Download Semester V Course Name Course Code Credits Inorganic

Department of Chemistry
Dr. Hari Singh Gour University, Sagar
B.Sc. Vth Semester
Pure Chemistry
Semester V
Course Name
Course Code
Credits
Inorganic Chemistry
CHE-C-511
1
Organic Chemistry
CHE-C-512
1
Physical Chemistry
CHE-C-513
2
Laboratory Exercise
CHE-C-514
2
CHE C – 511
Paper I: Inorganic Chemistry
L
T
P
C
01
0
01
01
15 Hrs (1 Hrs/week)
1. Metal ligand bonding in Transition metal complexes:
Limitations of valance bond theory, an elementary idea of crystal field theory,
crystal field splitting in octahedral, tetrahedral and square planer complexes,
factors affecting the crystal field parameters.
2. Magnetic Properties of Transition Metal complexes:
Types of magnetic behaviours, method of determining magnetic susceptibility,
spin only formula, L-S coupling, correlation of  and effective values, orbital
contribution to magnetic moments, applications of magnetic moment data for
3d-metal complexes.
CHE C – 512
Paper II : Organic Chemistry
L
T
P
C
01
0
01
01
15 Hrs (1 Hrs/week)
1
2.
3.
4.
Carbohydrates
Introduction and classification, osazone formation, mutual transformation,
epimerisation, cyclic structure of glucose and fructose, mutarotation, General
idea about disaccharides and polysaccharides, structure of sucrose, maltose,
lactose and starch.
Fats, Oils and detergents
Introduction, glycerides, hydrogenation of unsaturated oils, acid value,
saponification value, iodine value, synthetic detergents,
Amino Acids, Peptides, Proteins
Introduction, classification of amino acids, acid base behaviours, iso-electric
point of amino acids, -amino acid-preparation, properties and physiological
importance, peptide synthesis – classical and solid phase . End group analysis of
amino acids, detection, classification and importance of proteins.
Synthetic Dyes
Introduction, colours and constitution, chromospheres, auxoxhrome and valence
bond theory, synthesis of methyl orange, congored, malachite green, crystal
violet, phenolphthalein, fluorescein, indigo
CHE C – 513
Paper III: Physical Chemistry
L
T
P
C
02
0
01
02
30 Hrs (2 Hrs/week)
1.
2.
4.
5.
6.
7.
Quantum Mechanism-I
Black body radiation, Plank’s radiation law, photoelectric effect, heat capacity
of solids, Bohr’s model of Hydrogen atom (no derivation) and its defects,
Compton Effect
De-Broglie hypothesis, Heisenberg’s uncertainty principle, sinusoidal wave
equation, Hamiltonian operator, Schrödinger equation and its importance,
physical interpretation of the wave function, postulates of quantum mechanism,
particle in one dimensional box.
Quantum Mechanics-II
Schrodinger wave equation for H- atom, separation into three equations (without
derivation), quantum numbers and their importance, Hydrogen like wave
functions, radial wave function, angular wave function
Molecular orbital theory, basic idea- criteria for forming MO from AO,
construction of MO’s by LCAO-H2+ ion, calculation of energy levels from wave
function, physical picture of bonding – anti bonding, wave function, concept of
orbital’s and their characteristics. Hybrid orbitals – sp, sp2, sp3,
calculation of coefficient of AO’s used in these hybrid orbitals. Introduction to
valance bond models of H2, comparison of MO and VB models.
Spectroscopy
Introduction; electromagnetic radiation of the spectrum, basic features of
different spectrometers, statement of Born-Oppenheimer Approximation, degree
of freedom
Rotational Spectra
Di atomic molecules, energy levels of a rigid rotors (semi classical principles),
Selection rules, spectral intensity, distribution using population distribution
(Maxwell-Boltzmann distribution) determination of bond length, qualitative
description of non-rigid rotor, isotope effect.
Vibrational Spectrum
Infra red spectrum, energy levels of simple harmonic oscillators, selection rules,
pure vibrational spectrum, intensity, determination of force constant and
qualitative relation of force constant and bond energies, effect of anharmonic
motion and isotope on spectrum, idea of vibrational frequencies of different
functional groups.
Raman Spectrum
Concept of polarizability, pure Rotational and pure vibrational Raman spectra of
diatomic molecules, selection rules
CHE C – 514
Laboratory Course in Chemistry
Credits-02
Inorganic:
Synthesis and Analysis
a. Preparation of sodium trioxalato ferrate (III) Na3[Fe(C2O4)3] and determination of
its composition by permangnetometry
b. Preparation of [Ni(II)-(DMG)2]
c. Preparation of Copper tetra-amine complex, [Cu(NH3)4]SO4
d. Preparation of cis and trans bisoxalato diaqua chromate (III) ion.
Organic Chemistry
Column Chromatography:
Separation of fluorescein and methyl blue; leaf pigments from spinach leaves.
Qualitative Analysis;
Analysis of an organic mixture containing two solid components using water or
NaHCO3 for separation and preparation of soluble derivatives.
Physical Chemistry
Electrochemistry:
a. Conductometrically determine the strength of the given acid using standard alkali
solution
b. Conductometrically determine the solubility of a sparingly soluble electrolyte
c. Conductometrically determine the saponification of ethyl acetate
d. Conductometrically determine the ionisation constant of a weak acid
e. To titrate potentiometrically the given FAS ferrous ammonium sulphate solution
using KMnO4 / K2Cr2O7 as titrant and calculate the redox- potential of Fe++/ Fe+++
system on the hydrogen scale.
Books :
1. Organic Chemistry, I. L. Finar, ELBS Publication
2. Organic Chemistry, Morrison and Boyed, Prentice-Hall.
3. Organic
Chemistry,
Jagdamba
Singh,
Pragati
Prakashan,
4. Fundamentals of Organic Chemistry, Soloman, John
Wiley & Sons.
5. Organic Chemistry, F.A. Carry, Mc Graw Hill Pub.
6. Advanced experimental Physical chemistry, J.B.Yadav,
Goel Publishing House.
7. Vogel’s text Book of practical organic Chemistry,
B.S.Furniss, A.J. Hannaford, V. Rogers, P.W.G. SSmith
and A.R. Tatchell, ELBS.
8. Experimental
Organic
Chemistry,
Vol
I
and
II,
P.R.Singh, D.S. Gupta and K.S. Bajpai, Tata McGraw
Hill.
9.
A laboratory hand book of Organic qualitative analysis
and
separations,
V.S.
Kulkarni,
S.P.pathak,
D.
ramchandra & Co., Pune.
10. Text book of organic practical chemistry, V.S. Kulkarni,
S.P.pathak, D. ramchandra & Co., Pune.
11. Organic Chemistry, Vol I,II and III, S.M. Mukherjee,
S.P.Singh and R.P.Kapoor, Wiley Eastern Ltd. New Age
International.