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PETROLOGY OF SEDIMENTARY ROCKS Dr. Sugeng S Surjono Lab. Sedimentografi Jurusan Teknik Geologi, Fakultas Teknik Universitas Gadjah Mada GED 2008 GED 2008 INTRODUCTION Three Rock Types: Igneous, Sedimentary, Metamorphic rocks Sedimentary rocks : rocks formed at the surface of the earth under lowtemperature and low-pressure, result from the accumulation and solidification of sediments, material transported in water, air or ice (Raymond, 1995). Origin of sedimentary rocks: - Formation of source rocks/sediment source : intrusion, metamorphism, volcanism, tectonic uplift - Weathering : physical and chemical breakdown of source rocks - Erosion and Transportation agent of transportation : water, wind, ice - Deposition material is deposited within depositional basins - Diagenesis sediment is covered by successive layer of younger sediment; increased temperature and pressure leading to consolidation and lithification of the sediment into sedimentary rocks GED 2008 INTRODUCTION Sedimentary rocks are characterized by : -Presence of layers -Presence of transported grains -Sedimentary structures -Fossils Types of Sedimentary Rocks: (Tucker, 1991) Siliciclastic (fragmental) : - Conglomerates & breccias - Sandstones - Mudrocks Biogenic, biochemical and organic : - limestones & dolomites - cherts - phosphates - coal - oil shale Chemical : - evaporites - ironstones Volcaniclastic : (e.g.) ignimbrites, tuffs, hyaloclastites GED 2008 GED 2008 Sedimentary rocks • • • • Clastic (siliciclastic) rocks (80-85% of the stratigraphic record) Carbonate sediments and rocks (10-15% of the stratigraphic record) Volcaniclastic sediments and rocks Others (< 5% of the stratigraphic record) : - Organic (carbonaceous) sediments and rocks Evaporites GED 2008 SILICICLASTIC SEDIMENTARY ROCKS Clast (from the Greek klastos, meaning ‘broken’) is the technical term for broken fragment within sedimentary rocks. It is also called as terrigenous grains Because most terrigenous grains are composed in part of silica, they are often referred to as siliciclastic grains. Siliciclastic sedimentary rocks are composed by clasts that originated from transportation and deposition of pre-existing rocks within depositional environments. Mechanism involved in the transportation include the wind, glaciers, river currents, waves, tidal currents, debris flow and turbidity currents (Tucker, 1991). Two important features of siliciclastic sediments related to depositional processes and diagenesis are sedimentary textures and structures. DESCRIPTION OF SEDIMENTARY ROCKS (Prothero & Schwab, 2005): -Color -Sedimentary textures -Sedimentary structures -Composition -Fossil contents -Geometry of sedimentary rocks GED 2008 Basic components of siliciclastic sedimentary rock are : -clasts or fragments -matrix -cements Color -Color usually reflects some aspect of the rock’s composition (bulk color can reflect the color of major mineralogical components) -Color of rock controlled by color of clast, matrix and cement -Color is not treated as an independent property, however, but as an aspect of sedimentary rock composition GED 2008 Sedimentary textures Textures refers to the size, morphology, and arrangement (fabric) of siliciclastic grains that make up a sedimentary rock. Grain size -Grain or siliciclastic particles range in size from clay to boulder -The grade scale most widely used by sedimentologist is the Udden-Wenthworth scale -The Udden-Wentworth grain-size scale is based on factors of two: = -log2 d ; where d is grain size in mm - It extends from <1/256 mm (0.0039) to >256 mm and is divided into four major size categories (clay, silt, sand, and gravel) that can be further subdivided GED 2008 Mud Udden-Wenthworth grain-size scale for sediments and the equivalent phi scale GED 2008 Grain size parameters : mean, sorting, skewness, kurtosis • Grain-size (particle-size, granulometric) analysis • • The old-fashioned way: direct measurement (gravel) and sieve/pipette analysis (sand and mud) The modern technology: laser particle sizing (sand and mud) GED 2008 Grain size parameters Graphical method Graphic Mean Standard deviation Skewness Kurtosis (Mz) = (σ1) = 16 50 84 3 84 16 4 95 5 + (SK1) = 84 16 2 50 2( 84 16) (KG) = 6,6 + 95 5 2 50 2( 95 5) 95 5 2,44( 75 25) GED 2008 Grain size parameters Moment measures (mathematic method) • First moment: mean (cf. median, mode) • Premier measure of the grain size xø= • fm N Second moment: variance (cf. standard deviation) • Measure of the degree of sorting σø = f (m X ) ( = standard deviation) 2 100 • Third moment : Skewness - Measure of the symmetry of the grain-size distribution Skø = f (m X ) 3 100 3 • Fourth moment : Kurtosis - Measure of the sharpness or peakedness of a grain-size frequency curve f (m X ) 4 Kø = 100 4 GED 2008 GED 2008 SK1 class : +1,0 - +0,3 +0,3 - +0,1 +0,1 - -0,1 -0,1 - -0,3 -0,3 - -1,0 very fine-skewed fine-skewed near-symmetrical coarse-skewed very coarse-skewed KG class: <0,67 very platykutic 0,67 – 0,90 platykurtic 0,90 – 1,11 mesokurtic 1,11 – 1,50 leptokurtic 1,50 – 3,00 very leptokurtic >3,00 extremely leptokurtic GED 2008 GED 2008 GED 2008 GED 2008 GED 2008 Grain Morphology Three aspects of grain morphology are the shape, sphericity and roundness. • The shape or form of grain is measured by various ratios of the long, intermediate and short axes. • Sphericity is a measure of how closely the grain shape approaches that of a sphere. • Roundness is concerned with the curvature of the corners of a grain and six classes from very angular to well rounded. GED 2008 Grain shape classification Roundness and Sphericity GED 2008 GED 2008 Grain Fabric Fabric for grain in sedimentary rock refers to their orientation and packing and to the nature of contacts between them. • Grain Packing is a function of the size and shape of grains and postdepositional physical and chemical processes that bring about compaction of sediment. • Grain orientation is mainly a function of the physical processes and condition operating at the time of deposition GED 2008 GED 2008 Sedimentary structures • Sedimentary structures occur at very different scales, from less than a mm (thin section) to 100s–1000s of meters (large outcrops); most attention is traditionally focused on the bedform-scale : Microforms (e.g., ripples) ;Mesoforms (e.g., dunes); Macroforms (e.g., bars) The majority of structures form by physical processes, before, during and after sedimentation. Other result from organic and chemical processes GED 2008 GED 2008 • • • Laminae and beds are the basic sedimentary units that produce stratification; the transition between the two is arbitrarily set at 10 mm Normal grading is an upward decreasing grain size within a single lamina or bed (associated with a decrease in flow velocity), as opposed to reverse grading Fining-upward successions and coarsening-upward successions are the products of vertically stacked individual beds GED 2008 Cross stratification • • • • Cross lamination (small-scale cross stratification) is produced by ripples Cross bedding (large-scale cross stratification) is produced by dunes Cross-stratified deposits can only be preserved when a bedform is not entirely eroded by the subsequent bedform (i.e., sediment input > sediment output) Straight-crested bedforms lead to planar cross stratification; sinuous or linguoid bedforms produce trough cross stratification GED 2008 GED 2008 Low angle planar cross-bedding, Kali Ngalang-Gunung Kidul, YK GED 2008 GED 2008 Cross stratification • • • The angle of climb of cross-stratified deposits increases with deposition rate, resulting in ‘climbing ripple cross lamination’ Antidunes form cross strata that dip upstream, but these are not commonly preserved A single unit of cross-stratified material is known as a set; a succession of sets forms a co-set Planar stratification • • Planar lamination (or planar bedding) is formed under both lowerstage and upper-stage flow conditions Planar stratification can easily be confused with planar cross stratification, depending on the orientation of a section (strike sections!) GED 2008 GED 2008 • • • Cross stratification produced by wave ripples can be distinguished from current ripples by their symmetry and by laminae dipping in two directions Hummocky cross stratification (HCS) forms during storm events with combined wave and current activity in shallow seas (below the fair-weather wave base), and is the result of aggradation of mounds and swales Heterolithic stratification is characterized by alternating sand and mud laminae or beds • • Flaser bedding is dominated by sand with isolated, thin mud drapes Lenticular bedding is mud-dominated with isolated ripples GED 2008 GED 2008 Gravity-flow deposits • • Debris-flow deposits are typically poorly sorted, matrixsupported sediments with random clast orientation and no sedimentary structures; thickness and grain size commonly remain unchanged in a proximal to distal direction Turbidites, the deposits formed by turbidity currents, are typically normally graded, ideally composed of five units (Bouma-sequence with divisions ‘a’-‘e’), reflecting decreasing flow velocities and associated bedforms GED 2008 GED 2008 GED 2008 GED 2008 • Imbrication commonly occurs in water-lain gravels and conglomerates, and is characterized by discoid (flat) clasts consistently dipping upstream • Sole marks are erosional sedimentary structures on a bed surface that have been preserved by subsequent burial • • • Scour marks (caused by erosive turbulence) Tool marks (caused by imprints of objects) Paleocurrent measurements can be based on any sedimentary structure indicating a current direction (e.g., cross stratification, imbrication, flute casts) GED 2008 GED 2008 • • • • Trace fossils (ichnofossils) are the tracks, trails or burrows left behind in sediments by organisms (e.g., feeding traces, locomotion traces, escape burrows) Disturbance of sediments by organisms is known as bioturbation, which can lead to the total destruction of primary sedimentary structures Since numerous trace fossils are connected to specific depositional environments, they can be very useful in sedimentologic interpretations Soft-sediment deformation structures are sometimes considered to be part of the initial diagenetic changes of a sediment, and include: • • • Slump structures (on slopes) Dewatering structures (upward escape of water, commonly due to loading) Load structures (density contrasts between sand and underlying wet mud; can in extreme cases cause mud diapirs) GED 2008 GED 2008 GED 2008 GED 2008 GED 2008 Clastic (siliciclastic) rocks • Sandstones (20-25% of the stratigraphic record) can be subdivided according to the Pettijohn classification, based on texture and composition (relative proportions of quartz, feldspar, and lithic fragments) • • • • Quartz arenite: quartz-dominated Arkosic arenite: feldspar-dominated Lithic arenite: dominance of lithic fragments Wacke: significantly matrix-supported (>15% mud) • • Quartz wacke Greywacke (feldspathic or lithic wacke) GED 2008 Classification of Sandstone (Pettijohn, 1975) GED 2008 Clastic (siliciclastic) rocks • Mudstones (60% of the stratigraphic record) are also known as mudrocks or shales and commonly exhibit a distinct fissility • • • Claystone Siltstone Conglomerates are consolidated gravels; breccias are conglomerates with dominantly angular clasts • • Clast-supported conglomerates Matrix-supported conglomerates GED 2008 Halang Formation, Panujah, Slawi, Central Jawa GED 2008 Alternating of siltstone and claystone, Sambipitu Formation-Wonogiri GED 2008 Black shale (upper part) overlying above thickly bedded fine sandstone Sambipitu Formation-Wonogiri GED 2008 Normal grading sandstone, from coarse sst to fine sst, ambipitu Formation-Wonogiri GED 2008 Conglomerate in Kali Ngalang, Gunung Kidul. Nglanggran Formation GED 2008 Breccia, in Kali Ngalang, Gunung Kidul. Nglanggran Formation GED 2008 Siliciclastic rocks classification (Pettijohn, 1975) GED 2008 CARBONATE SEDIMENT AND ROCKS • • • Principal minerals: calcite, aragonite (unstable), and dolomite (diagenetic) Principal rocks: limestone (>50% CaCO3) and dolomite (dolostone) (CaMg(CO3)2) Formation of carbonate sediments and rocks occurs by means of two main processes: • • Biomineralization of CaCO3 by organisms Direct chemical precipitation Ca2 2HCO3 CaCO3 H2CO3 Biogenic carbonate formation occurs by a wide range of organisms (e.g., molluscs, corals, forams, algae, bacteria, and many others) • • • Most organisms initially form unconsolidated carbonate sediments Coral reefs and microbial mats (e.g., stromatolites) are examples of more solid carbonate structures Chemical precipitation produces non-skeletal carbonate grains of various sizes (e.g., ooids, pisoids, micrite) GED 2008 GED 2008 GED 2008 GED 2008 GED 2008 GED 2008 GED 2008 CARBONATE SEDIMENT AND ROCKS • Biogenic carbonate formation occurs by a wide range of organisms (e.g., molluscs, corals, forams, algae, bacteria, and many others) • • • Most organisms initially form unconsolidated carbonate sediments Coral reefs and microbial mats (e.g., stromatolites) are examples of more solid carbonate structures Chemical precipitation produces non-skeletal carbonate grains of various sizes (e.g., ooids, pisoids, micrite) GED 2008 After Scholle, 2003 GED 2008 CARBONATE SEDIMENT AND ROCKS Carbonate sand usually consists either of (fragmented) skeletal remains or non-skeletal grains Carbonate mud (micrite) is commonly the product either of chemical precipitation or algal/bacterial activity Dunham classification of carbonate rocks: Texturally-based subdivision (cf. clastics): mudstone, wackestone, packstone, grainstone, rudstone Organically bound framework during formation: boundstone GED 2008 GED 2008 GED 2008 GED 2008 GED 2008 Modified of Dunham Classification GED 2008 ORGANIC (CARBONACEOUS) SEDIMENTS AND ROCKS • Peat and organic-rich clastic sediments form in relatively anaerobic (reducing) environments (e.g., mires, lakes, oceans) • • • • • • • Minerotrophic peat: mostly nutrient-rich, groundwater-fed mires (e.g., floodplains, delta plains, coastal plains) Ombrotrophic peat: mostly nutrient-poor, rainwater-fed mires (e.g., relatively high, flat terrains) Gyttja: organic-rich lake sediment Sapropel: organic-rich marine sediment Coal consists primarily of solid organic matter; the remainder is known as ‘ash’ Carbonaceous shales have a lower proportion of solid organic matter Oil shales (may be formed in anaerobic lake and marine environments) contain organic matter that can be driven off as liquid or gas by heating GED 2008 Thickly bedded coal, in between shale – siltstone (Bontang, East Kalimantan) GED 2008 GED 2008 GED 2008 EVAPORITES • • • Dissolved salts precipitate out of sea water due to concentration (brine formation) during evaporation (1 km of sea water --> 12 m of evaporites) Evaporites commonly lithify into consolidated rocks upon formation Least soluble compounds precipitate first: • • • • • • • CaCO3 (calcium carbonate) CaSO4 (calcium sulphate: gypsum or anhydrite) NaCl (halite: rock salt) Other, less stable (highly soluble) chlorides Dissolved salts precipitate out of sea water due to concentration (brine formation) during evaporation (1 km of sea water --> 12 m of evaporites) Evaporites commonly lithify into consolidated rocks upon formation Least soluble compounds precipitate first: • • • • CaCO3 (calcium carbonate) CaSO4 (calcium sulphate: gypsum or anhydrite) NaCl (halite: rock salt) Other, less stable (highly soluble) chlorides GED 2008 GED 2008 VOLCANICLASTIC SEDIMENTS AND ROCKS • • Lava (cooled magma flows) produces volcaniclastic sediment upon weathering Pyroclastic material or tephra (ejected particulate material) can be subdivided into different compositional categories: • • • Mineral grains Lithic fragments Vitric material (volcanic glass or pumice) GED 2008 Pillow lava, Watuadeg-Bantul, DIY GED 2008 Kekar tiang, lava. Kali Grindulu, Pacitan GED 2008 Tephra of Merapi pyroclastic flow mechanism, Kaliadem, Sleman GED 2008 GED 2008 GED 2008