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The Impact of Ligand Design on the Coordination Chemistry and
The Impact of Ligand Design on the Coordination Chemistry and

chapter 4 types of chemical reactions and solution stoichiometry
chapter 4 types of chemical reactions and solution stoichiometry

... unequal sharing of electrons in bonds that results in unequal charge distribution in the overall molecule. Polar molecules have a partial negative end and a partial positive end. These are not full charges as in ionic compounds but are charges much smaller in magnitude. Water is a polar molecule and ...
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... resource, a major component of natural gas, coal-bed gas and shale gas, but also from a variety of renewable sources as biogas,14 could provide an economical and sustainable alternative to petroleum. Furthermore, methane is one of the most destructive greenhouse gas. Thus, the transformation of meth ...
Catalytic oxidation of ammonia to nitrogen
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... The emissions of nitrogen oxides (NOx) and sulphur oxides (SOx) give rise to acidification of the environment. NOx and SOx are converted in the atmosphere to give nitric and sulphuric acid. However emission of ammonia causes acidification of the environment in an indirect way. Reaction of ammonia wi ...
Corrosion of Ceramic and Composite Materials, Second Edition
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... liquid phase sintering (also crystal growth studies) and the dissolution of various raw materials in molten glass in the manufacture of glass products. The proper selection of materials and good design practices can greatly reduce the cost caused by corrosion. To make the proper selection, engineers ...
Chemical Equilibrium - local.brookings.k12.sd.us
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volume 2 - PianetaChimica

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Kinetic investigation of low-pH Fe(II) oxidation and development of a
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Bioorthogonal chemistry



The term bioorthogonal chemistry refers to any chemical reaction that can occur inside of living systems without interfering with native biochemical processes. The term was coined by Carolyn R. Bertozzi in 2003. Since its introduction, the concept of the bioorthogonal reaction has enabled the study of biomolecules such as glycans, proteins, and lipids in real time in living systems without cellular toxicity. A number of chemical ligation strategies have been developed that fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry), between nitrones and cyclooctynes, oxime/hydrazone formation from aldehydes and ketones, the tetrazine ligation, the isocyanide-based click reaction, and most recently, the quadricyclane ligation.The use of bioorthogonal chemistry typically proceeds in two steps. First, a cellular substrate is modified with a bioorthogonal functional group (chemical reporter) and introduced to the cell; substrates include metabolites, enzyme inhibitors, etc. The chemical reporter must not alter the structure of the substrate dramatically to avoid affecting its bioactivity. Secondly, a probe containing the complementary functional group is introduced to react and label the substrate.Although effective bioorthogonal reactions such as copper-free click chemistry have been developed, development of new reactions continues to generate orthogonal methods for labeling to allow multiple methods of labeling to be used in the same biosystems.
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