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What is Thermodynamics?
What is Thermodynamics?

... • The change in Gibbs free energy for a reaction at non-STP is written simply as ∆GR. • Although ∆GoR is a constant at STP for any reaction, ∆GR changes as a function of T and P. • Regardless of T and P, a reaction occurs spontaneously in the direction that will reduce the value of ∆GR because ∆GR i ...
Theoretical problems - Scheikundeolympiade
Theoretical problems - Scheikundeolympiade

... atmospheric pressure. If a diver uses a snorkel for breathing, we can use this fact to determine how far below water the surface of the water she can swim. The pressure experienced by the diver a distance d below the surface of the water is determined by the force per unit area exerted by the mass o ...
- Catalyst
- Catalyst

... – a solid precipitate forms when aqueous solutions of certain ions are mixed • Acid-Base: proton transfer reactions – acid donates a proton to a base, forming a molecule (water or another weak acid) and an aqueous salt – Acid: proton-donor; Base: proton-acceptor • Oxidation-Reduction: electron trans ...
Competition for Electrons
Competition for Electrons

... track of electrons based on the arbitrary assumption that shared electrons belong to the more electronegative element n Rules for assigning oxidation numbers q Oxidation numbers for atoms that are free elements are always zero q The oxidation numbers of ions are the same as the charge on the ion q S ...
Spectroscopic Characterization of Mixed Fe−Ni
Spectroscopic Characterization of Mixed Fe−Ni

... overpotential of reaction and the stable activity. Corrigan et al. examined electrodeposited Ni−Fe catalysts in a mixed oxide system for their oxygen evolution capability.20 These electrodeposited films showed higher oxygen evolution activity compared to that of pure Ni or Fe oxide. Miller also inves ...
Types of Chemical Reactions
Types of Chemical Reactions

... Two problems 1. Atomic masses do not convert easily to grams 2. They can’t be weighed (they are too small) ...
in-class assignment - hrsbstaff.ednet.ns.ca
in-class assignment - hrsbstaff.ednet.ns.ca

... compound. It's used as a sunblock for people sensitive to the sun's UV light or are in high risk environments (mountains, snow, water) Notice unlike sodium or potassium chloride, this name uses a Roman numeral between metal and non-metal. Sodium and potassium ions are always a plus one charge, so th ...
Ch 06
Ch 06

... The theoretical interpretation is that the first elementary step is relatively slow because it has a fairly high activation energy. The rate of the overall reaction is basically controlled by this step, just as the slowest worker determined the overall rate at which cars were produced. The second st ...
Theoretical Study of Gas-Phase Reactions of Fe(CO)5 with OH
Theoretical Study of Gas-Phase Reactions of Fe(CO)5 with OH

... in the gas phase,18 since (CO)4FeH2 is a strong acid. The reaction rate was reported to be slow in basic solutions18 as previously predicted. Finally, loss of H2 followed by addition of CO to reform Fe(CO)5 (eqs 5 and 6) was found to be exothermic in the gas phase and rapid in solution.18 While much ...
Unit D: Quantitative Relationships in Chemical Change
Unit D: Quantitative Relationships in Chemical Change

... For each of the following questions, write a balanced chemical equation and then use the mole ratio to answer the question. 1. A student mixes together a solution of silver nitrate with a solution of sodium chromate and a precipitate forms. What amount of precipitate will form if the student has rea ...
L22 - Supplementary Student Notes Package
L22 - Supplementary Student Notes Package

... For each of the following questions, write a balanced chemical equation and then use the mole ratio to answer the question. 1. A student mixes together a solution of silver nitrate with a solution of sodium chromate and a precipitate forms. What amount of precipitate will form if the student has rea ...
Chemical Equations
Chemical Equations

... solution, these can also be balanced in acidic solution or basic solution. They are part of the general topic of oxidation and reduction, oxidation numbers, half-reactions, and electrochemistry which we won't go into here, except to outline the steps. In the method of half-reactions, you first break ...
Main-group elements as transition metals
Main-group elements as transition metals

... labels. This type of activation by main-group species is general, as shown by the fact that several other unsaturated heavier main-group molecules, including the carbene-like :GeAr2 and :SnAr2 as well as the monovalent :GaAr species, have been recently shown to react directly with H2 (Fig. 3a and b) ...
Chem101 - Lecture 5 Introduction Introduction
Chem101 - Lecture 5 Introduction Introduction

... only one product, which is formed from two or more products. - It is also called an addition reaction ...
Types of Aqueous Reactions
Types of Aqueous Reactions

... Group 1A salts are all soluble. All salts containing nitrates, ammonium, chlorate, perchlorate, and acetate are soluble. All Cl, Br, I salts are soluble EXCEPT for Ag, Pb, and Hg22+ salts All sulfates are soluble EXCEPT Pb, Ca, Ag, Sr, Hg22+ and Ba Metal hydroxides are INSOLUBLE except for those of ...
Chapter 7: Recent advances in enzyme technology
Chapter 7: Recent advances in enzyme technology

... and 500 molecules of water for each enzyme molecule) and the enzyme may effectively be operating in an almost anhydrous state. Some hydrophobic lipases retain activity even if fewer molecules of water remain; presumably just sufficient to stabilise the conformation of the active site. The pH of such ...
AP CHEMISTRY – Source: 1999 AP Exam CHAPTER 8 TEST
AP CHEMISTRY – Source: 1999 AP Exam CHAPTER 8 TEST

... I. Mg 2+ is more positively charged than Na+. II. O 2- is more negatively charged than F-. III.The O 2- ion is smaller than the F- ion (A)II only (B) I and II only (C)I and III only (D)II and III only (E) I, II, and III 25. H2Se(g) + 4 O2F2(g)  SeF6(g) + 2 HF(g) + 4 O2(g) Which of the following is ...
pH and pOH (cont.)
pH and pOH (cont.)

... Reactions Between Acids and Bases (cont.) • Measured volumes of the standard solution are added slowly and mixed into the solution in the beaker, and the pH is read and recorded after each addition. The process continues until the reaction reaches the equivalence point, which is the point at which ...
AP Chemistry Standards and Benchmarks
AP Chemistry Standards and Benchmarks

... These descriptive facts, including chemistry involved in environmental and societal issues, should not be isolated form the principles being studied but should be taught throughout the course to illustrate and illuminate the principles. The following areas should be covered: • chemical reactivity an ...
Honors Chemistry Unit 4 Student Packet: Honors Chemistry Problem
Honors Chemistry Unit 4 Student Packet: Honors Chemistry Problem

... 1. In an equation, a substance is shown to be in the gaseous state by placing an upwardpointing arrow after its formula. 2. The symbol ∆ placed over the arrow in an equation means that heat is supplied to the reaction. 3. Atoms are destroyed in a chemical reaction. 4. A skeleton equation is not a ba ...
Questions
Questions

... for the structure given at the start of the question. Draw the structure that is actually present in the solid, and explain why the melting temperature is so high. ...
17.2.3 Interhalogen compounds(65-67)
17.2.3 Interhalogen compounds(65-67)

... IF3 but ClF3 and BrF3 are well-characterized volatile molecular liquids. Both have an unusual T-shaped structure of CzV symmetry, consistent with the presence of 10 electrons in the valency shell of the central atom (Fig. 17.7a,b). A notable feature of both structures is the slight deviation from co ...
summer fun - West Windsor-Plainsboro Regional School District
summer fun - West Windsor-Plainsboro Regional School District

... The solubility of a solute is the amount that can be dissolved in a given quantity of solvent at a given temperature. For example, the solubility of lead (II) nitrate is 56 g/100 mL at 20oC. The solubilities of ionic solids in water vary over a wide range of values. For convenience, we divide compou ...
Ch 17 practice assessment w
Ch 17 practice assessment w

... package and sealing. Some perishable items can be sensitive to changes in temperature and humidity. If they are to stay fresh for the longest possible time, they need to be kept in a controlled environment. But, how can this be accomplished if they are traveling in a truck through different weather ...
Intro to Titrimetry
Intro to Titrimetry

... 1. A Fajans titration of a 0.7908 g sample required 45.32 mL of 0.1046 M AgNO3. What is the %Cl of the sample? 2. The bismuth in 0.7405 g of an alloy was precipitated as BiOCl and separated from the solution by filtration. The washed precipitate was dissolved in nitric acid to convert all chlorine t ...
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Hydrogen-bond catalysis

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