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MR. SURRETTE VAN NUYS HIGH SCHOOL CHAPTER 12: ACIDS and BASES WORKSHEET SOLUTIONS 1. The hydronium ion is: 1A. H3O+ 2. Ammonia + water _____ + hydroxide. 2A. NH4+ 3. Kw = 3A. 10-14 4. Acids that have one hydrogen atom that dissociates in water are called: 4A. monoprotic 5. __________ defined acids as substances that donate protons. 5A. Bronsted-Lowry 6. The hydronium ion concentration is the same as the hydroxide ion concentration in __________ solutions. 6A. neutral 7. The hydronium ion concentration is less than the hydroxide ion concentration in __________ solutions. 7A. basic 8. Acid + base salt + water. This reaction is an example of: 8A. neutralization 9. __________ defined acids as substances that produce H+ when dissolved in water. 9A. Arrhenius 10. A sample of pond water has a pH value of 5. This makes the pond water: 10A. acidic 11. (A) (B) (C) (D) HNO3 is a __________ acid. strong monoprotic single hydrogen all of these 12. (A) (B) (C) (D) All of the following are polyprotic acids except: hydrochloric phosphoric sulfuric carbonic 1|Page CHEMISTRY MR. SURRETTE VAN NUYS HIGH SCHOOL 13. Sodium hydroxide is added to pure water. The water will become: 13A. basic 14. Complete the following reaction: sulfuric acid + potassium hydroxide 14A. (1) Identify the reactants (2) Sulfuric acid = H2SO4 (3) Potassium hydroxide = KOH (4) Identify the ions of the reactants (5) H2SO4 = 2 H+ + SO4-2 (6) KOH = K+ + OH(7) Swap opposite charges: (H+ + OH-) + (K+ + SO4-2) (8) Determine the products: H2O + K2SO4 (9) Write a skeletal equation: __ H2SO4 + __ KOH __ K2SO4 + __ H2O (10) Balance the skeletal equation: H2SO4 + 2 KOH K2SO4 + 2 H2O (11) Determine if the K2SO4 product is soluble or insoluble. (12) According to the solubility table: K2SO4 is soluble. (13) Final Equation: H2SO4(aq) + 2 KOH (aq) K2SO4(aq) + 2 H2O (l) 15. Complete the following unbalanced reaction: HCl(g) + H2O(l) 15A. HCl(g) + H2O(l) H3O+(aq) + Cl-(aq) 16. Write the chemical equation that describes what happens when potassium hydroxide dissolves in water. 16A. KOH(aq) K+(aq) + HO-(aq) 17. Predict the chemical equation for ammonia dissolved in water. 17A. NH3(aq) + H2O(l) NH4+(aq) + HO-(aq) 18. What is the concentration of hydronium ions in a solution if the concentration of hydroxide ions is 1.0 x 10-13 M? 18A. (1) [H3O+] [HO-] = Kw (2) [H3O+] = Kw / [HO-] (3) [H3O+] = (1.0 x 10-14) / (1.0 x 10-13) (4) [H3O+] = 1.0 x 10-1 M 2|Page CHEMISTRY MR. SURRETTE VAN NUYS HIGH SCHOOL 19. What is the pH of a solution that contains 1.0 x 10-11 M hydronium ions? 19A. (1) pH = - log[H3O+] (2) pH = - log (1.0 x 10-11) (3) pH = 11 20. Write chemical equations that describe the dissociation of sulfuric acid in water. 20A. First hydrogen: H2SO4(aq) + H2O(l) H3O+(aq) + HSO4-(aq) Second hydrogen: HSO4-(aq) + H2O(l) H3O+(aq) + SO42-(aq) 3|Page CHEMISTRY MR. SURRETTE VAN NUYS HIGH SCHOOL CHAPTER 12: ACIDS and BASES QUIZ SOLUTIONS 1. __________ defined bases as substances that produce OH- when dissolved in water. 1A. Arrhenius 2. The hydronium ion is: 2A. H3O+ 3. Acids that have one hydrogen atom that dissociates in water are called: 3A. monoprotic 4. HNO3 is a __________ acid. (A) strong (B) monoprotic (C) single hydrogen (D) all of these 5. All of the following are monoprotic acids except: 5A. Carbonic 6. __________ defined bases as substances that accept protons. 6A. Bronsted-Lowry 7. Kw = 7A. 10-14 8. The hydronium ion concentration is greater than the hydroxide ion concentration in __________ solutions. 8A. acidic 9. The hydronium ion concentration is less than the hydroxide ion concentration in __________ solutions. 9A. basic 10. A solution has a pH value of 12. This makes the solution: 10A. basic 11. Sodium hydroxide is added to pure water. The water will become: 11A. basic 12. HClO3 is added to pure water. The water will become: 12A. acidic 13. Pure H2O has a pH value of: 13A. 7 4|Page CHEMISTRY MR. SURRETTE VAN NUYS HIGH SCHOOL 14. Complete the following reaction: sulfuric acid + sodium hydroxide 14A. (1) Identify the reactants (2) Sulfuric acid = H2SO4 (3) Sodium hydroxide = NaOH (4) Identify the ions of the reactants (5) H2SO4 = 2 H+ + SO4-2 (6) NaOH = Na+ + OH(7) Swap opposite charges: (H+ + OH-) + (Na+ + SO4-2) (8) Determine the products: H2O + Na2SO4 (9) Write a skeletal equation: __ H2SO4 + __ NaOH __ Na2SO4 + __ H2O (10) Balance the skeletal equation: H2SO4 + 2 NaOH Na2SO4 + 2 H2O (11) Determine if the Na2SO4 product is soluble or insoluble. (12) According to the solubility table: Na2SO4 is soluble. (13) Final Equation: H2SO4(aq) + 2 NaOH(aq) Na2SO4(aq) + 2 H2O(l) 15. Complete the following unbalanced reaction: HNO3(aq) + H2O(l) 15A. HNO3(aq) + H2O(l) H3O+(aq) + NO3-(aq) 16. Write the chemical equation that describes what happens when sodium hydroxide is stirred into water. 16A. NaOH(aq) Na+(aq) + HO-(aq) 17. Predict the chemical equation for ammonia dissolved in water. 17A. NH3(aq) + H2O(l) NH4+(aq) + HO- (aq) 18. What is the concentration of hydroxide ions in a solution if the concentration of hydronium ions is 1.0 x 10-11 M? 18A. (1) [H3O+] [HO-] = Kw (2) [OH-] = Kw / [H3O+] (3) [OH-] = (1.0 x 10-14) / (1.0 x 10-11) (4) [HO-] = 1.0 x 10-3 M 5|Page CHEMISTRY MR. SURRETTE VAN NUYS HIGH SCHOOL 19. What is the pH of a solution that contains 1.0 x 10-4 M hydronium ions? 19A. (1) pH = - log[H3O+] (2) pH = - log (1.0 x 10-4) (3) pH = 4 20. Write chemical equations that describe the dissociation of carbonic acid in water. 20A. Carbonic acid is a reaction intermediate: H2CO3(aq) CO2(g) + H2O(l) 6|Page CHEMISTRY