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SCH3U Unit 1 Review List of topics covered during unit Chemistry Matter Properties of matter Physical and chemical change Classifying matter Atoms Modern atomic theory Structure of an atom Determining protons, neutrons, electrons Isotopes How to calculate average atomic mass and isotopic abundance Periodic table Categorizing groups, periodic/group patterns Lewis Dot structures Atomic size, ionization energy, electron affinity, and electronegativity trends Ionic and covalent compounds Predicting bonding type using electronegativity scale Physical properties and reasoning why (intermolecular forces and intramolecular forces) Ionic and covalent Lewis dot Structures Diatomic atoms Polar and non-polar bonds and molecules Intermolecular forces Valence shell electron repulsion theory Geometrical and molecular shape Review questions 1. Name the element; provide the total number of neutrons, electrons and protons from the atomic symbol below. Symbol Name Protons Neutrons Electrons Hg Iodine 47 87 2. Define the following properties as either; Qualitative physical, Quantitative physical, or Chemical. Color ___________________________ Reactivity with acid ___________________________ Density ___________________________ Toxicity ___________________________ Physical State ___________________________ Reactivity with air ___________________________ Hardness ___________________________ Odor ___________________________ 3. Explain the difference between a polar and non-polar bond. Use the following molecules to illustrate the difference. H - Cl H- H 4. Identify the following bonds as Ionic, Polar covalent, or covalent. If polar, illustrate the direction of the dipole using the vector symbol. a. Ti---Cl b. Na---Br c. O---O d. H---F e. Cu---Se 5. The difference between an ionic bond and a covalent bond is that the cation in an ionic bond _____________ its electrons to the anion and in a covalent bond, the electrons are _____________. 6. Determine and explain why the following processes are either a physical or chemical change. (a) A rose bush grows from a seed that you planted and nourished. (b) A green coating forms on a copper statue when the statue is exposed to air. (c) Your sweat evaporates to help balance your body temperature. (d) Frost forms on the inside of a freezer. (e) Juice crystals dissolve in water. (f) An ice-cream cone melts on a hot day. 7. For the following compounds, draw the Lewis Dot structure; determine the geometrical shape, molecular shape, and polarity. K2O N2 AsBr3 CCl3F SrI2 CCl4 HNC S2 MgBr2 F2 8. Using only their locations in the periodic table, rank the atoms in each set by decreasing atomic size. (a) Mg, Be, Ba (b) Ca, Se, Ga (c) Br, Rb, Kr (d) Se, Br, Ca (e) Ba, Sr, Cs (f) Se, Br, Cl (g) Mg, Ca, Li (h) Sr, Ca, Li (i) In, Br, I (j) S, Se, O 9. Using their locations on the periodic table, rank the atoms in each set by increasing electronegativity. (a) Sn, In, Sb (b) Sr, Ca, Ba (c) K, Ca, Rb (d) C, Br, F 10. Explain why ionic compounds generally have a higher melting point when compared to covalent compounds. 12. What is hydrogen bonding, and why does this intermolecular force cause water molecules to be attracted to each other? 13. What are London Dispersion forces? Why are they so weak? 14. In nature, silicon is composed of three isotopes. Calculate the average atomic mass of silicon for the values below. 27.98 u 92.23% 28.97 u 4.67% 29.97 u 3.10 % 15. Lead occurs naturally as fur isotopes. Calculate the average atomic mass of lead from the values below. 204.0 u 206.0 u 207.0 u 208.0 u 1.37% 26.26% 20.82% 51.55% 16. Naturally occurring silver exists in two isotopes, and has an average atomic mass of 107.9 u. From the values below, calculate the isotopic mass of silvers second isotope (solve for X below). Isotope 1: 106.9 u 51.8 % Isotope 2: X 48.2 %