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REACTIVE RED Safety Data Sheet Emergency Telephone Number: CHEMTREC 1-800-424-9300 For Information call: DUDLEY 732-886-3100 DUDLEY CORPORATION 125 Kenyon Drive Lakewood, New Jersey 08701 Effective Date: January 1, 2015 1. PRODUCT IDENTIFICATION: Synonyms: Reactive Red 120, CAS No: 61951-82-4 Weight: 615.34 Chemical Formula: C44H24Cl2N14Na6O20S6 2. HAZARDS IDENTIFICATION: GHS Classification: Respiratory sensitisation (Category 1) Skin sensitisation (Category 1) Pictogram Signal word Danger Hazard statement(s): H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Precautionary statement(s): P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. HMIS Classification: Health hazard: 2, Chronic Health Hazard: *, Flammability: 0, Physical hazards: 0 NFPA Rating: Health hazard: 2, Fire: 0, Reactivity Hazard: 0 Potential Health Effects: Eyes: May cause irritation. Skin: May cause allergic skin reaction. Ingestion: May be harmful if swallowed. Inhalation: May cause irritation of respiratory tract. Chronic: No information. 3. COMPOSITION, INFORMATION ON INGREDIENTS: Chemical Name CAS No. Percent Hazardous Reactive Red 61951-82-4 90-100 No 4. FIRST AID MEASURES:Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin: In case of contact, flush skin with plenty of water for at least 15 minutes while removing contaminated clothes and shoes. Get medical attention if irritation develops or persists.Ingestion: If victim is conscious and alert, give 2-4 cupfuls water or milk to drink. Do NOT induce vomiting. NEVER give anything by mouth to an unconscious person. Get medical attention if irritation or symptoms appear. Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. 5. FIRE FIGHTING MEASURES: General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Special Hazards Arising: Carbon & nitrogen oxides Flash Point: Not applicable. Auto-ignition Temperature: Not applicable. Explosion Limits: Not available. 6. ACCIDENTAL RELEASE MEASURES:General Information: Wear Respirator, PPE as indicated in section 8. Spills/Leaks: Sweep up, place in a bag and hold for waste disposal. Avoid raising dust, Ventilate area and wash spill site after material pickup is complete. 7. HANDLING AND STORAGE: Handling: Wear Respirator, chemical safety goggles, rubber boots and heavy rubber gloves Storage: Store in a tightly closed container. Protect container from physical damage. Store in a cool, dry ventilated area from sources of heat or ignition. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION: Engineering Controls: Mechanical exhaust required. Chemical Name ACGIH NIOSH OSHA-Final/Vacated PEL’s Reactive Red None listed None listed None listed Personal Protective Equipment: Eyes: Chemical safety goggles. Skin: Compatible chemical resistant gloves. Clothing: Appropriate protective clothing. Respirators: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN143) respirator. 9. PHYSICAL AND CHEMICAL PROPERTIES: Appearance: Solid. Odor: No data Solubility: Soluble-Ethanol:H20 (1:1). Boiling Point: No data Melting Point: No data Vapor Density & Pressure: No data Evaporation Rate: No data 10. STABILITY AND REACTIVITY: Stability: Stable. Incompatibilities: Strong oxidizing Agents. Hazardous Decomposition Products: Nature of Decomposition products not known. 11. TOXICOLOGICAL INFORMATION: LD50/LC50: No information. Route of Exposure: Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion or skin absorption. Sensitization: May cause allergic reaction. Conditions Aggravated by Exposure: The toxicological properties have not been thoroughly investigated. 12. ECOLOGICAL INFORMATION: No Data Available. 13. DISPOSAL CONSIDERATIONS: Disposal: Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all Federal, State and Local Environmental Regulations.Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. 14. TRANSPORT INFORMATION: Not regulated. 15. REGULATORY INFORMATION: SARA 311/312: None SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. Section 313 No chemicals are reportable under Section 313. STATE CAS# 61951-82-4 is not present on state lists from CA, PA, MA, MN, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives Hazardous Symbols: Xn – Harmful. WGK (Water Danger/Protection) CAS#61951-82-4: No information available. Canada - DSL/NDSL CAS# 61951-82-4 is not listed on Canada’s DSL List. Canada - WHMIS WHMIS: Not available. CAS# 61951-82-4 is not listed on Canada’s Ingredient Disclosure List. 16. DISCLAIMER INFORMATION: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.