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Preparation of G-ORME
Preparation of G-ORME

... chemistry. The strong interatomic repulsive forces are demonstrated in that the G-ORMEs remain as a powder at 1200oC. This phenomenon results from canceling of the normal attractive forces arising from the net interaction between the shielded, paired electrons and the unshielded, unpaired 's' and 'd ...
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... static and uniform magnetic field B [2, 3] which allows us to find out the new additional aspects. In particular, it is found that the kinematical restrictions on the photon absorption process lead to interesting selection effects in angles of propagation of photons which can be absorbed by electron ...
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... system have rewarded researchers with the 1985 and the 1998 Nobel Prizes in Physics. The fact that the two-dimensional systems that experimenters study lies 1000 Angstroms beneath the surface has made determination of the microscopic character of the quantum Hall state quite difficult. Our group has ...
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... frequency redshifted by the superlattice for the parabolic well with superlattice ~PB32!. Both resonances are approximately independent of the number of electrons ~i.e., the gate bias! in the wells. The noise at either end of the spectral range is due to the reduced transmission of the 50 mm beamspl ...
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X-ray photoelectron spectroscopy



X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the elemental composition at the parts per thousand range, empirical formula, chemical state and electronic state of the elements that exist within a material. XPS spectra are obtained by irradiating a material with a beam of X-rays while simultaneously measuring the kinetic energy and number of electrons that escape from the top 0 to 10 nm of the material being analyzed. XPS requires high vacuum (P ~ 10−8 millibar) or ultra-high vacuum (UHV; P < 10−9 millibar) conditions, although a current area of development is ambient-pressure XPS, in which samples are analyzed at pressures of a few tens of millibar.XPS is a surface chemical analysis technique that can be used to analyze the surface chemistry of a material in its as-received state, or after some treatment, for example: fracturing, cutting or scraping in air or UHV to expose the bulk chemistry, ion beam etching to clean off some or all of the surface contamination (with mild ion etching) or to intentionally expose deeper layers of the sample (with more extensive ion etching) in depth-profiling XPS, exposure to heat to study the changes due to heating, exposure to reactive gases or solutions, exposure to ion beam implant, exposure to ultraviolet light.XPS is also known as ESCA (Electron Spectroscopy for Chemical Analysis), an abbreviation introduced by Kai Siegbahn's research group to emphasize the chemical (rather than merely elemental) information that the technique provides.In principle XPS detects all elements. In practice, using typical laboratory-scale X-ray sources, XPS detects all elements with an atomic number (Z) of 3 (lithium) and above. It cannot easily detect hydrogen (Z = 1) or helium (Z = 2).Detection limits for most of the elements (on a modern instrument) are in the parts per thousand range. Detection limits of parts per million (ppm) are possible, but require special conditions: concentration at top surface or very long collection time (overnight).XPS is routinely used to analyze inorganic compounds, metal alloys, semiconductors, polymers, elements, catalysts, glasses, ceramics, paints, papers, inks, woods, plant parts, make-up, teeth, bones, medical implants, bio-materials, viscous oils, glues, ion-modified materials and many others.XPS is less routinely used to analyze the hydrated forms of some of the above materials by freezing the samples in their hydrated state in an ultra pure environment, and allowing or causing multilayers of ice to sublime away prior to analysis. Such hydrated XPS analysis allows hydrated sample structures, which may be different from vacuum-dehydrated sample structures, to be studied in their more relevant as-used hydrated structure. Many bio-materials such as hydrogels are examples of such samples.
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