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Minimum electrophilicity principle in Lewis acid–base complexes of
Minimum electrophilicity principle in Lewis acid–base complexes of

Coulomb-Blockade Oscillations in Semiconductor Nanostructures
Coulomb-Blockade Oscillations in Semiconductor Nanostructures

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Design principles for oxygen-reduction activity on perovskite oxide
Design principles for oxygen-reduction activity on perovskite oxide

Oxidation-Reduction Reactions - An Introduction to Chemistry
Oxidation-Reduction Reactions - An Introduction to Chemistry

... Bonds between zinc atoms and oxygen atoms are lost in this reaction, so chemists say the zinc has been reduced. Like the term oxidation, the term reduction has been expanded to include similar reactions, even when oxygen is not a participant. The zinc ions in zinc oxide have a +2 charge, and the ato ...
Photophysical studies of formic acid in the VUV. Absorption
Photophysical studies of formic acid in the VUV. Absorption

... The distinction between valence and Rydberg transitions is not always easy to establish since there can be quite a lot of mixing between valence and Rydberg states. Our analysis of the absorption spectrum of formic acid seeks to characterise those states that are predominantly valence or predominant ...
Electron paramagnetic resonance of photoexcited
Electron paramagnetic resonance of photoexcited

... the people who directly or indirectly contributed towards the completion of this thesis. I sincerely thank my supervisor Professor Kohei M. Itoh for giving me an oppertunity to pursue this work under his guidence and for the fruitful discussions that we had on the topics related to this work. His us ...
Trapping and cooling rubidium atoms for quantum information
Trapping and cooling rubidium atoms for quantum information

... Starting with the invention of Isidor Isaac Rabi [1], who used radio-frequency resonance techniques on atomic and molecular beams in 1938, coherent control became possible. In 1949 Norman Ramsey [2] had the ingenious idea to separate the microwave interaction fields with a radiation free zone, allow ...
298
298

Engineering a Robust Quantum Spin Hall State in Graphene via
Engineering a Robust Quantum Spin Hall State in Graphene via

... insulators (TIs) its first experimental confirmation. While many three-dimensional TIs have since been identified, HgTe remains the only known two-dimensional system in this class. Difficulty fabricating HgTe quantum wells has, moreover, hampered their widespread use. With the goal of breaking this ...
Chemistry 133 Problem Set Introduction
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... 1.55 Determine which of the following quantities are measured and which are exact. (a) A book has a mass of 1.000 kg. (b) There are 1000 g in a kilogram. (c) There are 12 inches in a foot. (d) Thirty-seven people entered a room. (e) A football stadium holds 80,000 people. 1.56 How many significant ...
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Disproportionation of Gold(II)

... showed this conclusion could be extended to neutral, threecoordinate AuI complexes of the type Au(phosphine)2X (X ) univalent anion, e.g., chloride, bromide or iodide). The results of these theoretical predictions have been utilized by the experimental group of Omary to design series of novel lumine ...
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electron transport in quantum dots. - Leo Kouwenhoven

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Numerical analysis of transmission coefficient, LDOS, and DOS in

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... [1], a pure 2D crystal consisting of carbon atoms arranged in a honey-comb lattice. For a long time before graphene had been considered only by theoreticians as a basic block used to build theory for graphite [2] and carbon nanotubes [3]. Its existence was doubt since the theory predicted that perfe ...
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... The dihedral angles between the triazine (TZ) ring and the PQO groups, which mainly characterize the differences between the four energy minima are listed in Table 1. They show the same trend as the experimental values (vide supra), since there are always two rather close values which are largely sup ...
Quantum Coherence in Biological Systems
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Level shifts of rubidium Rydberg states due to binary interactions
Level shifts of rubidium Rydberg states due to binary interactions

... 兩C典 are single-particle Rydberg states. Generally, the interaction operator, VInt, can be expanded in multipole terms that scale with increasing negative powers of the interatomic separation, R 关25–27兴. This paper primarily addresses situations in which the typical Rydberg-atom separation, R, is abo ...
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Resolved-Sideband Raman Cooling of a Bound Atom to the 3D Zero

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Exam Review
Exam Review

... propane, and butane. All four compounds contain only carbon and hydrogen. All bonds are nonpolar, therefore all of the molecules are nonpolar. The only type of intermolecular attraction is dispersion for all four molecules. As the size of the atom increases (and the number of electrons) the amount o ...
Curriculum Vitae - Université Paris-Sud
Curriculum Vitae - Université Paris-Sud

... latent image or the effects of radiation were at that time unexplained. Progressively, the complexity of the specific absorption of high-energy radiation by matter, including the non-homogeneous spatial distribution of initial ions and radicals, was better understood, at least in aqueous solutions. ...
M.Sc.Course - Department of Chemistry, IIT Bombay
M.Sc.Course - Department of Chemistry, IIT Bombay

... Variation theorem, variation method, the linear variation method, and the non-crossing rule. Applications: Many-electron atoms, self-consistent field, atomic orbitals, Slater Type Orbitals, Slater exponents and the periodic properties of elements; LCAO-MO, Hückel orbitals; Born-Oppenheimer approxima ...
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Electron configuration



In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom is 1s2 2s2 2p6.Electronic configurations describe electrons as each moving independently in an orbital, in an average field created by all other orbitals. Mathematically, configurations are described by Slater determinants or configuration state functions.According to the laws of quantum mechanics, for systems with only one electron, an energy is associated with each electron configuration and, upon certain conditions, electrons are able to move from one configuration to another by the emission or absorption of a quantum of energy, in the form of a photon.Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements. The concept is also useful for describing the chemical bonds that hold atoms together. In bulk materials, this same idea helps explain the peculiar properties of lasers and semiconductors.
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