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Synthesis and thermal decarbonylation of W(CO)5 complexes
Synthesis and thermal decarbonylation of W(CO)5 complexes

... In all cases the TGA curves exhibited a distinct first weight loss step between 100 and 300 C, and a main loss between 300 and 800 C. It was clearly noted that the weight loss produced by further heating the complexes for 1/2 h at 800 C were almost negligible, while the free polymeric ligands unde ...
1. Introduction
1. Introduction

... This chapter is divided into four main parts. Firstly, a brief overview of chemical sensors is provided. It aims at giving a first vision of chemical sensing, as well as at classifying the different devices available at the moment. The second part will focus on gas sensors based on metal oxides. It ...
Preparation and reactions of some lower tungsten halides and
Preparation and reactions of some lower tungsten halides and

... in a volumetric flask. Aliquots were taken for the tungsten and halide analyses. For the tungsten analysis the solution was acidified with 6N nitric acid to a pH less than one and digested just below the boiling point for one hour. Five milliliters of a ten per cent cinchonine solution in 1:1 hydroc ...
W – Tungsten
W – Tungsten

... broadly correlated with Mo, Sb and V values. Lowest W values in stream water (<0.002 µg l-1) are found in northernmost Finland and Norway on Precambrian Shield terrain, in southwest Norway on Caledonides and partly on Precambrian Shield rocks, in north Scotland (partly on Laurentian rocks), central ...
Reaction of niobium with water
Reaction of niobium with water

... solutions using a liquid-liquid extraction technique. In this process tantalum salts are extracted into the ketone MIBK (methyl isobutyl ketone, 4-methyl pentan-2-one). The niobium remains in the HF solution. This solvent extraction procedure yields 98% pure niobium oxide in one phase and a 99.5% pu ...
Letter to Suppliers [DOC]
Letter to Suppliers [DOC]

2C - Edexcel
2C - Edexcel

... volume of alkali. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ......................................... cm3 maximum temperature. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .......................................... °C ...
A1981LW60900001
A1981LW60900001

... marginal lands during the national ploughing-up campaign. I was told to produce effects of all possible nutritional disorders in any chosen crop using sand culture on an unprecedented scale. Being young, inexperienced, and unaware that my senior predecessor had departed at the prospect, I saw no pro ...
Unit Analysis Matter Classification
Unit Analysis Matter Classification

... b) Solid tungsten metal (W) is made up of repeating unit cells that are cubes with edges of length 0.316522 nanometers. Each cube contains two tungsten atoms. Tungsten has a density of 19.300 g/cm3 . 1 mole of tungsten is 183.85 grams. Calculate the number of tungsten atoms in one mole of tungsten. ...
1

Tungsten

Tungsten, also known as wolfram, is a chemical element with symbol W and atomic number 74. The word tungsten comes from the Swedish language tung sten directly translatable to heavy stone, though the name is volfram in Swedish to distinguish it from scheelite, which in Swedish is alternatively named tungsten.A hard, rare metal under standard conditions when uncombined, tungsten is found naturally on Earth only in chemical compounds. It was identified as a new element in 1781, and first isolated as a metal in 1783. Its important ores include wolframite and scheelite. The free element is remarkable for its robustness, especially the fact that it has the highest melting point of all the elements. Also remarkable is its high density of 19.3 times that of water, comparable to that of uranium and gold, and much higher (about 1.7 times) than that of lead. Polycrystalline tungsten is an intrinsically brittle and hard material due to its weak grain boundaries, making it difficult to work. However, pure single-crystalline tungsten is more ductile, and can be cut with a hard-steel hacksaw.Tungsten's many alloys have numerous applications, most notably in incandescent light bulb filaments, X-ray tubes (as both the filament and target), electrodes in TIG welding, superalloys, and radiation shielding. About half is used in the form of tungsten carbide, WC. Tungsten's hardness and high density give it military applications in penetrating projectiles. Tungsten compounds are also often used as industrial catalysts.Tungsten is the only metal from the third transition series that is known to occur in biomolecules, where it is used in a few species of bacteria and archaea. It is the heaviest element known to be used by any living organism. Tungsten interferes with molybdenum and copper metabolism and is somewhat toxic to animal life.
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