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MEASURES OF AMOUNT OR SIZE,STATE VARIABLE MEMBERS OF GROUP NEWTON: 1)Yuganesh a/l Murugiah 2)Tan See Yean 3)Nazzira Md Zin 4)Nor Fatehah Kamaruddin Three measures of amount or size in common use: • Mass,m • Number of moles,n • Total volume,Vt The measures for a specific system are in direct porpotion to one another. Formulae of calculate: • Number of moles, n = m M • Specific volume, Vt = mV • Molar volume, Vt = nV Vt = the size of a system Definition Of Intensive & Extensive thermodynamic variable • An intensive quantity (also intensive variable) is a physical quantity whose value does not depend on the amount of the substance for which it is measured. • It is the counterpart of an extensive quantity. For instance, the mass of an object is not a bulk property, because it depends on the amount of that substance being measured. Examples: • • • • • • • • • • • temperature pressure chemical potential density viscosity electrical resistivity melting point boiling point spectral absorption maxima (in solution) flammability specific energy Extensive Variables • An extensive quantity (also extensive variable or extensive parameter) is a physical quantity, whose value is proportional to the size of the system it describes. Such a property can be expressed as the sum of the quantities for the separate subsystems that compose the entire system. • Extensive quantities are the counterparts of intensive quantities, which are intrinsic to a particular subsystem and remain constant regardless of size. Dividing one type of extensive quantity by a different type of extensive quantity will in general give an intensive quantity (mass divided by volume gives density). Examples: • • • • • • • mass volume entropy energy electrical resistance texture heat The differences between intensive and extensive properties • An intensive property is independent of the amount of mass. While the value of an extensive property varies directly with the mass. • Thus, if a quantity of matter in a given state is divided into two equal parts, each part will have the same value of intensive property as the original and half the value of the extensive property. • Temperature, pressure, specific volume, and density are examples of intensive properties. • Mass and total volume are examples of extensive properties. The End