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Periodicity and Periodic Trends
Periodic Law
– The chemical and physical properties of the
elements are periodic functions of their atomic
numbers; properties of the elements occurred at
repeated intervals called periods.
– This defines the property of periodicity
Periodic Trends
– properties that show patterns when examined across the
periods or vertically down the groups
– while there are many periodic trends, we will focus on
o atomic radii (the plural of radius)
o ionization energy
o electronegativity
Atomic Radii – one half the distance between the nuclei of
identical atoms that are bonded together.
Distance between nuclei
– decreases across periods because the higher nuclear charge
(positive) pulls the electrons closer to the nucleus
– increases down groups because energy levels are being
added outside the nucleus
All content by HST Educational Innovations © 2012. All rights reserved. Use of this material is invited with proper
attribution to the source.
Ionization Energy – the energy required to remove one
electron from a neutral atom of an element.
– increases across periods because it takes more energy to
overcome the electrons attraction to the increasing nuclear
charge
– decreases down groups because it is easier to overcome the
nuclear charge for the outermost electrons as the number of
energy levels increases
Electronegativity – a measure of the ability of an atom in a
compound to attract electrons from other atoms
– increases across periods as a result of the increasing nuclear
charge and ability of the nucleus to attract electrons from a
neighboring atom
– decreases down groups because the nuclear charge is less
able to attract electrons from another atom as additional
energy levels are added
All content by HST Educational Innovations © 2012. All rights reserved. Use of this material is invited with proper
attribution to the source.
Picture used courtesy of http://staff.kings.edu/kdils/studentwork/collinsb/lesson_three.htm
All content by HST Educational Innovations © 2012. All rights reserved. Use of this material is invited with proper
attribution to the source.
Ions
Ions are charged particles or molecules created through
the loss or gain of valence electrons
 Cation – positively charged particle or molecule
created through the loss of valence electrons as a
result of ionization
 Anion – negatively charged particle or molecule
created through the gain of valence electrons as a
result of electronegativity
Ionic Radius
As electrons are gained or lost from a neutral atom, the
atomic radius is altered
 Positive ions (those that experience a loss of
valence electrons)
o Lose an energy level
o The remaining electrons more strongly
attracted to the positive nucleus
o RADIUS DECREASES
 Negative ions (those that experience a gain of
valence electrons)
o Fill the outermost energy level
o Each valence electron is more strongly
repelled by the other electrons
Ions
All content by HST Educational Innovations © 2012. All rights reserved. Use of this material is invited with proper
attribution to the source.
Ions are charged particles or molecules created through
the loss or gain of valence electrons
 Cation – positively charged particle or molecule
created through the loss of valence electrons as a
result of ionization
 Anion – negatively charged particle or molecule
created through the gain of valence electrons as a
result of electronegativity
Ionic Radius
As electrons are gained or lost from a neutral atom, the
atomic radius is altered
 Positive ions (those that experience a loss of
valence electrons)
o Lose an energy level
o The remaining electrons more strongly
attracted to the positive nucleus
o RADIUS DECREASES
 Negative ions (those that experience a gain of
valence electrons)
o Fill the outermost energy level
o Each valence electron is more strongly
repelled by the other electrons
o RADIUS INCREASES
All content by HST Educational Innovations © 2012. All rights reserved. Use of this material is invited with proper
attribution to the source.