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National 4 & 5 Chemistry NATIONAL 4 AND NATIONAL 5 CHEMISTRY Unit 1: Chemical Changes and Structure WRITING CHEMICAL FORMULAE (INCLUDING – IONIC FORMULAE) PRACTICE EXAMPLES BOOKLET Page 1 of 17 National 4 & 5 Chemistry N4 ELEMENT FORMULAE N4 In your jotter, write the formulae of the following elements. Present the information in a table with the headings “ELEMENT” and “FORMULA.” carbon aluminium lithium oxygen chromium tungsten hydrogen germanium xenon nitrogen silicon radon chlorine arsenic bromine cobalt titanium zirconium silver N4 radium - IDE COMPOUNDS 1 N4 In your jotter, name the elements in the following compounds. Present the information in a table with the headings “COMPOUND NAME” and “ELEMENTS PRESENT.” N4 potassium oxide sodium chloride magnesium sulphide aluminium bromide calcium carbide hydrogen iodide silicon oxide lithium phosphide copper fluoride magnesium nitride mercury oxide sodium silicide - IDE COMPOUNDS 2 In your jotter, name the following compounds. Present the information in a table with the headings “FORMULA” and “COMPOUND NAME.” MgCl2 CaF2 CuO Al2O3 K2O K3N NH3 H2S PI3 PbBr4 Na2O LiI Fe2S3 MnO2 AuCl3 SiBr4 Page 2 of 17 N4 National 4 & 5 Chemistry N4 -ATE & -ITE COMPOUNDS N4 In your jotter, name the elements in following compounds. Present the information in a table with the headings “COMPOUND NAME” and “ELEMENTS PRESENT.” sodium sulphate aluminium nitrate calcium carbonate cobalt phosphate tin sulphite lead chlorate silver nitrite mercury bromate aluminium silicate copper carbonate nickel chromate barium iodate N4 1. VALENCY DIAGRAMS Draw the valency picture of the following atoms. potassium 2. N4 N4 carbon fluorine oxygen barium Draw the valency diagram and write the formula of the following compounds. potassium oxide sodium chloride magnesium oxide aluminium bromide calcium carbide aluminium sulphide silicon oxide lithium phosphide nitrogen fluoride hydrogen oxide carbon hydride sodium silicide FORMULAE OF -IDE COMPOUNDS Use the short cut method to write the formulae of the following compounds. lithium fluoride beryllium sulphide aluminium nitride rubidium oxide sulphur chloride boron oxide phosphorus hydride carbon oxide aluminium sulphide nitrogen iodide silicon nitride magnesium carbide sodium hydride barium chloride germanium bromide Page 3 of 17 N4 National 4 & 5 Chemistry N4 RULE BREAKING FORMULAE N4 Write the formulae of the following compounds. nitrogen dioxide phosphorus tribromide chlorine trifluoride manganese dioxide dinitrogen oxide sulphur dioxide phosphorus pentachloride silicon tetrabromide nitrogen triiodide N5 FORMULAE WITH GROUPS 1 N5 Draw the valency diagram and write the formula of the following compounds. ammonium fluoride calcium sulphate aluminium phosphate lithium carbonate potassium hydroxide sodium sulphate ammonium hydroxide potassium nitrate rubidium phosphate N5 FORMULAE WITH GROUPS 2 N5 Use the table of “Formulae Of Selected Ions Containing More Than One Atom” to write the formulae of the following compounds. ammonium nitrate calcium chromate potassium permanganate sodium hydrogencarbonate lithium dichromate rubidium hydrogensulphate ammonium ethanoate potassium sulphite hydrogen phosphate caesium hydroxide magnesium carbonate barium dichromate Page 4 of 17 National 4 & 5 Chemistry N5 ROMAN NUMERAL FORMULAE 1 N5 Write the formulae of the following transition metal compounds. You will need to use the “Formulae Of Selected Ions Containing More Than One Atom” to write the formula of some of the compounds. copper(II) oxide nickel(II) chloride gold(I) nitrate iron(II) carbonate silver(I) hydroxide mercury(I) sulphate zinc(II) sulphide platinum(II) fluoride cobalt(III) phosphate manganese(IV) oxide chromium(III) bromide vanadium(V) oxide titanium(II) sulphite iron(III) phosphate scandium(III) chloride N5 ROMAN NUMERAL FORMULAE 2 Write the formulae of the following compounds. zinc chloride lead(II) sulphate tin(IV) chloride lead(II) sulphide zinc carbonate silver nitrate ammonium bromide nickel(III) fluoride tin(IV) oxide lead(II) chromate mercury(II) iodide magnesium sulphite zinc dichromate silver permanganate tin(II) phosphide sodium ethanoate ammonium hydroxide zinc sulphite lead(IV) oxide titanium(IV) chloride vanadium(V) iodide Page 5 of 17 N5 National 4 & 5 Chemistry N5 REMOVING BRACKETS N5 Write the formulae of the following compounds. copper(II) carbonate potassium ethanoate sodium permanganate mercury(II) dichromate silver hydroxide ammonium fluoride lithium phosphate barium sulphate caesium hydrogencarbonate nickel(II) chromate cobalt(III) phosphate gold(II) carbonate N5 FORMULAE WITH GROUPS 3 N5 Write the formulae of the following compounds. calcium nitrate ammonium carbonate aluminium sulphate zinc hydroxide iron(III) sulphite copper(II) hydroxide ammonium phosphate lead(II) nitrate gold(III) hydrogensulphate silver chromate tin(II) phosphate barium permanganate magnesium hydroxide cobalt(II) phosphate ammonium dichromate tin(IV) hydrogencarbonate manganese(IV) carbonate nickel(II) hydroxide lithium chromate lead(IV) sulphite ammonium phosphate N5 IONIC FORMULAE 1 Write the ionic formulae of the following compounds. sodium chloride calcium oxide aluminium bromide potassium sulphide nickel(II) chloride iron(III) oxide sodium phosphide aluminium oxide silver oxide barium sulphide copper(II) iodide lead(II) chloride tin(II) chloride cobalt(III) sulphide manganese(IV) oxide calcium nitride zinc chloride magnesium carbide Page 6 of 17 N5 National 4 & 5 Chemistry N5 IONIC FORMULAE 2 Write the ionic formulae of the following compounds. iron(II) carbonate aluminium sulphate sodium phosphate barium hydroxide copper(II) sulphite potassium permanganate calcium ethanoate ammonium dichromate zinc hydrogencarbonate lead(II) hydroxide silver chromate ammonium chloride tin(IV) phosphate mercury(II) nitrate ammonium phosphate Page 7 of 17 N5 National 4 & 5 Chemistry NATIONAL 4 AND NATIONAL 5 CHEMISTRY Unit 1: Chemical Changes and Structure BALANCING EQUATIONS PRACTICE EXAMPLES BOOKLET Rules 1. Can’t change formula 2. Can change quantity. Page 8 of 17 National 4 & 5 Chemistry N5 BALANCING EQUATIONS 1 N5 In your Jotter balance the following chemical equations using the ‘check table to help you’: 1) Zn + HCl Left ZnCl2 + H2 3) CaO CaCl2 + H2O Right Ca O H Cl 2) Na + H2SO4 Na2SO4 + H2 4) Al + Fe2O3 Al2O3 + Fe Right Na H S O N5 HCl Left Right Zn H Cl Left + Left Right Al Fe O BALANCING EQUATIONS 2 In your jotter balance the following chemical equations: Page 9 of 17 N5 National 4 & 5 Chemistry NATIONAL 4 AND NATIONAL 5 CHEMISTRY Unit 1: Chemical Changes and Structure FORMULA MASS PRACTICE EXAMPLES BOOKLET RELATIVE ATOMIC MASS The average mass of an atom is called the RELATIVE ATOMIC MASS. The relative atomic mass of selected elements is listed in the chemistry data booklet. ATOM RELATIVE ATOMIC MASS H 1 hydrogen O 16 oxygen Cl 35.5 chlorine MASS OF A FORMULA The total mass of all the atoms in a formula is called the FORMULA MASS. oxygen gas (O2) O O 1 32 Cl 35.5 16 1 O H H FORMULA MASS 12 water (H2O) 16 R A M 16 carbon chloride (CCl4) 35.5 Cl C Cl Cl 35.5 Page 10 of 17 18 35.5 154 National 4 & 5 Chemistry N4 FORMULA MASS N4 Calculate the formula mass of each of the following : 1. chlorine [Cl2] 2. hexane [C6H14] 3. magnesium hydroxide [Mg(OH)2] 4. 5. aluminium carbonate [Al2(CO3)3] 6. Calcium Carbonate [CaCO3] ammonium phosphate [(NH4)3PO4] Calculate the formula and then the formula mass of each of the following : 7. Oxygen 8. Hydrogen 9. Lithium Nitride 10. Sodium hydride 11. lithium carbonate N5 12. Copper (ii) sulphate GRAM FORMULA MASS N5 1. oxygen [O2] 2. sucrose [C12H22O11] 3. calcium carbonate [CaCO3] 4. iron(III) sulphate [Fe2(SO4)3] 5. ammonium nitrate [NH4NO3] 6. Ammonium carbonate [(NH4)2CO3] Calculate the formula and then the gram formula mass of each of the following : 7. Nitrogen 9. Calcium Chloride 11. ammonium phosphate 8. Bromine 10. Aluminium Oxide 12. Calcium nitrite Page 11 of 17 National 4 & 5 Chemistry NATIONAL 4 AND NATIONAL 5 CHEMISTRY Unit 1: Chemical Changes and Structure THE MOLE Page 12 of 17 National 4 & 5 Chemistry N5 GRAM FORMULA MASS IS ONE MOLE N5 Calculate the mass of 1 mole of each of the following compounds: 1. Hydrogen 4. Sulfur dioxide 7. Calcium carbonate N5 2. Nitrogen monoxide 5. Carbon hydride 8. Magnesium nitrate 3. Sodium chloride 6. Potassium permanganate 9. Lithium hydroxide MOLES TO MASS CALCULATION N5 Calculate the mass (m) of each of the following: 1. 2. 3. 4. 5. 6. 7. N5 2 moles of iron [Fe] 0.1 mole of nitrogen [N2] 1.5 moles of sodium oxide [Na2O] 0.75 moles of zinc nitrate [Zn(NO3)2] 4.7 moles of sodium hydroxide [NaOH] 0.125 mole silver(I) nitrate [AgNO3] 4 mole of butane [C4H10]. MASS TO MOLES CALCULATION Calculate the number of moles (n) in : 1. 2. 3. 4. 5. 6. 7. 8. 28 g of silicon [Si] 40 g of bromine [Br2] 36 g of water [H2O] 33.3 g of calcium chloride [CaCl2] 456.25 g of nickel(II) nitrate [Ni(NO3)2] 6 g of water [H2O] . 6.4g of oxygen [O2] . 693 g of ammonium sulphate [(NH4)2SO4] Page 13 of 17 N5 National 4 & 5 Chemistry N5 1. THE MOLE AND REACTION QUANTITIES (MOLE RATIO) N5 The balanced equation below shows the reaction between silicon and chlorine producing silicon chloride. Si + 2Cl2 SiCl4 Calculate the number of moles of chlorine required to make 5 mole of silicon chloride. 2. The balanced equation for the combustion of butane, C4H10, is shown below. 2 C4H10 + 13 O2 8 CO2 + 10H2O Calculate the number of moles of oxygen required to burn 0.5 mole of butane, C4H10. 3. The balanced equation for the reaction between zinc and silver nitrate is shown below. Zn + 2 AgNO3 Zn(NO3)2 + 2 Ag Calculate the number of moles of zinc required to produce 12 mole of silver. 4. The balanced equation for the reaction between magnesium oxide and phosphoric acid is shown below. 3 MgO + 2 H3PO4 Mg3(PO4)2 + 3 H2O Calculate the number of moles of magnesium oxide, MgO, required to make 2.5 mole of magnesium phosphate, Mg3(PO4)2. 5. The balanced equation below shows the reaction between aluminium and iodine producing aluminium iodide. 2 Al + 3 I2 2 AlI3 Calculate the number of moles of iodine, which reacts with 0.25 mole of aluminium. Page 14 of 17 National 4 & 5 Chemistry N5 1. MOLE RATIO & MASSES N5 Calcium reacts with chlorine to form calcium chloride as shown by the following balanced equation. Ca + Cl2 CaCl2 Calculate the mass of chlorine, which will react, with 10 g of calcium. 2. Sodium reacts with water to form sodium hydroxide and hydrogen gas. The balanced equation for the reaction is shown below. 2 Na + 2 H2O 2 NaOH + H2 Calculate the mass of sodium hydroxide produced when 9.2 g of sodium is reacted with water. 3. Zinc reacts with nitric acid to produce zinc(II) nitrate and hydrogen gas. . The balanced equation for the reaction is shown below. Zn + 2 HNO3 Zn(NO3)2 + H2 Calculate the mass of zinc required to produce 75.6 g of zinc(II) nitrate when zinc is reacted with nitric acid. 4. Copper(II) oxide reacts with hydrochloric acid to produce copper(II) chloride and water . The equation for the reaction is shown below. CuO (a) + HCl CuCl2 + H2O Copy and balance the equation. (b) Calculate the mass of copper(II) chloride produced when 201.25 kg of copper(II) oxide is reacted with hydrochloric acid. Page 15 of 17 National 4 & 5 Chemistry 5. The alcohol called methanol (CH3OH) is produced in industry by reacting hydrogen with carbon monoxide. The equation for the reaction is shown below. CO + H2 CH3OH The manufacturer has an order for 800 tonnes of methanol (CH3OH). (a) Copy and balance the equation. (b) Calculate the mass of carbon monoxide required to make 800 tonnes of methanol. (c) Calculate the mass of hydrogen required to make 800 tonnes of methanol. Page 16 of 17 National 4 & 5 Chemistry N5 MOLE CALCULATIONS INVOLVING SOLUTIONS N5 Calculate the concentration of the following solutions. 1. 2. 3. 4. 5. 0.5 mole of sodium chloride in 500 cm3 of solution. 2 mole of nitric acid in 4000 cm3 of solution. 0.25 mole of potassium carbonate in 200 cm3 of solution. 1.5 mole of nickel(II) sulphate in 3 litres of solution. 0.05 mole of lithium bromide in 50 cm3 of solution. Calculate the number of moles of solute in the following solutions. 1. 2. 3. 4. 5. N5 200 cm3 of a 2 mol l -1 solution of potassium hydroxide. 1800 cm3 of a 0.25 mol l -1 solution of cobalt(II) chloride. 75 cm3 of a 0.5 mol l -1 solution of phosphoric acid. 2 litres of a 0.4 mol l -1 solution of zinc nitrate. 750 cm3 of a 3 mol l -1 solution of copper(II) chloride. MOLE CALCULATIONS INVOLVING SOLUTIONS & MASSES Calculate the mass of compound in the following solutions. 1. 2. 3. 4. 5. 500 cm3 of a 2 mol l -1 solution of potassium carbonate (K2CO3). 2500 cm3 of a 0.2 mol l -1 solution of copper(II) chloride (CuCl2). 100 cm3 of a 0.5 mol l -1 solution of sulphuric acid (H2SO4). 2 litres of a 0.4 mol l -1 solution of potassium nitrate (KNO3). 250 cm3 of a 1.5 mol l -1 solution of tin(II) sulphate (SnSO4). Calculate the concentration of the following solutions. 1. 2. 3. 4. 5. 7.975 g of copper(II) sulphate [CuSO4] in 100 cm3 of solution. 5 g of sodium hydroxide [NaOH] in 500 cm3 of solution. 273 g of zinc chloride [ZnCl2] in 1500 cm3 of solution. 37.125 g of magnesium nitrate [Mg(NO3)2] in 400 cm3 of solution. 59.6 g of ammonium phosphate [(NH4)3PO4] in 2 litres of solution. Page 17 of 17 N5