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Lesson Plan Chapter 5 The Periodic Law Chapter Opener __Chapter Overview, TE Review the objectives listed in the Student Edition. (GENERAL) __Scientific American, EXT Visit go.hrw.com for advanced project ideas from Scientific American. Section 1 History of the Periodic Table PACING: 90 minutes TENNESSEE SCIENCE CURRICULUM FRAMEWORK: CLE.3221.1.2 Analyze the organization of the modern periodic table. Objectives 1. Explain the roles of Mendeleev and Moseley in the development of the periodic table. 2. Describe the modern periodic table. 3. Explain how the periodic law can be used to predict the physical and chemical properties of elements. 4. Describe how the elements belonging to a group of the periodic table are interrelated in terms of atomic number. National Science Education Standards UCP 1 Systems, order, and organization UCP 2 Evidence, models, and explanation UCP 5 Form and function SAI 1 Abilities necessary to do scientific inquiry SAI 2 Understandings about scientific inquiry HNS 1 Science as a human endeavor HNS 3 Historical perspectives PS 2b An element is composed of a single type of atom. When elements are listed in order according to the number of protons (called the atomic number), repeating patterns of physical and chemical properties identify families of elements with similar properties. This “Periodic Table” is a consequence of the repeating pattern of outermost electrons and their permitted energies. KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 1 Chapter 5 The Periodic Law Lesson Plan FOCUS (5 minutes) __Lesson Starter, TE Ask students what they already know about the periodic table. (GENERAL) MOTIVATE (10 minutes) __Reading Skill Builder, Brainstorming, TE Students discuss examples of periodic occurrences in order to relate them to the concept of periodic law. (BASIC) TEACH (65 minutes) __Holt PowerPoint Resources Use the customizable presentation to enhance your lecture. __Teaching Transparency 30, Periodicity of Atomic Numbers __Teaching Transparency 24A, Properties of Some Elements Predicted by Mendeleev __Teaching Transparency 25A, Predicted Versus Actual Properties for Three Elements __Visual Strategy, Figure 2, TE Ask students to compare Mendeleev’s periodic table with the modern periodic table and explain how the two tables are arranged. (GENERAL) __Visual Strategy, Figure 3, TE Ask students to explain the meaning of unreactive. (GENERAL) __Reading Skill Builder, Reading Hint, TE Students should bookmark the periodic table in their texts and refer back to it often. (BASIC) __Application, TE The noble gases are used for lighted signs because of the light given off by their excited electrons. __QuickLab, Designing Your Own Periodic Table, SE Design a periodic table using information similar to what was available to Mendeleev. __Datasheet for In-Text Lab, QuickLab Designing Your Own Periodic Table, ANC Students use the datasheet to complete the QuickLab. (GENERAL) __Chapter Lab, Inquiry Lab, The Mendeleev Lab of 1869, SE Determine the identity of unknown elements by observing their properties and considering trends in the periodic table. __Datasheet for In-Text Lab, The Mendeleev Lab of 1869, ANC Students use the datasheet to complete the Chapter Lab. (GENERAL) CLOSE (10 minutes) __Section Review, SE Students answer end-of-section vocabulary, key ideas, critical thinking, and interpreting graphics questions. (GENERAL) OTHER RESOURCE OPTIONS KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 2 Chapter 5 The Periodic Law Lesson Plan __Study Guide, Section Review, ANC Use this worksheet to assess students’ understanding of the main concepts presented in the section. (GENERAL) __Section Quiz, ANC Use this quiz to assess students’ understanding of the section. (GENERAL) KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 3 Chapter 5 The Periodic Law Lesson Plan Section 2 Electron Configuration and the Periodic Table PACING: 90 minutes TENNESSEE SCIENCE CURRICULUM FRAMEWORK: CLE.3221.1.2 Analyze the organization of the modern periodic table; CU.3221.1.5 Use the periodic table to identify an element as a metal, nonmetal, or metalloid. Objectives 1. Describe the relationship between electrons in sublevels and the length of each period of the periodic table. 2. Locate and name the four blocks of the periodic table. Explain the reasons for these names. 3. Discuss the relationship between group configurations and group numbers. 4. Describe the locations in the periodic table and the general properties of the alkali metals, the alkaline-earth metals, the halogens, and the noble gases. National Science Education Standards UCP 1 Systems, order, and organization UCP 2 Evidence, models, and explanation UCP 3 Constancy, change, and measurement UCP 5 Form and function PS 2b An element is composed of a single type of atom. When elements are listed in order according to the number of protons (called the atomic number), repeating patterns of physical and chemical properties identify families of elements with similar properties. This “Periodic Table” is a consequence of the repeating pattern of outermost electrons and their permitted energies. FOCUS (5 minutes) __ Lesson Starter, TE Discuss what information can be gathered about an element from its place in the periodic table. Then have the students identify trends and list the characteristics shared by elements in the same group of the periodic table. (GENERAL) MOTIVATE (10 minutes) __Application TE Students should locate examples of metals, metalloids, nonmetals, and noble gases in magazines. TEACH (65 minutes) __Holt PowerPoint Resources Use the customizable presentation to enhance your lecture. KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 4 Chapter 5 The Periodic Law Lesson Plan __Teaching Transparency 31, Blocks of the Periodic Table __Teaching Transparency 26A, The Periodic Table __Teaching Transparency 27A, Relationship Between Periodicity and Electron Configurations __Table Strategy, Table 1, Relationship Between Period Length and Sublevels Being Filled in the Periodic Table, TE Review the Aufbau principle concerning electron configurations. (GENERAL) __Discussion, TE Have students write electron configurations for magnesium, calcium, fluorine, and chlorine; check their answers on the periodic table; and then make observations about other elements from the same group, regarding electron configurations. (GENERAL) __Visual Strategy, Figure 6, TE Discuss the information found on the periodic table, and draw the periodic table with the actinide and lanthanide elements. (BASIC) __Using the Handbook, TE Properties and uses of Group 1 and Group 2 elements are further discussed in the Elements Handbook. __Demonstration, Comparing Reactivities of Alkaline-Earth Metals, TE Demonstrate the reactivities of magnesium and calcium. __Discussion, TE Compare the reactivities of the alkali metals with the alkaline-earth metals. (BASIC) __Sample Problem A, SE Demonstrate the relationship between the positions of elements in the periodic table and their electron configurations. __Practice Problems A, SE Students relate the positions of elements in the periodic table to their electron configurations. __Using the Handbook, TE Properties and uses of transition metals are further discussed in the Elements Handbook. __Visual Strategy, Figure 10, TE Discuss how the transition elements fill s and p orbitals with electrons at the same time and how this relates to oxidation states. (GENERAL) __Application, TE Jewelry is made from gold, silver, and platinum alloys because of the softness of these metals. __Reading Skill Builder, Paired Summarizing, TE Students read the text in pairs and take turns summarizing what they have read. (BASIC) __Careers in Chemistry, Materials Scientist, SE Materials scientists help determine what materials should be used in products, based on desired properties. They also help to synthesize new materials and to produce them efficiently. __Sample Problem B, SE Demonstrate how to use electron configurations of elements to locate those elements in the periodic table. __Practice Problems B, SE Students use electron configurations of elements to locate those elements in the periodic table. __Using the Handbook, TE Properties and uses of the elements in groups 13 through 17 are discussed in the Elements Handbook. KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 5 Chapter 5 The Periodic Law Lesson Plan __Table Strategy, Table 2, Relationships Among Group Numbers, Blocks, and Electron Configurations, TE Explain the outer s and p electrons in p-block elements and what n represents. (GENERAL) __Using the Handbook, TE The chemistry of semiconductors is discussed with Group 14 in the Elements Handbook. __Application, TE Discuss where students have heard the terms halogen and halite before. __Sample Problem C, SE Demonstrate how to classify elements and write their electron configurations based on their period and group. __Practice Problems C, SE Students classify elements and write their electron configurations based on their period and group. __Sample Problem D, SE Demonstrate how to locate elements on the periodic table and predict their properties based on their electron configurations. __Practice Problems D, SE Students locate elements on the periodic table and predict their properties based on their electron configurations. __Math Tutor, Writing Electron Configurations, SE Write the electron configurations of elements by filling the sublevels in order of increasing energy. __Microscale Experiment, Reactivity of Halide Ions, ANC (GENERAL) CLOSE (10 minutes) __Section Review, SE Students answer end-of-section vocabulary, key ideas, critical thinking, and interpreting graphics questions. (GENERAL) __Alternative Assessment, TE In groups, students should research six properties of an assigned chemical family. (GENERAL) __Alternative Assessment, TE Students should research a category of materials (metals, ceramics, polymers, semiconductors, composites) in order to discuss changes in this material’s properties. (GENERAL) OTHER RESOURCE OPTIONS __Study Guide, Section Review, ANC Use this worksheet to assess students’ understanding of the main concepts presented in the section. (GENERAL) __Section Quiz, ANC Use this quiz to assess students’ understanding of the section. (GENERAL) __Additional Sample Problems, TE Demonstrate the relationship between the position of an element in the periodic table and its electron configuration, how to use an element’s electron configuration to locate it in the periodic table, how to classify an element and write its electron configuration based on its period and group, and how to locate an element on the periodic table and predict its properties based on its electron configurations. (GENERAL) __Additional Practice Problems, EXT Students can practice more problems that ask them to relate positions of elements in the periodic table with electron configurations, to use the KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 6 Chapter 5 The Periodic Law Lesson Plan electron configurations of elements to locate those elements in the periodic table, to classify elements and write their electron configurations based on period and group, and to locate elements on the periodic table and predict their properties based on their electron configurations. KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 7 Chapter 5 The Periodic Law Lesson Plan Section 3 Electron Configuration and Periodic Properties PACING: 90 minutes TENNESSEE SCIENCE CURRICULUM FRAMEWORK: CLE.3221.1.2 Analyze the organization of the modern periodic table; CU.3221.1.9 Sequence selected atoms from the main-group elements based on their atomic or ionic radii; CU.3221.1.10 Sequence selected atoms from the main-group elements based on first ionization energy, electron affinity, or electronegativity; SPI.3221.1.3 Describe the trends found in the periodic table with respect to atomic size, ionization energy, electron affinity, or electronegativity. Objectives 1. Define atomic and ionic radii, ionization energy, electron affinity, and electronegativity. 2. Compare the periodic trends of atomic radii, ionization energy, and electronegativity, and state the reasons for these variations. 3. Define valence electrons, and state how many are present in atoms of each main-group element. 4. Compare the atomic radii, ionization energies, and electronegativities of the d-block elements with those of the main-group elements. National Science Education Standards UCP 1 Systems, order, and organization UCP 2 Evidence, models, and explanation UCP 3 Constancy, change, and measurement PS 2a Atoms interact with one another by transferring or sharing electrons that are furthest from the nucleus. These outer electrons govern the chemical properties of the element. PS 2b An element is composed of a single type of atom. When elements are listed in order according to the number of protons (called the atomic number), repeating patterns of physical and chemical properties identify families of elements with similar properties. This “Periodic Table” is a consequence of the repeating pattern of outermost electrons and their permitted energies. PS 2c Bonds between atoms are created when electrons are paired up by being transferred or shared. A substance composed of a single kind of atom is called an element. The atoms may be bonded together into molecules or crystalline solids. A compound is formed when two or more kinds of atoms bind together chemically. FOCUS (5 minutes) __ Lesson Starter, TE Discuss trends in everyday life and how trends can be observed in the arrangement of elements in the periodic table. (GENERAL) KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 8 Chapter 5 The Periodic Law Lesson Plan MOTIVATE (10 minutes) __Reading Skill Builder, Reading Organizer, TE Help students organize what they are reading by filling in a chart as they go along. (BASIC) TEACH (65 minutes) __Holt PowerPoint Resources Use the customizable presentation to enhance your lecture. __Teaching Transparency 32, Periodic Trends of Radii __Teaching Transparency 33, Additional Periodic Trends __Teaching Transparency 28A, Electronegativities __Teaching Transparency 29A, Summary of Periodic Trends __Teaching Transparency 30A, Melting Points and Boiling Points of Period 6 Elements __Visual Strategy, Figure 12, TE Point out why there is no firm agreement on exact values for atomic radii. (GENERAL) __Using the Handbook, TE Summaries of group trends for groups 1 through 17 can be found in the Elements Handbook. __Sample Problem E, SE Demonstrate how to use periodic trends in atomic radius to predict relative sizes of atoms. __Practice Problems E, SE Students use periodic trends in atomic radius to predict relative sizes of atoms. __Visual Strategy, Figure 16, TE Remind students that the different line segments on the graph represent different periods in the periodic table. (BASIC) __Table Strategy, Table 3, Ionization Energies (in kJ/mol) for Elements of Periods 1–3, TE Explain that a large amount of energy is required to ionize any atom or ion that has a noblegas configuration. (ADVANCED) __Sample Problem F, SE Demonstrate how to use periodic trends in ionization energy to predict an element’s location on the periodic table. __Practice Problems F, SE Students use periodic trends in ionization energy to predict an element’s location on the periodic table. __Visual Strategy, Figure 19, TE Have students compare atom and ion sizes for several elements and look for trends. Point out the size difference between cations and anions. (GENERAL) __Table Strategy, Table 4, Valence Electrons in Main-Group Elements, TE Students should focus on trends and relationships concerning reactivity, position in the periodic table, and number of valence electrons. (GENERAL) __Visual Strategy, Figure 20, TE Students should compare Figure 20 with Figure 15 and Figure 17 and note the trends they observe. (BASIC) __Sample Problem G, SE Demonstrate how to use periodic trends to predict periodic properties. __Practice Problems G, SE Students use periodic trends to predict periodic properties. KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 9 Chapter 5 The Periodic Law Lesson Plan __Microscale Experiment, Periodicity of Properties of Oxides, ANC (GENERAL) CLOSE (10 minutes) __Section Review, SE Students answer end-of-section vocabulary, key ideas, critical thinking, and interpreting graphics questions. (GENERAL) __Alternative Assessment, TE Students should compare the atomic radii, ionic energies, and electronegativities of d- and f-block elements with main-group elements and note any trends. OTHER RESOURCE OPTIONS __Study Guide, Section Review, ANC Use this worksheet to assess students’ understanding of the main concepts presented in the section. (GENERAL) __Section Quiz, ANC Use this quiz to assess students’ understanding of the section. (GENERAL) __Additional Sample Problems, TE Demonstrate how to use periodic trends in atomic radius to predict relative sizes of atoms, locations of elements, and periodic properties. (GENERAL) __Additional Practice Problems, EXT Students can practice more problems that ask them to use periodic trends to predict relative sizes of atoms, locations of elements, and periodic properties. __Cross-Disciplinary Connection, EXT Go to go.hrw.com for a full-length article on elements and nutrition. __Interactive Tutor CD-ROM, Periodic Properties Students practice what they have learned using this interactive activity. (GENERAL) KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 10 Chapter 5 The Periodic Law Lesson Plan End of Chapter Review and Assessment PACING: 90 minutes __Chapter Review, SE Students answer questions organized by section and as a mixed review. (GENERAL) __Study Guide, Mixed Review, ANC Use this worksheet to assess students’ understanding of the main concepts presented in the chapter. (GENERAL) __Chapter Test A, The Periodic Law, ANC Assign questions for general level chapter assessment. (GENERAL) __Chapter Test B, The Periodic Law, ANC Assign questions for advanced level chapter assessment. (ADVANCED) __Test Item Listing for ExamView Test Generator Use the Test Item Listing to identify questions to use in a customized homework, quiz, or test using the HRW Test Generator program. OTHER RESOURCE OPTIONS __Standardized Test Prep, SE Have students complete the standardized test prep to help them prepare for standardized tests. (GENERAL) __Holt PowerPoint Resources Use the customizable presentation to help students practice standardized test-taking skills. __Holt PuzzlePro Use this software to create crossword puzzles and word searches that make learning vocabulary fun. (GENERAL) __Graphing Calculator, Graphing Periodic Trends, EXT Go to go.hrw.com for a graphing calculator exercise that asks you to answer questions based on a graph of atomic radius versus atomic number. __Holt Online Learning Visit go.hrw.com to access online resources. Click Holt Online Learning for an online edition of this textbook. __Scientific American For advanced-level project ideas from Scientific American, visit go.hrw.com. __ Interactive Tutor CD-ROM Students practice what they have learned using this interactive activity. (GENERAL) __SciLinks Visit www.scilinks.org, maintained by the National Science Teachers Association, for information on The Periodic Table, Noble Gases, Halogens, and Alkali Metals. __CNN Video, CNN Presents Science in the News: Chemistry Connections Segment 13, Atom Builders KEY SE = Student Edition TE = Teacher Edition ANC = Ancillary EXT = Extension Resource Copyright © by Holt, Rinehart and Winston. All rights reserved. Modern Chemistry 11 Chapter 5 The Periodic Law