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CHAPTER 10-11 PRACTICE FOR TEST Matching Match each itme with the correct statement below. Match each item with the correct statement below. a. molar volume b. molar mass c. atomic mass ____ 1. the number of grams of an element that is numerically equal to the atomic mass of the element in amu ____ 2. the mass of a mole of any element or compound ____ 3. the volume occupied by a mole of any gas at STP Match each item with the correct statement below. a. representative particle d. percent composition b. mole e. standard temperature and pressure c. Avogadro's number f. empirical formula ____ 4. the number of representative particles of a substance present in 1 mole of that substance ____ 5. an atom, an ion, or a molecule, depending upon the way a substance commonly exists ____ 6. the SI unit used to measure amount of substance ____ 7. 0 C and 1 atm ____ 8. the percent by mass of each element in a compound ____ 9. the smallest whole number ratio of the atoms in a compound Match each item with the correct statement below. a. product c. chemical equation b. reactant d. balanced equation ____ 10. an equation in which each side has the same number of atoms of each element. ____ 11. a new substance formed in a chemical reaction ____ 12. a starting substance in a chemical reaction ____ 13. a concise representation of a chemical reaction Match each item with the correct statement below. a. double-replacement reaction c. combustion reaction b. single-replacement reaction d. decomposition reaction ____ 14. a reaction in which a single compound is broken down into simpler substances ____ 15. a reaction in which oxygen reacts with another substance, often producing heat or light ____ 16. a reaction in which the atoms of one element replace the atoms of a second element in a compound ____ 17. a reaction in which two compounds are broken down into ions in solution then each of the cations rebond to the opposite anions to form new compounds Multiple Choice Identify the choice that best completes the statement or answers the question. ____ 18. Which of the following elements exists as a diatomic molecule? a. neon c. nitrogen b. lithium d. sulfur ____ 19. How many atoms are in 0.075 mol of titanium? a. 1.2 10-25 c. 6.4 b. 2.2 10 d. 4.5 ____ 20. How many molecules are in 2.10 mol CO ? a. 2.53 10 molecules b. 3.79 10 molecules c. 3.49 d. 1.26 10 10 10 10 molecules molecules ____ 21. Which of the following is NOT a true about atomic mass? a. The atomic mass is 12 g for magnesium. b. The atomic mass is the mass of one mole of atoms. c. The atomic mass is found by checking the periodic table. d. The atomic mass is the number of grams of an element that is numerically equal to the mass in amu. ____ 22. The mass of a mole of NaCl is the ____. a. molar mass b. atomic mass c. molecular mass d. gram atomic mass ____ 23. What is the molar mass of (NH ) CO ? a. 144 g b. 138 g c. 96 g d. 78 g ____ 24. What is the mass in grams of 5.90 mol C H ? a. 0.0512 g c. 389 g b. 19.4 g d. 673 g ____ 25. What is the number of moles in 432 g Ba(NO ) ? a. 0.237 mol c. 1.65 mol b. 0.605 mol d. 3.66 mol ____ 26. The molar volume of a gas at STP occupies ____. a. 22.4 L c. 1 kilopascal b. 0 C d. 12 grams ____ 27. Which combination of temperature and pressure correctly describes standard temperature and pressure, STP? a. 0 C and 101 kPa c. 0 C and 22.4 kPa b. 1 C and 0 kPa d. 100 C and 100 kPa ____ 28. The molar mass of a substance can be calculated from its density alone, if that substance is a(n) ____. a. element c. liquid b. gas at STP d. solid ____ 29. What is the volume, in liters, of 0.500 mol of C H gas at STP? a. 0.0335 L c. 16.8 L b. 11.2 L d. 22.4 L ____ 30. If the density of an unknown gas Z is 4.50 g/L at STP, what is the molar mass of gas Z? a. 0.201 g/mol c. 26.9 g/mol b. 5.00 g/mol d. 101 g/mol ____ 31. If 60.2 grams of Hg combines completely with 24.0 grams of Br to form a compound, what is the percent composition of Hg in the compound? a. 28.5% c. 71.5% b. 39.9% d. 60.1% ____ 32. Which of the following compounds has the lowest percent gold content by weight? a. AuOH c. AuCl b. Au(OH) d. AuI ____ 33. The lowest whole-number ratio of the elements in a compound is called the ____. a. empirical formula c. binary formula b. molecular formula d. representative formula ____ 34. What is the empirical formula of a compound that is 40% sulfur and 60% oxygen by weight? a. SO c. SO b. SO d. S O ____ 35. The ratio of carbon atoms to hydrogen atoms to oxygen atoms in a molecule of dicyclohexyl maleate is 4 to 6 to 1. What is its molecular formula if its molar mass is 280 g? a. C H O c. C H O b. C H O d. C H O ____ 36. Which of the following is NOT true about empirical and molecular formulas? a. The molecular formula of a compound can be the same as its empirical formula. b. The molecular formula of a compound can be some whole-number multiple of its empirical formula. c. Several compounds can have the same empirical formula, but have different molecular formulas. d. The empirical formula of a compound can be triple its molecular formula. ____ 37. Chemical equations ____. a. describe chemical reactions b. show how to write chemical formulas c. give directions for naming chemical compounds d. describe only biological changes ____ 38. In the chemical equation H O (aq) H O(l) O (g), the a. catalyst c. product b. solid d. reactant is a ____. ____ 39. If you rewrite the following word equation as a balanced chemical equation, what will the coefficient and symbol for fluorine be? nitrogen trifluoride a. 6F b. F nitrogen fluorine c. 6F d. 3F ____ 40. Chemical equations must be balanced to satisfy ____. a. the law of definite proportions c. the law of conservation of mass b. the law of multiple proportions d. Avogadro’s principle ____ 41. When potassium hydroxide and barium chloride react, potassium chloride and barium hydroxide are formed. The balanced equation for this reaction is ____. a. KH BaCl KCl BaH c. 2KOH BaCl 2KCl Ba(OH) b. KOH BaCl KCl BaOH d. KOH BaCl KCl BaOH ____ 42. In a combustion reaction, one of the reactants is ____. a. hydrogen c. oxygen b. nitrogen d. a metal ____ 43. What are the correct formulas and coefficients for the products of the following double-replacement reaction? RbOH H PO a. Rb(PO ) c. Rb PO H O 3H O b. RbPO d. H Rb PO OH 2H O ____ 44. A double-replacement reaction takes place when aqueous Na CO reacts with aqueous Sn(NO ) . You would expect one of the products of this reaction to be ____. a. NaNO c. Sn(CO ) b. NaSn d. CNO ____ 45. What is the balanced chemical equation for the reaction that takes place between bromine and sodium iodide? a. Br c. Br NaI NaI NaBr I NaBrI b. Br d. Br NaI 2NaI 2NaBr I NaBr I Short Answer 46. What is the percent by mass of hydrogen in aspirin, C H O ? 47. Calculate the molecular formulas of the compounds having the following empirical formulas and molar masses: C H , 58 g/mol; CH, 78 g/mol. 48. Balance the following equation. Au O Au O 49. Balance the following equation. Na PO ZnSO Na SO Zn (PO ) 50. Write a balanced net ionic equation for the following reaction. H PO (aq) Ca(OH) (aq) Ca (PO ) (aq) H O(l) Essay 51. Predict the precipitate that forms when aqueous solutions of silver nitrate and potassium chloride react to form products in a double-replacement reaction. Include a discussion of how to determine the products and which of them is the solid precipitate. Be sure to include the whole balanced equation with your discussion. CHAPTER 10-11 PRACTICE FOR TEST Answer Section MATCHING 1. ANS: C PTS: 1 DIF: L1 REF: p. 294 OBJ: 10.1.3 Distiguish between the atomic mass of an element and its molar mass. STA: Ch.1.a 2. ANS: B PTS: 1 DIF: L1 REF: p. 294 | p. 295 OBJ: 10.1.3 Distiguish between the atomic mass of an element and its molar mass. | 10.1.4 Describe how the mass of a mole of a compound is calculated. STA: Ch.3.d 3. ANS: A PTS: 1 DIF: L1 REF: p. 300 OBJ: 10.2.2 Identify the volume of a quantity of gas at STP. STA: Ch.4 4. ANS: C PTS: 1 DIF: L1 REF: p. 290 OBJ: 10.1.2 Relate Avogadro’s number to a mole of a substance. STA: Ch.3.b 5. ANS: A PTS: 1 DIF: L1 REF: p. 290 OBJ: 10.1.2 Relate Avogadro’s number to a mole of a substance. STA: Ch.3.b 6. ANS: B PTS: 1 DIF: L1 REF: p. 290 OBJ: 10.2.1 Describe how to convert the mass of a substance to the number of moles of a substance, and moles to mass. STA: Ch.3.b | Ch.3.c 7. ANS: E PTS: 1 DIF: L1 REF: p. 300 OBJ: 10.2.2 Identify the volume of a quantity of gas at STP. STA: Ch.4.d 8. ANS: D PTS: 1 DIF: L1 REF: p. 305 OBJ: 10.3.1 Describe how to calculate the percent by mass of an element in a compound. STA: Ch.5 9. ANS: F PTS: 1 DIF: L1 REF: p. 309 OBJ: 10.3.2 Interpret an empirical formula. STA: Ch.3 10. ANS: OBJ: 11. ANS: OBJ: 12. ANS: OBJ: 13. ANS: OBJ: STA: D 11.1.2 A 11.1.2 B 11.1.2 C 11.1.3 Ch.3.a PTS: 1 DIF: L1 REF: p. 323 Describe how to write a skeleton equation STA: Ch.3.a PTS: 1 DIF: L1 REF: p. 323 Describe how to write a skeleton equation STA: Ch.3.e PTS: 1 DIF: L1 REF: p. 323 Describe how to write a skeleton equation STA: Ch.3.e PTS: 1 DIF: L1 REF: p. 323 Describe the steps for writing a balanced chemical equation. 14. ANS: OBJ: 15. ANS: OBJ: 16. ANS: OBJ: 17. ANS: D PTS: 1 DIF: L1 11.2.1 Describe the five general types of reactions. C PTS: 1 DIF: L1 11.2.1 Describe the five general types of reactions. B PTS: 1 DIF: L1 11.2.1 Describe the five general types of reactions. A PTS: 1 DIF: L1 REF: p. 332 REF: p. 336 | p. 337 STA: Ch.3.g | Ch.7.b REF: p. 333 REF: p. 333 OBJ: 11.2.2 Predict the products of the five general types of reactions. MULTIPLE CHOICE 18. ANS: C PTS: 1 DIF: L1 REF: p. 290 OBJ: 10.1.2 Relate Avogadro’s number to a mole of a substance. STA: Ch.1 19. ANS: D PTS: 1 DIF: L2 REF: p. 291 | p. 292 OBJ: 10.1.2 Relate Avogadro’s number to a mole of a substance. STA: Ch.3.d 20. ANS: D PTS: 1 DIF: L2 REF: p. 291 | p. 292 OBJ: 10.1.2 Relate Avogadro’s number to a mole of a substance. STA: Ch.3.d 21. ANS: A PTS: 1 DIF: L2 REF: p. 294 OBJ: 10.1.3 Distiguish between the atomic mass of an element and its molar mass. STA: Ch.3 22. ANS: A PTS: 1 DIF: L1 REF: p. 295 OBJ: 10.1.4 Describe how the mass of a mole of a compound is calculated. STA: Ch.3 23. ANS: C PTS: 1 DIF: L2 REF: p. 295 | p. 296 OBJ: 10.1.4 Describe how the mass of a mole of a compound is calculated. STA: Ch.3 24. ANS: D PTS: 1 DIF: L2 REF: p. 297 | p. 298 OBJ: 10.2.1 Describe how to convert the mass of a substance to the number of moles of a substance, and moles to mass. STA: Ch.3 25. ANS: C PTS: 1 DIF: L2 REF: p. 299 OBJ: 10.2.1 Describe how to convert the mass of a substance to the number of moles of a substance, and moles to mass. STA: Ch.3 26. ANS: A PTS: 1 DIF: L1 REF: p. 300 OBJ: 10.2.2 Identify the volume of a quantity of gas at STP. STA: Ch.4.c 27. ANS: A PTS: 1 DIF: L1 REF: p. 300 OBJ: 10.2.2 Identify the volume of a quantity of gas at STP. STA: Ch.4.d 28. ANS: B PTS: 1 DIF: L1 REF: p. 302 OBJ: 10.2.2 Identify the volume of a quantity of gas at STP. STA: Ch.4.d 29. ANS: B PTS: 1 DIF: L2 REF: p. 301 OBJ: 10.2.2 Identify the volume of a quantity of gas at STP. STA: Ch.4.h 30. ANS: D PTS: 1 DIF: L2 REF: p. 302 OBJ: 10.2.2 Identify the volume of a quantity of gas at STP. STA: Ch.4.h 31. ANS: C PTS: 1 DIF: L2 REF: p. 305 | p. 306 OBJ: 10.3.1 Describe how to calculate the percent by mass of an element in a compound. STA: Ch.3 32. ANS: D PTS: 1 DIF: L3 REF: p. 307 OBJ: 10.3.1 Describe how to calculate the percent by mass of an element in a compound. STA: Ch.3 33. ANS: A PTS: 1 DIF: L1 REF: p. 309 OBJ: 10.3.2 Interpret an empirical formula. STA: Ch.3 34. ANS: C PTS: 1 DIF: L2 REF: p. 310 OBJ: 10.3.2 Interpret an empirical formula. STA: Ch.3 35. ANS: D PTS: 1 DIF: L3 REF: p. 310 OBJ: 36. ANS: OBJ: STA: 37. ANS: OBJ: 38. ANS: OBJ: 39. ANS: OBJ: STA: 40. ANS: OBJ: 41. ANS: OBJ: STA: 42. ANS: OBJ: 43. ANS: OBJ: 44. ANS: OBJ: 45. ANS: OBJ: STA: 10.3.2 Interpret an empirical formula. STA: Ch.3 D PTS: 1 DIF: L1 REF: p. 311 10.3.3 Distinguish between empirical and molecular formulas. Ch.3 A PTS: 1 DIF: L1 REF: p. 323 11.1.2 Describe how to write a skeleton equation STA: Ch.3.a C PTS: 1 DIF: L1 REF: p. 323 11.1.2 Describe how to write a skeleton equation STA: Ch.3.a D PTS: 1 DIF: L1 REF: p. 324 | p. 325 11.1.3 Describe the steps for writing a balanced chemical equation. Ch.3.a | Ch.3.e C PTS: 1 DIF: L1 REF: p. 325 11.1.3 Describe the steps for writing a balanced chemical equation. C PTS: 1 DIF: L2 REF: p. 327 11.1.3 Describe the steps for writing a balanced chemical equation. Ch.3.a | Ch.3.e C PTS: 1 DIF: L1 REF: p. 336 11.2.1 Describe the five general types of reactions. STA: Ch.3.g C PTS: 1 DIF: L2 REF: p. 334 | p. 335 11.2.1 Describe the five general types of reactions. STA: Ch.3.a | Ch.3.e A PTS: 1 DIF: L2 REF: p. 334 | p. 335 11.2.1 Describe the five general types of reactions. STA: Ch.3.a | Ch.3.e B PTS: 1 DIF: L2 REF: p. 333 | p. 334 11.2.2 Predict the products of the five general types of reactions. Ch.3.a | Ch.3.e SHORT ANSWER 46. ANS: 8.00 g H /180 g C H O 100% = 4.44% H PTS: 1 DIF: L3 REF: p. 307 OBJ: 10.3.1 Describe how to calculate the percent by mass of an element in a compound. STA: Ch.3 47. ANS: 58 g/mol/29 g/efm = 2 efm/mol; C H 78 g/mol/13 g/efm = 6 efm/mol; C H PTS: 1 DIF: L3 REF: p. 312 OBJ: 10.3.3 Distinguish between empirical and molecular formulas. STA: Ch.3 48. ANS: 2Au O 4Au 3O PTS: 1 DIF: L3 REF: p. 327 OBJ: 11.1.3 Describe the steps for writing a balanced chemical equation. STA: Ch.3.e 49. ANS: 2Na PO 3ZnSO 3Na SO Zn (PO ) PTS: 1 DIF: L3 REF: p. 327 OBJ: 11.1.3 Describe the steps for writing a balanced chemical equation. STA: Ch.3.e 50. ANS: H (aq) OH (aq) H O(l) PTS: 1 DIF: L3 REF: p. 342 | p. 343 OBJ: 11.3.1 Describe the information found in a net ionic equation. STA: Ch.3.a | Ch.3.e ESSAY 51. ANS: Because the reaction is a double-replacement type, cations are exchanged among compounds during the reaction. The first step is to write the equation in skeleton form: AgNO + KCl AgCl + KNO Inspection of this equation shows that the insoluble precipitate silver chloride forms in an aqueous solution of potassium nitrate. The relative amounts of elements are the same on either side of the equation, so the complete equation is: AgNO (aq) + KCl(aq) AgCl(s) + KNO (aq) (balanced) PTS: 1 DIF: L3 REF: p. 334 | p. 335 OBJ: 11.3.2 Predict the formation of a precipitate in a double-replacement reaction. STA: Ch.3.a | Ch.3.e