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Chem 1151 Spring 2007 Name________KEY______________ h = 6.626E-34 J s hc/λ = ΔE = - 2.18E-18 (1/nf2 – 1/ni2) J Quiz 7A 15 points, 15 min. Lab Sec_______ c = 3.00E+8 m/s λ = h/(mv) 1. (3) The wavelength of light associated with a frequency of 2.00E+9 Hz is A. 6.0E+17 m B. 6.67 m **C. 0.15 m λ = c/ν = 3E+8/2.00E+9 = 0.15 m D. 5.0E-10 m E. 2.00E+9 m 2. (6) A. B. C. D. E. F. Select the correct answer or fill in the blank It takes [more, the same, less] energy to remove an electron from the n = 4 level of hydrogen than from the n = 2 level (ionization process). The energy needed to remove an electron from the ground state of hydrogen is ___2.18E-18____Joules. (write down the value) The Heisenberg’s Uncertainty Principle is the mathematical expression of the “duality of nature”. This state is [true, false] The electron in the ground state of Li2+ is held [more tightly, less tightly, the same as] the electron in the ground state of H. The ground state of hydrogen has quantum number is [0, 1, ∞] The photoelectric effect demonstrated that electrons are [waves, particles, neither] 3. (3) The mass of a proton is @2000 times that of an electron. If both subatomic particles have the same velocity, calculate the ratio of their deBroglie wavelengths, λp/λe **A. 5E-4 λ is indirectly proportional to mass so λp/λe = me/mp = 0.0005 B. 44.72 C. not enough information D. 4E+6 E. 2000 4. (3) **A. B. C. D. E. Which hydrogen atom transition emits the largest amount of energy? ni = 4 nf = 1 ni = 1 nf = 4 ni = 4 nf = 3 ni = 6 nf = 4 ni = 1 nf = 2 Chem 1151 Spring 2007 Name________KEY________________ h = 6.626E-34 J s hc/λ = ΔE = - 2.18E-18 (1/nf2 – 1/ni2) J Quiz 7B 15 points, 15 min. Lab Sec_______ c = 3.00E+8 m/s λ = h/(mv) 1. (3) The frequency of light associated with a wavelength of 0.0043 m is A. 1.43E-11 Hz B. 0.0043 Hz C. 1.3E+6 Hz D. 2.16E+22 Hz **E. 7.00E+10 Hz ν = c/λ = 3E+8/0.0043m = 7E10 Hz 2. (6) A. B. C. D. E. F. Select the correct answer or fill in the blank The ground state of hydrogen has quantum number is [0, 1, ∞] The photoelectric effect demonstrated that electrons are [waves, particles, neither] It takes [more, the same, less] energy to remove an electron from the n = 4 level of hydrogen than from the n = 7 level (ionization process). The electron in the ground state of H is held [more tightly, less tightly, the same as] the electron in the ground state of Li2+. The Heisenberg’s Uncertainty Principle is the mathematical expression of the “duality of nature”. This state is [true, false] The energy needed to remove an electron from the ground state of hydrogen is ___2.18E-18_______Joules. (write down the value) 3. (3) The mass of a neutron is @2000 times that of an electron. If both subatomic particles have the same velocity, calculate the ratio of their deBroglie wavelengths, λe/λn A. 5E-4 **B. 2000 λ is indirectly proportional to mass so λe/λn = mn/me = 2000 C. not enough information D. 4E+6 E. 44.72 4. (3) A. **B. C. D. E. Which hydrogen atom transition emits the largest amount of energy? ni = 1 nf = 4 ni = 4 nf = 1 ni = 4 nf = 3 ni = 6 nf = 4 ni = 1 nf = 2