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Tutorial 9 - UBC Physics
Tutorial 9 - UBC Physics

... the unit vectors in our example, quantum states for any system can always be added together to get new quantum states. We interpret the equation in part b as telling us that the photon with polarization 0" is a QUANTUM SUPERPOSITION of a photon with polarization 0 and a photon with polarization (0 - ...
(Haroche) File
(Haroche) File

... spontaneous emission in free space. Consider a oneelectron atom with two electronic levels e and /"separated by an energy interval Ee — Ef = fuo. Spontaneous emission appears as a jump of the electron from level e to level f accompanied by the emission of a photon. This process can be understood as ...
Lanthanides and Actinides
Lanthanides and Actinides

Nitrogen Activation in a Mars–van Krevelen
Nitrogen Activation in a Mars–van Krevelen

1 Bonding in Molecular Crystals from the Local Electronic Pressure
1 Bonding in Molecular Crystals from the Local Electronic Pressure

Experimental Demonstration of Single Photon Nonlocality
Experimental Demonstration of Single Photon Nonlocality

... source (for the setup,   102 ). To minimize the influence of the false coincidences we choose r  t and jrj small to minimize the influence of Pfalse coincidence . This choice introduces a trade-off between the implementation of the projectors described by Eq. (2) and the goal to minimize the in ...
Controlling Cold Collisions of Polar Molecules with External
Controlling Cold Collisions of Polar Molecules with External

Standard Gibbs energies of formation and equilibrium constants
Standard Gibbs energies of formation and equilibrium constants

... equilibrium constants for both these reactions have not been discussed from a computational perspective with comparison between several methods. We present a systematic study comparing four ab-initio methods such as G3B3, CBS-APNO, W1 and CCSD(T), of different accuracy and computational intensity, t ...
Vibrational signatures of Hydrogen bonding in the protonated
Vibrational signatures of Hydrogen bonding in the protonated

... Euclidean volume element dτ = R 2 sin θ1 sin θ 2 dxdydzdRdθ1dθ 2 dφ . The torsion angle φ of the two NH3 fragments can be separated from the other six variables if the potential energy does not depend on it. We have confirmed that the ab initio PES depends only very weakly on this angle (the barrier ...
Coordination and Chemistry of Stable Cu (II) Complexes in the Gas
Coordination and Chemistry of Stable Cu (II) Complexes in the Gas

... identified by scanning the ESA. Mass-analyzed Ion Kinetic Energy (MIKE) scans were performed with the ion source operating at a potential of 5 kV, which allows the transmission of ions with kinetic energies of e10 keV.35 Two types of processes can be observed in the MIKE scans: unimolecular fragment ...
5. Physikalisches Institut
5. Physikalisches Institut

Theory of Excitation Energy Transfer in Pigment - diss.fu
Theory of Excitation Energy Transfer in Pigment - diss.fu

Figure 14-3 Figure 14-3
Figure 14-3 Figure 14-3

Effect of loss on the topological features of dimer chain described by
Effect of loss on the topological features of dimer chain described by

... locating at the non-loss sites, namely, the ‘dark state’. Such states result from the coherence of the wavefunction on the chain when θ = ±π/2. That means with the periodic boundary condition, even there is the loss on B-sites, the dark state can survive in a long time scale. However, the coupling b ...
Single Band Effective Mass Equation and Envolvent
Single Band Effective Mass Equation and Envolvent

... Abstract The single-band effective mass Schrödinger equation to calculate the envelope functions is described and its grounds are shown. These envelope functions are used to multiply periodic part of the Bloch functions to obtain approximate eigenfunctions of the Hamiltonian of a nanostructured semi ...
Disorder(Strength(δ2( Energy( Density( Ext,(( Para( ( MBL( Para
Disorder(Strength(δ2( Energy( Density( Ext,(( Para( ( MBL( Para

Quantum simulations with cold trapped ions
Quantum simulations with cold trapped ions

Raman Scattering in Solids
Raman Scattering in Solids

... lines of the liquid. At the same time, Landsberg and Mandelstam observed a similar effect in solids such as quartz6. This inelastic scattering of light by molecular and crystal vibrations is known as the Raman effect. It is caused by modulations of the susceptibility or polarizability of the scatter ...
Current fluctuations in single electron devices
Current fluctuations in single electron devices

h and j aggregates - DST Unit of Nanoscience
h and j aggregates - DST Unit of Nanoscience

... When  Scheibe  a  Jelly  noticed  J  bands  in  PIC  organic  molecules,  the  called  it  a  “communal”  state  of  the  dyes  [2].  Later  Frank  and  Teller  [3]  noticed  the  similarity  of  these  excitations  with the Frenkel excitation  that was  proposed  for  molecular  crystals  Although  ...
93, 023615 (2016)
93, 023615 (2016)

... can also indicate the type of phase transitions but is less experimentally accessible. Note that the behavior of Fz  is not directly related to the energy derivatives in the 1 -2 plane. In fact it cannot tell the transition involving the stripe phase, as we will show later. Figure 2(a) shows the ...
Probing dipole-forbidden autoionizing states by isolated attosecond
Probing dipole-forbidden autoionizing states by isolated attosecond

Quantum Random Bit Generation using Energy Fluctuations in
Quantum Random Bit Generation using Energy Fluctuations in

... a result, the SISRS is operating in the transient regime so the dynamics are coherent and dominated by a single temporal mode [4]. The spatial coherence of the Stokes beam is high because the pump is tightly focussed to a near diffraction-limited spot, with confocal parameter b ≈ 200 µm much shorter ...
Stability of Organic Cations in Solution
Stability of Organic Cations in Solution

... and orbital specific photoemission cross sections.15,16 We obtain a I:Pb intensity ratio of 2.9 ± 0.1, in good agreement with the MAPbI3 stoichiometry, and a N:Pb ratio of 1.3 ± 0.1, indicative of the presence of extra nitrogen species in the perovskite matrix, as discussed below. The C:N ratio shows ...
Photocatalysis on TiOn Surfaces: Principles, Mechanisms, and
Photocatalysis on TiOn Surfaces: Principles, Mechanisms, and

... Internuclear Distance ...
< 1 ... 18 19 20 21 22 23 24 25 26 ... 110 >

Franck–Condon principle



The Franck–Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. The principle states that during an electronic transition, a change from one vibrational energy level to another will be more likely to happen if the two vibrational wave functions overlap more significantly.
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