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A study of the structure and bonding of small aluminum oxide
A study of the structure and bonding of small aluminum oxide

Oxygen diffusion through perovskite membranes
Oxygen diffusion through perovskite membranes

... Perovskites (ABO3) are a prominent topic of research in materials science (high-Tcelectric conductor [1, 2], ferroelectric [3, 4] or high k dielectric [5], or magnetoresistance [6] material). Doping of these perovskites with multivalent cations on the A- and B- sites can lead to the simultaneous occ ...
2. Electrodics
2. Electrodics

Soft X-ray spectroscopy of single sized CdS nanocrystals: size
Soft X-ray spectroscopy of single sized CdS nanocrystals: size

Stability of layered Ni hydroxide surface precipitates—A dissolution
Stability of layered Ni hydroxide surface precipitates—A dissolution

Schiff base and its transition metal complexes
Schiff base and its transition metal complexes

Chemical Bonding in the Ternary Transition Metal Bismuthides
Chemical Bonding in the Ternary Transition Metal Bismuthides

Band Gap Extraction from Individual Two
Band Gap Extraction from Individual Two

... calculate the band gap of bulk In2O3, we distinguish in the following between the “fundamental gap” (which is the energy position where the first transition occurs) and the “optical gap” (where a significant intensity is measured in the VEELS or the UV−vis data). The results obtained by VEELS are disc ...
Table of Contents - University of Texas Libraries
Table of Contents - University of Texas Libraries

...detail
...detail

Cluster Coagulation and Growth Limited by Surface Interactions with
Cluster Coagulation and Growth Limited by Surface Interactions with

Parent Anions of Iron, Manganese, and Nickel Tetraphenyl
Parent Anions of Iron, Manganese, and Nickel Tetraphenyl

Heterogeneous nucleation in multi-component vapor on a partially
Heterogeneous nucleation in multi-component vapor on a partially

Materials Chemistry Prof. S. Sunder Manoharan Department of
Materials Chemistry Prof. S. Sunder Manoharan Department of

... Now, here I have listed some of the portfolio of this synthetic methods, and purposely I have grouped them into some categories. One of the main and the most simplest approach to solid state synthesis is the direct reaction of solids which is not very, very intricate it does not call for very string ...
The d-Block Elements
The d-Block Elements

Selective Oxidation of Methane over Vycor Glass
Selective Oxidation of Methane over Vycor Glass

Chapter 4. Hard and Soft Acid/Base Theory based on Lewis Acids
Chapter 4. Hard and Soft Acid/Base Theory based on Lewis Acids

... appropriate, because it is the give and take of electrons (+ seeks – and avoids +) that drives all of chemistry. As we will see, there is often a change in stereochemistry at the acceptor atom when the adduct forms. Recognition of Acids and Bases. Lewis Acids. Generally speaking, Lewis acids are not ...
SO2 DETECTION USING PLASMON DAMPING By ELI KASA
SO2 DETECTION USING PLASMON DAMPING By ELI KASA

Re-evaluating the Cu K pre-edge XAS transition in
Re-evaluating the Cu K pre-edge XAS transition in

... excitation into the Cu-centered 3d-hole. For other rst-row transition metals, shis in the pre-edge feature of ca. 1 eV has indicated a unit change in the oxidation state of the metal; however, of the few complexes that have been referred to as containing Cu(III) ions, the pre-edge transition was f ...
Formation and Stability of High-Spin Alkali Clusters - Max-Born
Formation and Stability of High-Spin Alkali Clusters - Max-Born

Kinetics and Chemical Equilibrium
Kinetics and Chemical Equilibrium

Comparison of electronic structures of mass
Comparison of electronic structures of mass

... For Ag islands prepared by evaporating Ag atoms on the sputtered HOPG surface, it was previously shown that the Ag 3d binding energy is very sensitive to the particle size: with decreasing particle size, a positive core level shift can be found, resulting in a shift of 0.6 eV for about 1 nm-sized pa ...
Non-covalent binding of fullerenes and biomolecules at surface
Non-covalent binding of fullerenes and biomolecules at surface

Text - Enlighten: Publications
Text - Enlighten: Publications

... contributions to the study of molecular systems by X-ray absorption near-edge spectroscopy (XANES).20–25 For the present work, we are interested in the study of the Cu K-edge (Cu1s / valence) for identifying the physical oxidation states of Cu ions bound by ligands from the 2p-elements. In this area ...
Oxidation of Pyrite and Marcasite by
Oxidation of Pyrite and Marcasite by

... As follows from the kinetic curves of pyrite and marcasite oxidation by Thiobacillus ferrooxidans bacteria, the processes of inhibition take place during leaching (Figs. 3 and 4). With increasing concentrations of the mineral in the system the rate constant of the reaction decreases while the rate o ...
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Surface properties of transition metal oxides

Transition metal oxides are compounds composed of oxygen atoms bound to transition metals. They are commonly utilized for their catalytic activity and semiconductive properties. Transition metal oxides are also frequently used as pigments in paints and plastics, most notably titanium dioxide. Transition metal oxides have a wide variety of surface structures which affect the surface energy of these compounds and influence their chemical properties. The relative acidity and basicity of the atoms present on the surface of metal oxides are also affected by the coordination of the metal cation and oxygen anion, which alter the catalytic properties of these compounds. For this reason, structural defects in transition metal oxides greatly influence their catalytic properties. The acidic and basic sites on the surface of metal oxides are commonly characterized via infrared spectroscopy, calorimetry among other techniques. Transition metal oxides are also able to undergo photo-assisted adsorption and desorption to control their semiconductivity. One of the more researched properties of these compounds is their response to electromagnetic radiation, which makes them useful catalysts for redox reactions, isotope exchange, specialized surfaces, and a variety of other uses currently being studied.
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