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Diapositiva 1
Diapositiva 1

... Note that it expression is independent of the size of the spherical specimen. So, if a very large sphere containing a dipole with internal moment i, in a infinite dielectric medium of relative permittivity 1 is considered, the dipole moment of the large sphere is also, i. For = 1 , the ...
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96 11. Use c = in vacuum, in a medium v = 12. Use λ = and 13. (i) (ii
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Circular dichroism



Circular dichroism (CD) is dichroism involving circularly polarized light, i.e., the differential absorption of left- and right-handed light. Left-hand circular (LHC) and right-hand circular (RHC) polarized light represent two possible spin angular momentum states for a photon, and so circular dichroism is also referred to as dichroism for spin angular momentum. This phenomenon was discovered by Jean-Baptiste Biot, Augustin Fresnel, and Aimé Cotton in the first half of the 19th century. It is exhibited in the absorption bands of optically active chiral molecules. CD spectroscopy has a wide range of applications in many different fields. Most notably, UV CD is used to investigate the secondary structure of proteins. UV/Vis CD is used to investigate charge-transfer transitions. Near-infrared CD is used to investigate geometric and electronic structure by probing metal d→d transitions. Vibrational circular dichroism, which uses light from the infrared energy region, is used for structural studies of small organic molecules, and most recently proteins and DNA.
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