. Which of the listed electronic configurations corresponds to Fe3+ion А. [Ar] 3d5 4s0 B. [Ar] 3d3 4s2 C. [Ar] 3d5 4s1 4p1 D. [Ar] 3d3 4s1 4p1 E. [Ar] 3d4 4s1 17.22. What is the oxidization number of central ion in coordination compounds Na2[Fe(CN)5NO]? А. +1 B. 0 C. +2 D. +3 E. +6 17.23. Which of the listed electronic configurations corresponds to Fe atom? А. 3d54s1 B. 4d65s2 C. 3d74s2 D. 3d84s2 E. 3d64s2 17.24. Which of the following equations represents the process of corrosion of iron: А. 4Fe + 8H2O + 3O2 → 4Fe(OH)3 B. 3Fe + 4H2O → Fe3O4 + 4H2 C. Fe + 2H2O → Fe(OH)2 D. 4Fe + 2H2O → 2Fe2O3 E. 2Fe + O2 → 2FeO 17.25. Complete and balance the equation of the reaction: Fe(OH)3 + NaOH → Point out the sum of the coefficients in the equation. А. 10 B. 6 C. 4 D. 3 E. 5 17.26. Complete and balance the equation of the reaction: FeCl2 + K3[Fe(CN)6] → Point out the sum of the coefficients in the equation. А. 5 B. 10 C. 9 D. 6 E. 12 17.27. What is the maximal oxidization number of Fe in its compounds? А. 3 B. 6 C. 8 D. 4 E. 2 1.1. 1.2. 1.3. 1.4. 1.5. 1.6. 1.7. 1.8. 1.9. 1.10. 1.11. 1.12. 1.13. 1.14. 1.15. 1.16. 1.17. 1.18. 1.19. 1.20. 1.21. 1.22. 1.23. 1.24. 1.25. 1.26. 1.27. 1.28. 1.29. 1.30. 1.31. 1.32. 1.33. 1.34. 1.35. 1.36. 1.37. 1.38. 1.39. 2.1. 2.2. D B B B D B B C E C E A E A C D C B C B D E E B C A C B B E E B A A D C B E A A B 2.3. 2.4. 2.5. 2.6. 2.7. 2.8. 2.9. 2.10. 2.11. 2.12. 2.13. 2.14. 2.15. 2.16. 2.17. 2.18. 2.19. 2.20. 2.21. 2.22. 2.23. 2.24. 2.25. 2.26. 2.27. 2.28. 2.29. 2.30. 2.31. 2.32. 2.33. 2.34. 2.35. 2.36. 2.37. 2.38. 2.39. 2.40. 2.41. 2.42. 2.43. E E A D E D E D E B B A C E B D E E E D D A B C B C C D E D D D C E A C B C B D D 2.44. 2.45. 2.46. 2.47. 2.48. 2.49. 2.50. 2.51. 2.52. 2.53. 2.54. 2.55. 2.56. 2.57. 2.58. 2.59. 3.1. 3.2. 3.3. 3.4. 3.5. 3.6. 3.7. 3.8. 3.9. 3.10. 3.11. 3.12. 3.13. 3.14. 3.15. 3.16. 3.17. 3.18. 3.19. 3.20. 3.21. 3.22. 3.23. 3.24. 3.25. C A B B D D E C D B B D C D B A B B B A E E B D D A E B B A A D A E D E E B A A B 3.26. 3.27. 3.28. 3.29. 3.30. 3.31. 3.32. 3.33. 3.34. 3.35. 3.36. 3.37. 3.38. 3.39. 3.40. 3.41. 3.42. 3.43. 3.44. 3.45. 3.46. 3.47. 3.48. 3.49. 3.50. 3.51. 3.52. 3.53. 3.54. 3.55. 3.56. 3.57. 3.58. 3.59. 3.60. 3.61. 3.62. 3.63. 3.64. 3.65. 3.66. A A C C A A C D C C B B D A C B A E C C B A B B E C D D C C B B A E B C A E B B C 3.67. 3.68. 3.69. 3.70. 3.71. 3.72. 3.73. 3.74. 3.75. 3.76. 3.77. 3.78. 3.79. 3.80. 4.1. 4.2. 4.3. 4.4. 4.5. 4.6. 4.7. 4.8. 4.9. 4.10. 4.11. 4.12. 4.13. 4.14. 4.15. 4.16. 4.17. 4.18. 4.19. 4.20. 4.21. 4.22. 4.23. 4.24. 4.25. 4.26. 4.27. E C B A E D D D D A E E E A D A D D E E A E D B A A A E D A B B E E D E B B B D C 4.28. 4.29. 4.30. 4.31. 4.32. 4.33. 4.34. 4.35. 4.36. 4.37. 4.38. 4.39. 4.40. 4.41. 4.42. 4.43. 5.1. 5.2. 5.3. 5.4. 5.5. 5.6. 5.7. 5.8. 5.9. 5.10. 5.11. 5.12. 5.13. 5.14. 5.15. 5.16. 5.17. 5.18. 5.19. 5.20. 5.21. 5.22. 5.23. 5.24. 5.25. C A C B D E E D D E E A C B C B B E B B D B E C E D D C B A B B E C B D B D D A C 5.26. 5.27. 5.28. 5.29. 5.30. 5.31. 5.32. 5.33. 5.34. 5.35. 5.36. 5.37. 5.38. 5.39. 5.40. 5.41. 5.42. 6.1. 6.2. 6.3. 6.4. 6.5. 6.6. 6.7. 6.8. 6.9. 6.10. 6.11. 6.12. 6.13. 6.14. 6.15. 6.16. 6.17. 6.18. 6.19. 6.20. 6.21. 6.22. 6.23. 6.24. 6.25. 6.26. 6.27. E C B E B B C A E B C E C E D C C E A A E B E C E A E E B D B B D D D D D B B A B E E C 7.1. 7.2. 7.3. 7.4. 7.5. 7.6. 7.7. 7.8. 7.9. 7.10. 7.11. 7.12. 7.13. 7.14. 7.15. 7.16. 7.17. 7.18. 7.19. 7.20. 7.21. 7.22. 7.23. 7.24. 7.25. 7.26. 7.27. 7.28. 7.29. 7.30. 8.1. 8.2. 8.3. 8.4. 8.5. 8.6. 8.7. 8.8. 8.9. 8.10. 8.11. 8.12. 8.13. 8.14. B D B A E B C D D A C A A E B A E D D B E B B C E B E A C A D B C A A D B B C E E C C B 8.15. 8.16. 8.17. 8.18. 8.19. 8.20. 8.21. 8.22. 8.23. 8.24. 8.25. 8.26. 8.27. 8.28. 8.29. 8.30. 8.31. 8.32. 8.33. 8.34. 8.35. 8.36. 8.37. 8.38. 9.1. 9.2. 9.3. 9.4. 9.5. 9.6. 9.7. 9.8. 9.9. 9.10. 9.11. 9.12. 9.13. 9.14. 9.15. 9.16. 9.17. 9.18. 9.19. 10.1. E A C D A B D B A E D A D A B D A A E C D A A C A A B D B E B C C D A B B E B C C C A D 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 10.8. 10.9. 10.10. 10.11. 10.12. 10.13. 10.14. 10.15. 10.16. 10.17. 10.18. 10.19. 10.20. 10.21. 10.22. 10.23. 10.24. 10.25. 10.26. 10.27. 10.28. 10.29. 10.30. 10.31. 10.32. 10.33. 10.34. 10.35. 10.36. 10.37. 10.38. 10.39. 10.40. 10.41. 10.42. 10.43. 10.44. 10.45. D A E E D C A C B B D E E A E D B B D E E E A B A B A D E D A C E D E E E A C D E C B B 10.46. 11.1. 11.2. 11.3. 11.4. 11.5. 11.6. 11.7. 11.8. 11.9. 11.10. 11.11. 11.12. 11.13. 11.14. 11.15. 11.16. 11.17. 11.18. 11.19. 11.20. 11.21. 11.22. 11.23. 11.24. 11.25. 11.26. 11.27. 11.28. 11.29. 11.30. 11.31. 11.32. 11.33. 11.34. 11.35. 11.36. 11.37. 11.38. 11.39. 11.40. 11.41. 12.1. 12.2. A C C C D D E D A E A A E E D E B C E A A C D B D E D B B A D E D E C B B B B C B A E A 12.3. 12.4. 12.5. 12.6. 12.7. 12.8. 12.9. 12.10. 12.11. 12.12. 12.13. 12.14. 12.15. 12.16. 12.17. 12.18. 12.19. 12.20. 12.21. 12.22. 12.23. 12.24. 12.25. 12.26. 12.27. 12.28. 12.29. 12.30. 12.31. 12.32. 12.33. 12.34. 12.35. 12.36. 12.37. 12.38. 12.39. 12.40. 12.41. 12.42. 12.43. 12.44. 12.45. 12.46. A B A A D A C A C D D D B D B B C D D E A A B B A D C A C E B C A A E D B B C D B C E E 12.47. 12.48. 12.49. 12.50. 13.1. 13.2. 13.3. 13.4. 13.5. 13.6. 13.7. 13.8. 13.9. 13.10. 13.11. 13.12. 13.13. 13.14. 13.15. 13.16. 13.17. 13.18. 13.19. 13.20. 14.1. 14.2. 14.3. D D D C A A E C C C E D D A C A E D A E D B A A E C C 14.4. 14.5. 14.6. 14.7. 14.8. 14.9. 14.10. 14.11. 14.12. 14.13. 14.14. 14.15. 14.16. 14.17. 14.18. 14.19. 14.20. 14.21. 14.22. 14.23. 14.24. 14.25. 14.26. 14.27. 14.28. 14.29. 14.30. C C B D A A E C D E C C A D B D A C A B A D B C D A B 15.1. 15.2. 15.3. 15.4. 15.5. 15.6. 15.7. 15.8. 15.9. 15.10. 15.11. 15.12. 15.13. 15.14. 15.15. 15.16. 15.17. 15.18. 15.19. 15.20. 15.21. 15.22. 15.23. 15.24. 15.25. 15.26. 15.27. A D A D D E B A C C A C E C D B C A B E C C D E A C A 15.28. 15.29. 15.30. 15.31. 15.32. 15.33. 15.34. 15.35. 15.36. 15.37. 16.1. 16.2. 16.3. 16.4. 16.5. 16.6. 16.7. 16.8. 16.9. 16.10. 16.11. 16.12. 16.13. 16.14. 16.15. 16.16. 16.17. A C C E B C C A C E B B E A D A C B B A A C E D C B C 16.18. 16.19. 16.20. 16.21. 16.22. 16.23. 16.24. 16.25. 16.26. 16.27. 16.28. 16.29. 16.30. 16.31. 16.32. 16.33. 16.34. 16.35. 16.36. 16.37. 16.38. 16.39. 16.40. 16.41. 16.42. 16.43. 17.1. E E B D D A D E B A E E C D B A A D A B C D B E C A C 17.2. 17.3. 17.4. 17.5. 17.6. 17.7. 17.8. 17.9. 17.10. 17.11. 17.12. 17.13. 17.14. 17.15. 17.16. 17.17. 17.18. 17.19. 17.20. 17.21. 17.22. 17.23. 17.24. 17.25. 17.26. 17.27. C E E A A D C B B C D D A E D D B C D A D E A E A B CONTENTS Chapter 1. General characteristic of s-elements. Hydrogen and its compounds .......... 2 Chapter 2. s-Elements of the І group of the Periodic Table. Alkali metals ................. 6 Chapter 3. s-Elements of the ІІ groups of the Periodic Table. Beryllium, Magnesium, and Alkaline earth metals .................................................... 11 Chapter 4. General characteristic of p-Elements. Boron and Alluminium ................ 19 Chapter 5. р-Elements of IVА Group. Carbon, Silicon ............................................ 24 Chapter 6. р-Elements of IVА Group. Germanium family elements (Germanium, Tin, and Lead) ................................................................... 28 Chapter 7. р-Elements of VА Group. Nitrogen and its compounds in the negative oxidation states .......................................................................... 31 Chapter 8. р-Elements of VА Group. Nitrogen and its compounds in the positive oxidation states ........................................................................... 34 Chapter 9. р-Elements of VА Group. Phosphorus and its compounds ...................... 38 Chapter 10. р-Elements of VА Group. Arsenic family elements (Arsenic, Antimony, and Bismuth) ......................................................................... 40 Chapter 11. р-Elements of VІІА Group. Halogens.................................................... 45 Chapter 12. General characteristic of d-Elements. d-Elements of IВ Group. Copper, Silver, Gold ................................................................................ 50 Chapter 13. d-Elements of IІВ Groups. Zinc, Cadmium, Mercury............................ 56 Chapter 14. d-Elements of VІВ Group. Chromium elements family ........................ 58 Chapter 15. d-Elements of VІІВ Group. Manganese elements family ...................... 61 Chapter 16. d-Elements of VІІІВ Group. Cobalt and Nickel compounds. Platinum metals ....................................................................................... 65 Chapter 17. d-Elements of VІІІВ Group. Iron and its compounds ............................ 70