CHAPTER 1 INTRODUCTION 1.1 Research Background
... were used as ligands in the formerly but due to some disadvantages, such as, the high cost of preparing tertiary (especially chiral) phosphines and their degradative trend in converting to phosphine oxides have only now been addressed by the rich field of NHC ligands used in homogeneous catalysis [8 ...
... were used as ligands in the formerly but due to some disadvantages, such as, the high cost of preparing tertiary (especially chiral) phosphines and their degradative trend in converting to phosphine oxides have only now been addressed by the rich field of NHC ligands used in homogeneous catalysis [8 ...
Catalytic, Thermal, Regioselective Functionalization of Alkanes and
... 2.2. Development of a Photochemical Catalytic Functionalization of Alkanes These results implied that boryl complexes could be used as intermediates in a catalytic functionalization of alkanes and arenes. However, a catalytic cycle involving the Cp*M(CO)n-boryl complexes was difficult to imagine bec ...
... 2.2. Development of a Photochemical Catalytic Functionalization of Alkanes These results implied that boryl complexes could be used as intermediates in a catalytic functionalization of alkanes and arenes. However, a catalytic cycle involving the Cp*M(CO)n-boryl complexes was difficult to imagine bec ...
New Phenylglycine-Derived Primary Amine Organocatalysts for the
... In 2007, a third report on the organocatalytic preparation of warfarin was published,[2c] this time by using the Cinchona-derived amines 9-amino-9-deoxyepiquinine (7) and 9-amino-9-deoxyepicinchonine (8), iminium catalysts previously developed by the same research group.[6] More than 90 % ee was obt ...
... In 2007, a third report on the organocatalytic preparation of warfarin was published,[2c] this time by using the Cinchona-derived amines 9-amino-9-deoxyepiquinine (7) and 9-amino-9-deoxyepicinchonine (8), iminium catalysts previously developed by the same research group.[6] More than 90 % ee was obt ...
Homogeneously catalysed hydrogenation of unsaturated fatty acids
... their solutions in f a t t y acid inactive, we may conclude that the mechanism of the reaction between pure soaps and hydrogen is different from that of the reaction between solutions of metal soaps in f a t t y acids and hydrogen. The catalysts referred to are smnmarized in Table I (for a more comp ...
... their solutions in f a t t y acid inactive, we may conclude that the mechanism of the reaction between pure soaps and hydrogen is different from that of the reaction between solutions of metal soaps in f a t t y acids and hydrogen. The catalysts referred to are smnmarized in Table I (for a more comp ...
Microsoft Word - Open Access Repository of Indian Theses
... The thesis entitled “ Studies directed towards the synthesis of chiral building blocks for bioactive molecules based on dioxolanones” consists of three parts. The Part-1 consists of a new racemisation free synthetic approach for the synthesis of -butyrolactones, the key precursors for the synthesis ...
... The thesis entitled “ Studies directed towards the synthesis of chiral building blocks for bioactive molecules based on dioxolanones” consists of three parts. The Part-1 consists of a new racemisation free synthetic approach for the synthesis of -butyrolactones, the key precursors for the synthesis ...
Richard R. Schrock - Nobel Lecture
... M(CH2C6H5)4, and M[CH2C(CH3)3]4 (M = Ti, Zr, or Hf; Fig 2), were rationalized on the basis of the fact that unlike a compound having an ethyl ligand, the alkyl ligands in these species lack  hydrogens and so of course cannot undergo decomposition processes that involve  hydrogens.7 In 1973 Wilkins ...
... M(CH2C6H5)4, and M[CH2C(CH3)3]4 (M = Ti, Zr, or Hf; Fig 2), were rationalized on the basis of the fact that unlike a compound having an ethyl ligand, the alkyl ligands in these species lack  hydrogens and so of course cannot undergo decomposition processes that involve  hydrogens.7 In 1973 Wilkins ...
Porphyrin Complex - Center for Biomimetic Systems
... (5) Groves, J. T.; Gross, Z.; Stern, M. K. Inorg. Chem. 1994, 33, 5065-5072. (6) The characteristic UV-vis [412 (soret) and 547 nm], 1H NMR (δpyrrole ) 2.8 ppm at 10 °C), and EPR (silence at 4 K) spectra indicate that 2 is (TPFPP)FeIVdO: (a) Nam, W.; Lim, M. H.; Moon, S. K.; Kim, C. J. Am. Chem. Soc ...
... (5) Groves, J. T.; Gross, Z.; Stern, M. K. Inorg. Chem. 1994, 33, 5065-5072. (6) The characteristic UV-vis [412 (soret) and 547 nm], 1H NMR (δpyrrole ) 2.8 ppm at 10 °C), and EPR (silence at 4 K) spectra indicate that 2 is (TPFPP)FeIVdO: (a) Nam, W.; Lim, M. H.; Moon, S. K.; Kim, C. J. Am. Chem. Soc ...
