Download Biochemistry - Chapter 12 Study Guide

Biochemistry - Chapter 12 Study Guide
Alcohols, Ethers, Aldehydes, Ketones and Thiols
Draw the following functional groups:
– OH
–O–
– CHO
=O
– SH
Alcohol
Ether
Aldehyde
Ketone
Thiol
Write out the oxidation reactions for each of the following:
1° alcohol
(final product)
1° alcohol

Aldehyde
2° alcohol

Ketone

Carboxylic Acid
2° alcohol
3° alcohol
No Reaction
Thiol
Thiol + Thiol

Disulfide
Aldehyde

Ketone
Aldehyde
Ketone
No Reaction
Name the following molecules:
1, 4 – butandiol
2-hydroxycyclopentanone
butanal
tertbutyl ethyl ether
1-butanethiol
Draw the following molecules in kekulé:
4-methyl-2-hexanol
tert-butyl methyl ether
OH
4-hydroxy-6-phenyl-2-hexenal
O
2,7-dimethyl-3-octanone
O
Indicate the chiral carbons of the following molecules (put an * by the chiral carbons)
A)
B)
C)
OOPS!
No Carbon
D)
E)
Which (if any) are stereo isomers? D and F are stereo isomers
Draw the following molecule in a D and L Fischer Projection:
F)