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Stoichiometry Mass Calculations Chemistry 11 Ms. McGrath Mass relationships in chemical equations As we saw, the coefficients in a chemical equation represents number of particles as well as moles. We can, therefore, use the molar masses to determine the mass ratios for a reactions. Mass relationships in chemical equations N2(g) + 3H2(g) -> 2NH3(g) For the above reaction, we can calculate the mass of each substance. 1 mol N2 x 28.02 g/mol N2 = 28.02 g N2 3 mol H2 x 2.02 g/mol H2 = 6.06 g H2 2 mol NH3 x 17.04 g/mol NH3 = 34.08 g NH3 Mass relationships in chemical equations Balanced equation Number of particles Amount (mol) Mass (g) Total mass (g) N2(g) + 3H2(g) 2NH3(g) 1 molecule N2 reacts with 3 molecules H2 to produce 2 molecules NH3 1 mol N2 + 3 mol H2 2 mol NH3 28.02 g N2 + 6.06 g H2 34.08 g NH3 34.1 g reactants 34.1 g products Mass relationships in chemical equations The Law of Conservation of Mass During a chemical reaction, the total mass of the reactants is always equal to the total mass of the products. If we determine the total mass of substances on each side of a balanced chemical reaction, we will find that the mass of the products is always equal to the mass of the reactants. Stoichiometry Stoichiometry is the study of the relative quantities of reactant and products in a chemical reaction. Gravimetric stoichiometry is the analysis involving mass of the reactants and products. Stoichiometry - Example In a spacecraft, a closed system, carbon dioxide that is produced by astronauts can be removed with lithium hydroxide. The reaction produces lithium carbonate and water. What mass of lithium hydroxide should engineers put on board a spacecraft, per astronaut, for each day if each astronaut produces 1.00 x 103 g of carbon dioxide each day? Stoichiometry - Example Strategy: 1. Write a balanced equation 2. Convert the given mass of CO2 to the number of moles of CO2 3. Calculate the number of moles of LiOH based on the mole ratios 4. Convert the number of moles to mass of LiOH Stoichiometry Try page 121, #11 - 13