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Chapter 8 Notes Packet Reactions and Aqueous Solutions 8.1 Predicting Whether a Reaction Will Occur What are the forces that tend to make reactions go in the direction of the arrow or towards products? 1. 2. 3. 4. 8.2 Reactions in Which a Solid Forms Precipitation Reaction – Soluble Solid– Insoluble Solid – Slightly Soluble Solid – Strong Electrolyte – Weak Electrolyte – When working with aqueous solutions, it is helpful to understand a few concerning which substances are soluble in water and which will form precipitates. The more common solubility rules are listed below: 1. All common salts of ____________ metals and the ammonium_________ ion are soluble. 2. All common acetates _________and nitrates _________are soluble 3. All binary (two element) compounds of halogens (other than F) with metals are soluble, except those of silver, mercury I, and lead. 4. All sulfates ________are soluble except those of barium, strontium, lead, calcium, silver, and mercury I. 5. Except for those in Rule #1, carbonates_________, hydroxides______, oxides_______, and phosphates _______are insoluble. Decide if the following compounds are soluble (S) or insoluble (I) in water. 1. NaOH 5. AgCl 2. KCl 6. ( NH4)2O 3. NaNO3 7. K3(PO4) 4. BaCO3 8. MgO Predict what will happen when the following solutions are mixed. Write the balanced equation for any reaction that occurs. Make sure you label the product that will precipitate and the product that will be dissolved in water. 1. Ba(NO3)2(aq) + K3PO4(aq) 2. Pb(NO3)2(aq) + KI(aq) 3. (NH4)2S(aq) + CoCl2(aq) 4. CaCl2(aq) + K2CO3(aq) 5. Na3PO4(aq) + CrCl3(aq) 8.3 Describing Reactions in Aqueous Solutions NaCl(aq) + AgNO3(aq) AgCl(s) + NaNO3(aq) Molecular Equation – Complete Ionic Equation – Spectator Ions – Net Ionic Equation – Write net ionic equations for the following chemical reactions Example Molecularequation: Pb(NO3)2 + 2 NaI PbI2 + 2 NaNO3 Ionic equation: Pb2+(aq) + 2 NO3-(aq) + 2 Na+(aq) + 2I-(aq) PbI2(s) + 2 Na+(aq) + 2 NO3-(aq) Net ionic equation: Pb2+(aq) + 2I-(aq) PbI2(s) 1. 2 NaF(aq) + Ca(OH)2(aq) 2. 2 HNO3(aq) 3. Pb(NO3)2(aq) + Mg(OH)2(s) + Na2SO4(aq) CaF2(aq) + 2 NaOH(aq) 2 H2O(l) + Mg(NO3)2(aq) PbSO4(s) + 2 NaNO3(aq) 4. Na2CO3(aq) 5. KCl(aq) 8.4 + 2 HCl(aq) + AgNO3(aq) 2 NaCl(aq) KNO3(aq) + H2O(l) + + CO2(g) AgCl(s) Reactions That Form Water: Acids and Bases Acid – Base – Strong Acid – Strong Base – Salt – What happens when acids and bases react together? In a typical acid-base reaction, the products are generally a ________________ and ________________. Look at the example of an acid-base reaction below. HCl + NaOH For the reactants, HCl and NaOH, to recombine and form products, they must first come apart and form ions. What ions do they form? Once these compounds have formed ions, recombinations can occur. The positive ions of one compound attract the negative ions of the other compound. What products are formed? Label the salt. This is a neutralization reaction. Predict the products, balance the equations and label the acid, base, salt and water in the equation. 1. H2SO4 + KOH 2. Mg(OH)2 + H3PO4 3. HF + Ca(OH)2 4. LiOH + HNO3 5. Carbonic Acid + Barium Hydroxide 8.5 - 8.7 Ways to Classify Reactions Acid-Base Reaction (Neutralization Reaction) – Double Displacement or Double Replacement (Precipitation Reactions) – Single Replacement Reactions - Combustion Reactions – Synthesis (Combination) Reactions – Decomposition Reactions – Classify the reactions below as synthesis, decomposition, single replacement, double replacement, combustion or neutralization. Balance the chemical equation. 1. Fe + H2SO4 Fe3(SO4)2 + H2 2. HClO4 + RbOH RbClO4 + H2O 3. K2SO4 + CaCl2 KCl + CaSO4 4. Ni + Cl2 NiCl2 5. H2O H2 6. CH4 + O2 + H2O + O2 CO2 Identify the type of reaction, predict the products and balance the chemical equation for the following reactions. 1. Al + Cl2 2. BaCl2 + Na2SO4 3. KOH + HCl 4. PbO2 5. C3H8 + 6. K MgCl2 + O2 Write correct chemical formulas, balance the atoms and label the reactions as one of four types. 1. Silver nitrate + potassium chloride 2. Iron (III) chloride 3. Chlorine + lithium iodide ACTIVITY SERIES OF THE ELEMENTS The ability of an element to react is referred to as the _______________ of the element. The more readily an element reacts with other substances, the _______________ its activity. An _______________ _______________ is a list of elements organized according to the ease with which they undergo certain chemical reactions. The __________ active element at the top of the series can replace every element below it. A metal will replace another metal in a compound if it is _______________ on the activity list. Activity Series of the elements Li Rb Can react with cold H2O and acids replacing Hydrogen K Ba Sr Ca Na___________________________________________________________ Mg Al Mn Can react with steam and acids, replacing Hydrogen Zn Cr Fe Cd___________________________________________________________ Co Ni Can react with acids, replacing Hydrogen Sn Pb H2 Sb React with oxygen, forming oxides Bi Cu Hg___________________________________________________________ Ag Pt Fairly unreactive Au___________________________________________________________ Demonstration Will the following reaction take place? What is the balanced chemical equation? What type of reaction is this? Based on the activity series, will this reaction occur? Record your observations in the space provided below. Predict whether or not each of the following reactions will occur. If the reactions occur, predict the products and balance the chemical equations. + CuCl2 2. Zn + Pb(NO3)2 3. Cu + FeSO4 1. K