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ATOMIC SPECTRA Theory
ATOMIC SPECTRA Theory

... 5. For the visible photons of question 3, predict the angles ϑ for the first order maxima. The grating has d = 1/651mm. Compare with measured angles. 6. A heavy hydrogen (deuterium) has a mass twice that of a hydrogen. Hydrogen and deuterium are ’isotopes’, which means that they have the same number ...
Click here to Ch 06.2 Covalent Bonding_Lewis Structures
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... • Exceptions to the octet rule include those for atoms that cannot fit eight electrons, and for those that can fit more than eight electrons, into their outermost orbital. • Hydrogen forms bonds in which it is surrounded by only two electrons. • Boron has just three valence electrons, so it tends to ...
PHYS 4011, 5050: Atomic and Molecular Physics
PHYS 4011, 5050: Atomic and Molecular Physics

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Low-energy spectrum and finite temperature properties of quantum

... are R = N rs /π and ω0 = CF ~2 π 2 /(32mrs2 ). The Heisenberg coupling energy of the model Hamiltonian can be fitted to the splitting of the lowest band (vibrational ground state) at a given angular momentum. For example, for six electrons J can be determined from the energy difference of the lowest ...
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... 2 How many milliliters of bromine (density = 3.19 g/mL) are needed to react completely with 85.0 grams of NH3 to produce ammonium bromine and nitrogen en according to the equation below ? 3Br2 (1)+ 8NH 3 (g) → 6NH 4 Br(s) + N 2 (g) a) *b) c) d) e) ...
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... Filtration: Separates components of a mixture based upon differences in particle size. Filtration usually involves separating a precipitate from solution. Crystallization: Separation is based upon differences in solubility of the components in a mixture. Distillation: Separation is based upon differ ...
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... exists as lines in a vibrational-rotational spectrum. CO2 has no pure rotational EM spectrum. The pure rotational energy levels of the molecule exist but they don’t interact with EM radiation. The rotational lines are only apparent as part of the vibrational-rotational spectra of these molecules. So ...
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... stems of all three plants consistently grew away from the center of gravity. So, roots will always grow towards the center of gravity, while stems grow away from the center of gravity. Errors: List here mistakes made in measuring, understanding, and/or procedure that could affect the results recorde ...
Ionic Bonding - Effingham County Schools
Ionic Bonding - Effingham County Schools

... the numbers of positive and negative charges are equal. Example: A sodium ion, Na+, has a charge of 1+. A chloride ion, Cl-, has a charge of 1-. There is an electrical force of attraction between oppositely charged ions. In sodium chloride, these ions combine in a one – to – one ratio so that each p ...
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... experimental results he was probably not aware of what he had begun. This could in retrospect be considered as the starting point of the development towards a new kind of physics, quantum mechanics, developed during the first part of the 20:th century. In the semi-classical Bohr model of the atom, p ...
symmetry in atomic and molecular systems
symmetry in atomic and molecular systems

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X-ray photoelectron spectroscopy



X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the elemental composition at the parts per thousand range, empirical formula, chemical state and electronic state of the elements that exist within a material. XPS spectra are obtained by irradiating a material with a beam of X-rays while simultaneously measuring the kinetic energy and number of electrons that escape from the top 0 to 10 nm of the material being analyzed. XPS requires high vacuum (P ~ 10−8 millibar) or ultra-high vacuum (UHV; P < 10−9 millibar) conditions, although a current area of development is ambient-pressure XPS, in which samples are analyzed at pressures of a few tens of millibar.XPS is a surface chemical analysis technique that can be used to analyze the surface chemistry of a material in its as-received state, or after some treatment, for example: fracturing, cutting or scraping in air or UHV to expose the bulk chemistry, ion beam etching to clean off some or all of the surface contamination (with mild ion etching) or to intentionally expose deeper layers of the sample (with more extensive ion etching) in depth-profiling XPS, exposure to heat to study the changes due to heating, exposure to reactive gases or solutions, exposure to ion beam implant, exposure to ultraviolet light.XPS is also known as ESCA (Electron Spectroscopy for Chemical Analysis), an abbreviation introduced by Kai Siegbahn's research group to emphasize the chemical (rather than merely elemental) information that the technique provides.In principle XPS detects all elements. In practice, using typical laboratory-scale X-ray sources, XPS detects all elements with an atomic number (Z) of 3 (lithium) and above. It cannot easily detect hydrogen (Z = 1) or helium (Z = 2).Detection limits for most of the elements (on a modern instrument) are in the parts per thousand range. Detection limits of parts per million (ppm) are possible, but require special conditions: concentration at top surface or very long collection time (overnight).XPS is routinely used to analyze inorganic compounds, metal alloys, semiconductors, polymers, elements, catalysts, glasses, ceramics, paints, papers, inks, woods, plant parts, make-up, teeth, bones, medical implants, bio-materials, viscous oils, glues, ion-modified materials and many others.XPS is less routinely used to analyze the hydrated forms of some of the above materials by freezing the samples in their hydrated state in an ultra pure environment, and allowing or causing multilayers of ice to sublime away prior to analysis. Such hydrated XPS analysis allows hydrated sample structures, which may be different from vacuum-dehydrated sample structures, to be studied in their more relevant as-used hydrated structure. Many bio-materials such as hydrogels are examples of such samples.
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