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1 Date: __________________________________ CARBOHYDRATES 1. 2. 3. 4. Carbohydrates are the cheapest and most abundant nutrients available. Their main function is the production of heat and energy. Animals cannot synthesise carbohydrates. Carbohydrates are chiefly found in plant foods where they are manufactured by photosynthesis. Functions of Carbohydrate 1. Provide _____________________ for physical activities. 2. Supply ______________. Excess carbohydrate is converted into fat and stored as adipose tissue beneath the skin. This has the advantage of reducing heat loss but too much causes obesity. 3. Cellulose stimulates the peristaltic movements of intestine. It aids ___________ and prevents ________________. What is the elemental composition of carbohydrate? ______________________________ ______________________________ ______________________________ Types of Carbohydrates There are _______________ main types of carbohydrates: 1. _________________________________ 2. _________________________________ 3. _________________________________ Monosaccharides and disaccharides are often called ________________ sugars whereas polysaccharides are often called ________________ sugars. Monosaccharides A monosaccharide is made of a single sugar molecule. They are ____________ _______________ __________ which dissolves easily in water to form ________________ _______________ solutions. F&NYr9-2012 2 Examples of monosaccharides are ___________________, _________________ and ____________________. Glucose and fructose can be found naturally in fruit. Galactose can be found in milk products. (a) Fructose Fructose is sometimes called ‘fruit sugar’ because it is found predominantly in fruits, plant juices and honey. (b) Glucose Glucose is used by the body for energy. All other carbohydrates are converted into glucose during digestion. Glucose is found in ripe fruits and some vegetables e.g. onions, beetroot. It is also available commercially in powdered, liquid or tablet form. It provides a fast source of energy and is often taken by athletes for this reason. (c) Galactose Galactose is found in the milk of mammals where it forms part of the milk sugar, lactose. Disaccharides Disaccharides contain two sugar molecules. Dissacharides are _________ ____________ ____________ that are ___________ and ________________ in water. Each disaccharide is made of ___________ ________________ molecules. Examples of disaccharides are _________________ (cane sugar or household sugar), ________________ (milk sugar) and __________________ (malt sugar). Sucrose and lactose can be found naturally in fruit and milk respectively. Maltose is obtained from cereal grains. (a) Sucrose Sucrose is formed from one unit of glucose and one unit of fructose. Sucrose is most commonly used in cookery and is obtained by refining sugar cane or beet. It is also present in some fruits and vegetables. (b) Lactose Lactose is formed from one unit of glucose and one unit of galactose. Lactose is found in the milk of mammals to supply the infant with a source of energy. It is not as sweet as sucrose. F&NYr9-2012 3 (c) Maltose Maltose is formed from two units of glucose. It is sometimes called ‘malt sugar’ and is found in cereals such as barley where it is formed during germination. Polysaccharides Polysaccharides are made up of _________ ___________________ molecules that are linked together. Unlike monosaccharides and disaccharides, most polysaccharides are not ______________ or ______________ in cold water. Examples of polysaccharides are ___________________, ___________________, ___________________ and ___________________. Glycogen, pectin and cellulose are collectively referred to as ________________ _________________. (a) Starch After photosynthesis, plants store their reserves of glucose by converting them to starch. Starch is made up of many glucose molecules linked together. Starch is plentiful in cereals such as rice, wheat, oats and is present in potatoes, pulse vegetables and some root vegetables. Starch is insoluble in cold water and difficult digest. Cooking will penetrates or breaks the outer covering, gelatinising the starch granules making it more digestible. (b) Dextrin Dextrin is formed when foods containing starch e.g. bread are baked or toasted. The dextrin forms part of the crust on such foods and is more soluble than starch. (c) Cellulose Cellulose consists of hair-like fibres which are not sweet and which do not dissolve in water. Like starch, cellulose is also formed by many glucose molecules that are linked together. However, in cellulose, the molecules are linked differently. Cellulose is found in the cell walls of plant cells. It is a strong structural material that provides support to plants. Thus, all plant foods contain cellulose. F&NYr9-2012 4 (d) Pectin Pectin is a polysaccharide that acts as a cementing agent between plant cells. It can be extracted for use as a setting agent for making spreadable gels. Pectin is commercially extracted from citrus peel and apple pulp to make fruit jellies, jams and marmalades. (e) Glycogen Some of the glucose in the body that is not used up immediately is converted to glycogen. Glycogen is temporarily stored in the liver and muscle cells and used as an energy reserve. When the body suddenly requires a supply of energy, glycogen can be quickly converted to glucose. However, if the energy is not used up, the glycogen will be converted to fat. Sources of Carbohydrates Simple carbohydrate foods are foods that are naturally rich in simple sugars such as glucose, fructose, sucrose, lactose and maltose. Honey produced by bees and most varieties of fruits such as apples and bananas are good sources of the simple sugars glucose and fructose. Complex carbohydrate foods are high in polysaccharide starch. These include underground stem and root vegetables such as potato, tapioca and yam as well as cereals such as rice, wheat and corn. Cereal grains can also be milled into flour and used to make a wide range of products including bread, pasta and noodles. These are also high in complex carbohydrates. Processed foods such as candy, ice cream, cakes and biscuits are also sweetened with sucrose. However, excess intake of these processed sources of simple sugars is discouraged as they tend to be stripped of other nutrients. F&NYr9-2012 5 Carbohydrate Requirements About two-thirds of the average diet consists of a mixture of carbohydrates. In poor countries, over 80% of the diet may be composed of carbohydrate foods. In wealthy countries, carbohydrates form less than 50% of the diet. Effects of Deficiency Except in cases of actual starvation, it is rare to find insufficient carbohydrate in the diet, as it is the cheapest food available. Dietary Problems due to Excess Intake of Carbohydrates If someone eats more carbohydrate than the body requires, the excess is converted into fat and stored under the skin. This is one of the major causes of ________________. Eating too many carbohydrates in the form of sugar can lead to _____________ ________________. This also leads to ___________________. Eating over-processed foods such as white bread, white sugar and white rice can lead to _______________ ____________________ and _________________ of the _____________________. This is because processed food lacks roughage (dietary fibres) which aids digestion. Carbohydrates in Food Preparation Caramelisation When sugars are heated at high temperatures in the presence of water, they can undergo caramelisation. During caramelisation, the water molecules evaporate, leaving behind a concentrate brown substance known as caramel. Caramel has a toffee-like aroma and flavour. Caramelisation contributes to the attractive flavour and brown colour of toasted bread and roasted onions. Maillard Browning When heated at high temperatures, some sugars can undergo a browning reaction in the presence of nitrogen-containing compounds such as proteins. This is known as Maillard Browning (refer to Protein notes). Dextrinsation When starch is heated or treated with hot acid, the long starch chains become hydrolysed, that is, they break down into shorter chains called dextrins. This process is called dextrinisation. Dextrins are flavourless compounds that are often used as fillers and flavour carriers in food seasonings. F&NYr9-2012 6 Gelatinisation When starch is heated in a solution that contains water, the starch granules undergo gelatinsation. In this process, the starch granules lose their ordered structure and absorb water. This results in the thickening of the whole solution. The gelatinisation of starch is important in the preparation of many food products, such as custard sauce. Gelation If the proportion of starch molecules to liquid is high enough, a gel may form after cooking. A gel is a semi-rigid substance consisting of a liquid trapped in a network of molecules. In a starch gel, the amylase molecules form a net-like structure, entrapping the liquid. Starch gels can be seen in custards, where corn flour is often used as a gelling agent. Many sauces and stews are thickened with gelatinised starch and may also form gels when cooled. Carbohydrates Written exercise 1. Name the three chemical elements found in carbohydrates. 2. What is the body’s main use for carbohydrates? 3. State three properties: (a) Monosaccharides (b) Disaccharides (c) Polysaccharides 4. What happens when you eat too much carbohydrate food? F&NYr9-2012