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Non-stationary States and Electric Dipole Transitions Evolution in
Non-stationary States and Electric Dipole Transitions Evolution in

... • The value of the transition moment will depend on the overlap of the radial functions, i.e., the the extent to which both radial wavefunction have the same sign in the same region of space. When the principal quantum numbers are very different, this tends to be small. Though there is not restrict ...
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... grain may be deflected by a small amount (as depicted in Figure 3d), but it is not free to swing away from the ‘easyaxis’ (usually the long axis) of the grain. Under the influence of a very high field the magnetisation may be forced out of the easyaxis, but the intensity of magnetisation will not chang ...
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Magnetochemistry



Magnetochemistry is concerned with the magnetic properties of chemical compounds. Magnetic properties arise from the spin and orbital angular momentum of the electrons contained in a compound. Compounds are diamagnetic when they contain no unpaired electrons. Molecular compounds that contain one or more unpaired electrons are paramagnetic. The magnitude of the paramagnetism is expressed as an effective magnetic moment, μeff. For first-row transition metals the magnitude of μeff is, to a first approximation, a simple function of the number of unpaired electrons, the spin-only formula. In general, spin-orbit coupling causes μeff to deviate from the spin-only formula. For the heavier transition metals, lanthanides and actinides, spin-orbit coupling cannot be ignored. Exchange interaction can occur in clusters and infinite lattices, resulting in ferromagnetism, antiferromagnetism or ferrimagnetism depending on the relative orientations of the individual spins.
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