The Shell Higher Olefins Process (SHOP)
... Generally accepted mechanism: Olefin insertion into a Ni–H bond. ...
... Generally accepted mechanism: Olefin insertion into a Ni–H bond. ...
DESIGN OF CHIRAL IMINO- AND AMINOPYRIDINE LIGANDS
... The synthesis of new molecules that can work as chiral ligands in metal catalyzed enantioselective reactions is currently an area of great interest.1,2 These ligands must be capable of coordinating with the metal ion, generating around it a highly asymmetric environment so that the complex formed is ...
... The synthesis of new molecules that can work as chiral ligands in metal catalyzed enantioselective reactions is currently an area of great interest.1,2 These ligands must be capable of coordinating with the metal ion, generating around it a highly asymmetric environment so that the complex formed is ...
Molybdenum based catalysts as Oxidants and Reductants
... cyclic and acyclic ketones with hydrogen peroxide playing peroxy intermediates with metals (scheme 4). Reduction ...
... cyclic and acyclic ketones with hydrogen peroxide playing peroxy intermediates with metals (scheme 4). Reduction ...
Study Guide on Ch 5 and 6
... a. What are alpha- () and beta- () anomers? (p. 229 bottom) H. Primary alcohols Oxidize to corresponding aldehydes (see the equation below) I. Aldehydes are further oxidized to carboxylic acids. J. Secondary alcohols to corresponding ketones. No more oxidation! ...
... a. What are alpha- () and beta- () anomers? (p. 229 bottom) H. Primary alcohols Oxidize to corresponding aldehydes (see the equation below) I. Aldehydes are further oxidized to carboxylic acids. J. Secondary alcohols to corresponding ketones. No more oxidation! ...
Abstract
... The use of first row transition metals in catalysis as a substitute for scarce and expensive second and third row transition metals is still a challenge One strategy to promote the use of first row transition metals is the use of bimetallic complexes as the cooperativity between the metal centers mi ...
... The use of first row transition metals in catalysis as a substitute for scarce and expensive second and third row transition metals is still a challenge One strategy to promote the use of first row transition metals is the use of bimetallic complexes as the cooperativity between the metal centers mi ...